Search results for "solution"
showing 10 items of 5638 documents
Cloud detection for CHRIS/Proba hyperspectral images
2005
Accurate and automatic detection of clouds in satellite scenes is a key issue for a wide range of remote sensing applications. With no accurate cloud masking, undetected clouds are one of the most significant source of error in both sea and land cover biophysical parameter retrieval. Sensors with spectral channels beyond 1 um have demonstrated good capabilities to perform cloud masking. This spectral range can not be exploited by recently developed hyperspectral sensors that work in the spectral range between 400- 1000 nm. However, one can take advantage of their high number of channels and spectral resolution to increase the cloud detection accuracy, and to describe properly the detected c…
Studies of CoxMg1-xO Solid Solutions Using Laboratory EXAFS-Spectrometer
1993
Studies of the local electronic structure and the short-range order in solid solutions Co x Mg1-x O with x equal from 0.02 to 1.00 have been carried out on the Co K-edge X-ray absorption spectra measured using the laboratory EXAFS-spectrometer. A non-monotonous change of the Co-O distance in the first coordination shell with the bent at x=0.5 has been established. The second coordination shell of cobalt has been formed by cobalt and magnesium atoms with a distribution close to statistical.
The Fluorescence Explorer (FLEX) Mission: From Spectral Measurements to High-Level Science Products
2021
The Fluorescence Explorer (FLEX) mission was selected in 2015, by the European Space Agency (ESA), as an Earth Explorer mission, with a launch planned for 2024. The key scientific objective of the mission is the quantitative global mapping of actual photosynthetic activity of terrestrial ecosystems, as a function of variable vegetation health status and environmental stress conditions. The measurements will have a spatial resolution of 300 m, adequate to resolve land surface processes associated to vegetation dynamics at a global scale. To be able to accomplish such objective, the FLEX mission carries the FLORIS spectrometer, specially optimized to map vegetation fluorescence with a spectra…
Coupled retrieval of aerosol optical thickness, columnar water vapor and surface reflectance maps from ENVISAT/MERIS data over land
2008
An algorithm for the derivation of atmospheric parameters and surface reflectance data from MEdium Resolution Imaging Specrometer Instrument (MERIS) on board ENVIronmental SATellite (ENVISAT) images has been developed. Geo-rectified aerosol optical thickness (AOT), columnar water vapor (CWV) and spectral surface reflectance maps are generated from MERIS Level-1b data over land. The algorithm has been implemented so that AOT, CWV and reflectance products are provided on an operational manner, making no use of ancillary parameters apart from those attached to MERIS products. For this reason, it has been named Self-Contained Atmospheric Parameters Estimation from MERIS data (SCAPE-M). The fund…
Spectral calibration and atmospheric correction of ultra-fine spectral and spatial resolution remote sensing data. Application to CASI-1500 data
2007
Imaging spectrometers operating in the solar spectrum measure the upwelling reflected solar radiation, and are an important tool in the bio/geochemical characterization of the Earth system. Surface reflectance is usually the starting point for the retrieval of biophysical parameters from remote measurements. Reliable radiometric and spectral calibrations and accurate atmospheric correction are mandatory in the interpretation of the surface reflectance. A complete surface reflectance retrieval scheme specifically designed for ultra-fine spectral resolution (bandwidth from 10 to 2 nm) and spatial resolution (pixel size less than 10 m) imaging spectrometers is presented in this work. The asses…
Reduction of Convective Low-Frequency Noise in Thermal Lens Spectrometry
1990
The construction and optimization of a thermal lens spectrometer with coaxial pump/probe configuration is reported. The low-frequency noise of convective origin is studied in detail, and it is demonstrated that a horizontal slit, instead of a pinhole, can be used as a simple way of reducing the noise to a negligible level without losing sensitivity.
Direct infusion mass spectrometry as a fingerprint of protein-binding media used in works of art
2005
A direct infusion mass spectrometry method for the characterization of proteinaceous glues from binding media used in pictorial works of art prior to conservation or restoration treatment is proposed. Amino acids are released by acid hydrolysis and dissolved in a mixture of acidic water and ethanol. This mixture is directly infused into a mass spectrometer without any derivatization. The mass spectrometer is operated in positive ion electrospray mode (ESI-MS) to yield [M+H]+ ions for the amino acids. Relative amounts of each amino acid are calculated for each protein (beef and porcine gelatines, albumin, casein and egg). The analyzed proteins were satisfactorily distinguished. The method is…
Synthesis, Characterization, and Saccharide Binding Studies of Bile Acid − Porphyrin Conjugates
2007
Synthesis and characterization of bile acid-porphyrin conjugates (BAPs) are reported. Binding of saccharides with BAPs in aqueous methanol was studied by monitoring changes in the visible absorption spectral of the porphyrin-moieties. Although these studies clearly showed absorbance changes, suggesting quite high if non-selective binding, the mass spectral studies do not unambiguously support these results.
Surfactant self-assembly in the gas phase: Bis(2-ethylhexyl)sulfosuccinate- alkaline metal ion aggregates
2008
Molecular dynamics (MD) simulations were conducted for systems in vacuo consisting of n AOT anions (bis(2-ethylhexyl)sulfosuccinate ions) and n 1 or n Na+ ions up to n = 20. For n = 15, positively charged systems with Li+, K+, and Cs+ cations were also considered. All systems were observed to form reverse micelle-like aggregates whose centre is occupied by cations and polar heads in a very compact solid-like way, while globally the aggregate has the form of an elongated and rather flat ellipsoid. Various types of statistical analyses were carried out on the systems to enlighten structural and dynamical properties including gyration radius, atomic pair correlation functions, atomic B-factor …
Host−Guest Interactions between β-Cyclodextrin and the (Z)-Phenylhydrazone of 3-Benzoyl-5-phenyl-1,2,4-oxadiazole: The First Kinetic Study of a Ring…
2002
The effect of beta-cyclodextrin (beta-CD) on the mononuclear heterocyclic rearrangement of the (Z)-phenylhydrazone of 3-benzoyl-5-phenyl-1,2,4-oxadiazole (1) in aqueous borate buffer at pH = 9.6 has been analyzed at temperatures ranging from 293.15 to 313.15 K. The trend of the absorption spectra of 1 as a function of time has been accounted for with the formation of two different 1:1 complexes between beta-CD and 1, the first, "unreactive" complex being formed faster than the "reactive" one. The occurrence of negative activation enthalpy values for the studied interconversion evidences the kinetic relevance of inclusion processes. Computational models elaborated using the MM2 molecular mec…