Search results for "small-angle"
showing 10 items of 258 documents
A new method for data evaluation of small angle neutron scattering experiments and its application to amorphous polycarbonate
1981
The conformation of single chains in bulk polymer materials can be evaluated from coherent neutron scattering on mixtures of normal and deuterated polymers. It is shown that the single-chain structure factor can be also obtained from measurements of highly concentrated mixtures and the procedure of evaluation is described. The application to amorphous polycarbonate demonstrates the advantages of the method.
A synchrotron radiation X-ray scattering study of aqueous solutions of native DNA
1999
Synchrotron radiation small-angle X-ray scattering (SAXS) was used to investigate solutions of native DNA at different ionic strengths and temperatures. The mass per unit length, radius of gyration of the cross-section of DNA and apparent second virial coefficient (A2) were obtained from Zimm plots in the rodlike particle approximation. The values of A2 obtained in this way are positive and almost constant indicating that the repulsive interactions still influence the scattering patterns at resolutions as high as 5-8 nm. SAXS measurements in continuous temperature scans indicate that the rod approximation is valid over a wide temperature range during DNA melting and confirm that the rodlike…
Advances in contrast variation for macromolecular structure determination by polarized neutron scattering and anomalous dispersion of synchrotron X-r…
1988
Contrast variation for macromolecular structure determination is usually achieved by isomorphous replacement of 1-H by 2-H (D) using small-angle neutron scattering (SANS). This is particularly easy in aqueous solvents. By adding heavy water the contrast of dissolved proteins, nucleic acids and membranes changes drastically. It is the region inaccesible to solvent molecules, which acts as a label. Measurements of the scattering intensity at three different scattering densities of a solvent yields the three basic scattering functions. The contrast dependence of the radius of gyration receives particular interest. More recently smaller labels have been used. Their dimensions are smaller than t…
Light transport in hetero-opal photonic crystals
2005
The effect of photonic bandgap interface upon the light scattering was studied in hetero-opals consisting of two opal thin films with different lattice constant. It is shown that the weak scattering regime is preserved in thin hetero-opal films. By comparing scattering spectra of single and hetero-opal films recorded under reversing angles of light incidence and detection it was demonstrated that the interface scatters stronger the light at oblique incident angles. Squeezing of the scattering diagram of hetero-opals compared to single opal films is also assigned to the interface scattering.
Second-order Raman scattering in CuO
2013
Polarized second-order Raman scattering spectra of CuO single crystals are reported. It is shown that for some scattering geometries the second-order processes dominate the inelastic light scattering spectra. Group-theoretical symmetry analysis of the selection rules for the first- and second-order scattering processes is performed and phonon dispersion relations are calculated within density functional theory. The main spectral features of the two-phonon spectra are assigned to overtones of the vibrational branches at various special points across the Brillouin zone.
Neutron scattering and crystal fields in Pr-hydrides
1978
The crystal field splittings of PrD2 and PrD2.5 have been determined by inelastic neutron scattering. While for PrD2 the crystal field experienced by the majority of Pr-ions is cubic, it is shown that in PrD2.5 the occupation of the octahedral interstitials occurs not in a statistical but rather in a well defined way which leads to an orthorhombic crystal field at the Pr-site.
Experimental studies of the liquid-glass transition in trimethylheptane
2000
The molecular glass former trimethylheptane was studied by calorimetric, dielectric, ultrasonic, neutron scattering, Brillouin scattering, and depolarized light-scattering techniques. The molecular structure appears to be nearly spherical optically as indicated by the low depolarization ratio and dielectric susceptibility values. A preliminary mode-coupling theory (MCT) analysis of the light-scattering and neutron-scattering data indicates that ${T}_{C}\ensuremath{\gtrsim}150 \mathrm{K},$ at least 25 K above ${T}_{G}.$ The susceptibility minima were analyzed with the MCT interpolation equation, and disagreement between the light and neutron results was observed despite the apparent isotropy…
Studies of structure and dynamics of solid polymers by elastic and inelastic neutron scattering
1978
Abstract Neutron scattering methods can be applied to solid polymers in order to investigate the structure of the bulk material as well as the nature of the molecular motion. A review of some recently performed studies is presented. Diffusional motion in crystals of chain molecules has been studied by means of quasielastic scattering for the case of n-C33H68 as an example for the relationship between structure and molecular motion. It can be shown that below the so-called rotational transition the paraffin crystals exhibit two types of molecular motion: a translational jump (τt = 0.5 10-8s) and a 180°-rotational jump (τr = 2.5 10-8s). The low frequency vibrations in n-alkanes as models of p…
Structure development in poly(ethylene terephthalate) quenched from the melt at high cooling rates: X-ray scattering and microhardness study
2000
The structure and microhardness of poly(ethylene terephthalate) (PET) cooled from the melt, using a wide range of cooling rates, was studied. PET thin films rapidly cooled from the melt (cooling rates larger than 5°C/s) show a continuous variation of structure and properties depending on cooling rate. Results highlight differences in the micro-mechanical properties of the glass suggesting the occurrence of amorphous structures with different degrees of internal chain ordering. The comparative X-ray scattering study of two glassy PET samples (7500 and 17°C/s) reveals the occurrence of frozen-in electron density states giving rise to an excess of scattering for the amorphous sample solidified…
Raman Scattering Applied to Materials Science
2015
Abstract One of the most powerful techniques to extract physical and chemical information of a material is the light scattering. Opposite to x-ray scattering for instance, where an average of the sample properties is obtained, Raman scattering is a local probe which can be used to detect inhomogeneities, local strain, lack of crystallinity, anharmonicities or information on the electronic structure by means of resonant Raman scattering. In this work, we will analyze the main contributions of Raman scattering in Materials Sciences. After a brief introduction of the technique and the equipment needed for the physical measurements, we will give practical examples of Raman scattering measuremen…