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showing 10 items of 2851 documents

Alcohol-Selective Oxidation in Water under Mild Conditions via a Novel Approach to Hybrid Composite Photocatalysts

2015

Abstract The oxidation of alcohols to carbonyl compounds in a clean fashion (i.e., with water as a solvent or under solvent‐free conditions, and using O2 or H2O2 as the primary oxidant) is the subject of considerable research efforts. A new approach for the selective oxidation of soluble aromatic alcohols in water under mild conditions via a novel composite photocatalyst has been developed. The catalyst is synthesized by grafting 4‐(4‐(4‐hydroxyphenylimino)cyclohexa‐2,5dienylideneamino)phenol and silver nanoparticles onto the surface of moderately crystalline titanium dioxide. The titanium dioxide‐based composite was first extensively characterized and then employed in the catalytic oxidati…

nanostructurePhotochemistryAldehydecompositesSilver nanoparticleCatalysischemistry.chemical_compoundphotocatalysinanostructuresPhenolcompositechemistry.chemical_classificationSettore ING-IND/24 - Principi Di Ingegneria ChimicaFull Papertitanium dioxidealcohol oxidation; composites; nanostructures; photocatalysis; titanium dioxide; Chemistry (all)Chemistry (all)alcohol oxidationGeneral ChemistryFull PapersCatalytic oxidationchemistryAlcohol oxidationTitanium dioxidePhotocatalysisSettore CHIM/07 - Fondamenti Chimici Delle Tecnologiephotocatalysis
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Ecological impacts of invasive signal crayfish in large boreal lakes

2012

native fishkalakannattulokaslajitmacroinvertebratestäplärapuparasitesselkärangattomatravinnonkäyttöinvasive speciesPacifastacus leniusculuspohjaeläimistöloisetmonimuotoisuushabitat connectivityvieraslajit
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A review of the analytical and numerical modeling of composites

2016

This review article is dedicated to the materials that are made from two or more constituent materials with different physical and/or chemical properties. The focus is on the materials, where the individual components remain separate and distinct within the final structure. The new combined material usually have some additional characteristic properties compared to the individual components, or, in other case, some critical properties of combined material may follow almost equally one of the components. Typically, preferred properties of the new material can be such as strength, porosity, conductivity or cheapness. The ultimate goal of this study is to find methods and tools for achieve adequ…

numerical modelingmateriaalitmallinnusmatemaattiset mallitcompositesmaterials
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Recent progress in metal-organic frameworks (MOFs) for CO2 capture at different pressures

2022

Global climate change ensued by the rise in atmospheric CO2 levels is one of the greatest challenges our planet is facing today. This worldwide distress demands technologies that can contribute to our society toward “negative carbon emissions”. Carbon capture and storage (CCS) technologies are in in important role for capturing CO2 from existing emission sources, such as industrial and energy production point sources, before new more prominent modifications to the energy infrastructure can be implemented. Recently, alongside point source capture, direct air capture (DAC) processes have emerged as highly sought-after technologies that are able to capture CO2 from the ambient air. Alongside t…

open metal sitescarbon capturehiiliProcess Chemistry and Technologyflue gasadsorption mechanismchemisorptionPollutionamine-functionalizedadsorbenthybrid ultra-microporous materialsphysisorptiondirect air captureregenerationChemical Engineering (miscellaneous)savukaasutadsorptiometal-organic frameworkshiilidioksidin talteenotto ja varastointiWaste Management and DisposalJournal of Environmental Chemical Engineering
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Influence of PDA Coating on the Structural, Optical and Surface Properties of ZnO Nanostructures

2020

Polydopamine (PDA) is a new biocompatible material, which has prospects in biomedical and sensor applications. Due to functional groups, it can host wide range of biomolecules. ZnO nanostructures are well known templates for optical sensors and biosensors. The combination of ZnO and PDA results in a change of optical properties of ZnO&ndash

optical sensorsMaterials sciencePhotoluminescenceNanostructureNanocompositeGeneral Chemical Engineeringengineering.materialArticlelcsh:Chemistryfundamental propertiessymbols.namesakeAdsorptionlcsh:QD1-999CoatingChemical engineeringengineeringsymbolsGeneral Materials ScienceDiffuse reflectionZnO–polydopamine nanocompositesFourier transform infrared spectroscopyRaman spectroscopyNanomaterials
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"Pamiętam, że...". O społecznej konstrukcji pamięci mieszkańców miast Ziem Zachodnich i Północnych na przykładzie Wrocławia

2017

Celem artykułu jest przedstawienie wątków pamięci społecznej, które z jednej strony opierają się na indywidualnym, potocznym doświadczeniu jednostki, z drugiej umieszczane są w społecznie wynegocjowanych ramach pamięci zbiorowej. Artykuł ten wpisuje się również w dyskusję nad miejscami pamięci i ich możliwą treścią - wykraczającą poza podtrzymujące pamięć zbiorową muzea, pomniki, upamiętniające tablice czy cmentarze - realizowaną w codziennym życiu jednostki. Przedmiotem analiz jest pamięć społeczna mieszkańców Wrocławia, ich konstrukcje światów społecznych opierające się na przestrzeni miasta obciążonej obcą kulturowo „pamięcią nieobecnych”.

pamięć społecznaanaliza dyskursusocial memoryWrocławmiejsca pamięcidiscourse analysissthe western and northern territoriesziemie zachodnie i północnetożsamośćsites of memoryidentittyOpuscula Sociologica
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How educators commit to enhancing children’s participation in early childhood education pedagogical plans

2022

Background: This is a descriptive study of children’s participation plans in early childhood education (ECE) settings in Finland. The study adopted a multidimensional approach to find out how practices of children’s participation were conceived in pedagogical plans made by ECE staff, representing a focus that is rare in the existing body of research. Aim: Aim of the study was to investigate educators’ commitments to enhancing children’s participation in pedagogical practices in their ECE settings. Setting: Ten centre-based plans for children’s participation composed by ECE staff at ECE centres were selected for the document data in this study. Methods: This study employs the categorisation …

participation practicesvarhaiskasvatuspedagogyprerequisites for participationchildren’s participationEducationvarhaiskasvatussuunnitelmatosallistaminenpedagoginen suunnitteluvarhaiskasvatuksen opettajatDevelopmental and Educational Psychologyearly childhood educationchildren's participationeducatorspedagogical plansSouth African Journal of Childhood Education
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PHOTOOXIDATION BEHAVIOR OF POLYPROPYLENE NANOCOMPOSITES WITH MODIFIED HALLOYSITE

2017

The photooxidation behaviour of polymer nanocomposites depends on the photooxidation of the matrix, but also on the possible interactions with the nanoparticles. In this work, the effect of halloysite modified nanoparticles on the photooxidation of a polypropylene matrix has been investigated.

photooxidation nanocomposites
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Polypropylene/polyhedral oligomeric silsesquioxane nanocomposites – study of free volumes, crystallinity degree and mass flow rate

2016

Nanokompozyty polipropylen/poliedryczne oligomeryczne silseskwioksany (PP/POSS) przygotowano metodą mieszania w stanie stopionym polimeru. Wpływ struktury oraz ilości zastosowanych nanonapełniaczy POSS na objętości swobodne w polipropylenie określono z zastosowaniem spektroskopii czasów życia pozytonów (PALS). Ustalono zależności pomiędzy parametrami PALS: czasem życia o-Ps (τ3) i natężeniem (I3) składowej o-Ps oraz wartościami stopnia krystaliczności (Xc ) i masowego wskaźnika szybkości płynięcia (MFR) badanych materiałów. Obecność nanonapełniaczy POSS wpłynęła na liczbę i rozmiary objętości swobodnych w polimerze, co spowodowało zmianę mikrostruktury osnowy polipropylenowej. Wraz ze zwięk…

poliedryczne oligomeryczne silseskwioksany (POSS)Materials sciencePolymers and PlasticsGeneral Chemical Engineering02 engineering and technology010402 general chemistry01 natural sciencesDegree (temperature)chemistry.chemical_compoundCrystallinitymass flow ratenanocompositesMaterials ChemistryMass flow rateComposite materialnanokompozytyPolypropyleneNanocompositepositron annihilation lifetime spectroscopy (PALS)masowy wskaźnik szybkości płynięciacrystallinity degreestopień krystaliczności021001 nanoscience & nanotechnologySilsesquioxane0104 chemical scienceschemistryspektroskopia czasów życia pozytonów (PALS)polipropylen0210 nano-technologypolypropylenepolyhedral oligomeric silsesquioxanes (POSS)Polimery
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Nanocomposites with polyhedral oligomeric silesquioxane nanofillers - characterization of morphology, thermal and mechanical properties

2016

High-density polyethylene nanocomposites with hydroxy-hepta(iso-butyl)-octasilsesquioxane (POSS-(i-Bu)7OH) and hydroxy-hepta(iso-octyl)-octasilsesquioxane (POSS-(i-Oct)7OH) as nanofillers were prepared by melt blending. The morphological, thermal and mechanical properties as well as processability of obtained nanocomposites were characterized. POSS nanofillers were homogenously dispersed in polymeric matrix. High compatibility between nanofiller and polymer induced enhanced thermal stability, Charpy impact strength and melt flow rate for composite materials. POSS particles acted also as a nucleating agent for polyethylene crystallization in the nanocomposite.

polyethylenesilsesquioxanesnanocompositesActa Innovations
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