Search results for "rfa"
showing 10 items of 11106 documents
Refractive index sensing by a silicon metasurface
2022
The availability of smart materials represents a key enabling milestone for the realization of smart sensors. In this research field, optical sensing has gained a lot of attention in various applications ranging from basic physics to chemistry and biology. Here, we exploit the non-invasive nature of light to achieve an innovative sensor based on all-optical dielectric nano-resonators arranged in a periodic fashion. The proposed sensor can measure refractive index changes up to 10(-6).
Use of digital displays and ocular surface alterations
2023
Aunque nuestra comprensión de los efectos del uso de dispositivos electrónicos sobre la superficie ocular ha aumentado considerablemente desde el inicio de siglo, varias preguntas importantes siguen sin respuesta. Asimismo, los avances tecnológicos y la aparición de nuevas formas de dispositivos digitales hacen necesaria una investigación continua. Esta tesis doctoral presenta un total de 12 estudios independientes los cuales constituyen los pilares de este trabajo (Capítulos 4-15). En primer lugar, el Capítulo 4 tuvo como objetivo evaluar la asociación entre los factores de riesgo de la enfermedad de ojo seco (EOS) y el síndrome visual informático (SVI). Se llevó a cabo una encuesta online…
Synthesis and Holographic Properties of Alkyl 2-Cyanoacetate Acceptor Fragment Containing Push – Pull Type Organic Glasses
2015
We present synthesis, optical and holographic properties of original structure organic glasses based on compounds consisting of three fragments: of N,N-bis(2-(trityloxy)ethyl)-4-vinylaniline or N,N-bis(5,5,5-triphenylpentyl)-4-vinylaniline fragments as electron donating fragment (D), 4H-pyran-4-ylidene fragment as linker(π) and of 2-(trityloxy)ethyl 2-cyanoacetate or 5,5,5-triphenylpentyl 2-cyanoacetate as acceptor (A) fragment. These push-pull (D- π-A) type molecular compounds show good solubility in non-polar solvents (CHCl3 or CH2Cl2) and neat thin films with sufficient optical qualities have been obtained by spin-coating technique. Maxima of UV–VIS absorption in dichloromethane solution…
Direct P-functionalization of azobenzene by a cationic phosphidozirconocene complex.
2016
International audience; We report that the cationic phosphidozirconocene complex [(eta(5)-C5H5)(2)Zr(PCy2)][CH3B(C6F5)(3)] (II) reacts with azobenzene, resulting in the expedient formation of Zr complex (2) bound to a tridentate PNN ligand. This reaction proceeds by a mechanism of cooperative nucleophilic substitution of hydrogen. The intermediate sigma(H) adduct (1) has been characterized by NMR spectroscopy.
An inverse problem for the minimal surface equation
2022
We use the method of higher order linearization to study an inverse boundary value problem for the minimal surface equation on a Riemannian manifold $(\mathbb{R}^n,g)$, where the metric $g$ is conformally Euclidean. In particular we show that with the knowledge of Dirichlet-to-Neumann map associated to the minimal surface equation, one can determine the Taylor series of the conformal factor $c(x)$ at $x_n=0$ up to a multiplicative constant. We show this both in the full data case and in some partial data cases.
Isolated lip dermatitis (atopic cheilitis), successfully treated with topical tacrolimus 0.03%
2020
Background Exfoliative and erosive cheilitis, may be a source of speech and chewing discomfort, but may also be an aesthetic issue for the patients affected. Such a clinical presentation may implicate a variety of inflammatory conditions, including atopic (eczematous) cheilitis. Topical and systemic agents, e.g. corticosteroids, have been used to treat inflammatory lip conditions. Topical tacrolimus has also been used in some inflammatory lip conditions. Material and Methods We performed a retrospective clinical analysis of atopic cheilitis patients. Results Between 2015 and 2020, we addressed 7 (seven) patients with atopic dermatitis affecting only lips and were diagnosed as atopic-eczemat…
Mezenhimālo stromas šūnu osteoģenēzes raksturojums uz amorfā kalcija fosfāta biomateriāla
2021
Mezenhimālās stromas šūnas ir plaši pētīts šūnu veids to potenciālo ārstniecisko efektu dēļ, no kuriem populārākie ir imūnmodulācija un audu reģenerācija. Bakalaura darbs bija fokusēts uz mezenhimālo stromas šūnu pielietojumu kaulaudu reģenerācijā un to biosaderību ar amorfo kalcija fosfātu, kas organismā atrodams kaula veidošanās sākumstadijā. Darba mērķis bija raksturot uz amorfā kalcija fosfāta biomateriāla audzētu mezenhimālo stromas šūnu osteoģenēzes potenciālu. Osteoģenēzes raksturošanai izmantoja osteokalcīna imūnfluorescento iezīmēšanu, savukārt, biosaderību analizēja ar kolorimetrisko CKK-8 analīzi. Rezultāti uzrādīja, ka mezenhimālas stromas šūnas ir spējīgas augt uz biomateriāla,…
DFT Prediction of Enhanced Reducibility of Monoclinic Zirconia upon Rhodium Deposition.
2018
Oxides are an important class of materials and are widely used, for example, as supports in heterogeneous catalysis. In a number of industrial catalytic processes, oxide supports actively participate in chemical transformations by releasing lattice oxygen anions. While this is intuitively understood for reducible oxides, the reducibility of irreducible oxides may be modified via nanoengineering or upon inclusion of foreign species. Our calculations predict that the ability of irreducible monoclinic zirconia to release oxygen improves substantially upon deposition of rhodium. Through a comprehensive screening of Rh/ZrO2 with different size of the rhodium species, we find that a Rh adatom and…
Caratterizzazione di tipi locali di Solanum melongena L. diffusi in Sicilia
2006
UV filters: From sunscreens to human body and the environment
2007
Recognition of the harmful effects of ultraviolet (UV) radiation on the skin has triggered development of organic chemicals (commonly referred as UV filters) that can absorb UV radiation and attenuate the negative effects of sunlight exposure. Depending on the properties and the intended degree of protection, a wide array of combinations is being marketed as delivering protection against most kinds of UV-induced skin damage. However, some UV filters have dermatological implications, so maximum applicable concentrations have been established. To monitor to what extent commercial products comply with the mandatory limits, several analytical methods have been used for their determination in co…