Search results for "supercapacitor"
showing 10 items of 59 documents
Polyoxometalate-based metal-organic frameworks for boosting electrochemical capacitor performance
2019
Abstract Polyoxometalate-based metal-organic frameworks (POMOFs) possess promising applications as capacitors. Herein, we report the syntheses, structures and electrochemical properties of five copper-containing POMOFs: [CuI4H2(btx)5(PW12O40)2]·2H2O (1), [CuIICuI3(H2O)2(btx)5(PWVI10WV2O40)]·2H2O (2), [CuI6(btx)6(PWVI9WV3O40)]·2H2O (3), [CuI4H2(btx)5(PMo12O40)2]·2H2O (4) and [CuIICuI3(btx)5(SiMoVI11MoVO40)]·4H2O (5) (btx = 1,4-bis(triazol-1-ylmethyl) benzene) with potential applications as capacitors. Compounds 1–3 contain the same Keggin-type polyoxometalate (POM) although with different oxidation states, allowing the analysis of the effect of the electronic population on the capacitance pe…
Wood and Black Liquor-Based N-Doped Activated Carbon for Energy Application
2021
The research was funded by the Latvian Council of Science project “Nanostructured Nitrogenated Carbon Materials as Promoters in Energy Harvesting and Storage Technologies”, project No LZP-2018/1-0194, “New biomass origin materials hybrid carbon composites for energy storage” project No LZP-2020/2-0019 and postdoc project “Nitrogen and phosphorus-containing biomass based activated carbons for fuel cells and supercapacitors” project No 1.1.1.2/VIAA/4/20/596.
Giant Enhancement in the Supercapacitance of NiFe–Graphene Nanocomposites Induced by a Magnetic Field
2019
The rapid rise in energy demand in the past years has prompted a search for low-cost alternatives for energy storage, supercapacitors being one of the most important devices. It is shown that a dramatic enhancement (≈1100%, from 155 to 1850 F g-1 ) of the specific capacitance of a hybrid stimuli-responsive FeNi3 -graphene electrode material can be achieved when the charge/discharge cycling is performed in the presence of an applied magnetic field of 4000 G. This result is related to an unprecedented magnetic-field-induced metal segregation of the FeNi3 nanoparticles during the cycling, which results in the appearance of small Ni clusters (<5 nm) and, consequently, in an increase in pseudoca…
Modelling, Simulation and Characterization of a Supercapacitor in Automotive Applications
2022
In the energy storage field, supercapacitors (SCs) are gaining more and more attention thanks to features such as high-power density, high life cycles and lack of maintenance. In this article, an improved SC three-branches model which considers the residual charge phenomenon is presented. The procedure to estimate the model parameters and the related experimental set-up are presented. The parameter estimation procedure is repeated for several SCs of the same type. The average parameters are then obtained and used as initial guesses for a recursive least square optimization algorithm, to increase the accuracy of the model. The model of a single SC is then extended to SC banks, testing differ…
Activated Cashew Carbon-Manganese Oxide Based Electrodes for Supercapacitor Applications
2023
The current global energy challenge which affects most developing countries in particular, is of major source of concern today. The availability of less expensive techniques of storing excess generated energy is critical to the success of the renewable energy roadmaps implementation. In this study, hydrothermal and chemical leaching methods have been used to synthesize MnO2 nanoparticles using KMnO4 and MnSO4 as precursors at 140 °C and from natural local manganese ore. Activated Carbon (ACF) have also been produced from agricultural Cashew biomass waste, through a physical carbonization and KOH activation process using temperatures of 700 °C – 900 °C for periods between 1-2 hours. The as-p…
Electrochemically Controlled Ion Dynamics in Porphyrin Nanostructures
2020
peer-reviewed The full text of this article will not be available in ULIR until the embargo expires on the 22/07/2021 The dynamics of ion intercalation into solid matrices influences the performance of key components in most energy storage devices (Li-ion batteries, supercapacitors, fuel cells, etc.). Electrochemical methods provide key information on the thermodynamics and kinetics of these ion-transfer processes but are restricted to matrices supported on electronically conductive substrates. In this article, the electrified liquid|liquid interface is introduced as an ideal platform to probe the thermodynamics and kinetics of reversible ion intercalation with nonelectronically active matr…
Photoswitchable Micro-Supercapacitor Based on a Diarylethene-Graphene Composite Film
2017
Stimuli-responsive micro-supercapacitors (MSCs) controlled by external stimuli can enable a wide range of applications for future on-chip energy storage. Here, we report on a photoswitchable MSC based on a diarylethene-graphene composite film. The microdevice delivers an outstanding and reversible capacitance modulation of up to 20%, demonstrating a prototype photoswitchable MSC. Terahertz spectroscopy indicates that the photoswitching of the capacitance is enabled by the reversible tuning of interfacial charge injection into diarylethene molecular orbitals, as a consequence of charge transfer at the diarylethene-graphene interface upon light modulation.
Optimal Integration of Hybrid Supercapacitor and IPT System for a Free-Catenary Tramway
2019
The aim of the paper is the study of an optimal integration of a supercapacitor-based storage system and inductive power transfer system for the free-catenary operation of a tramway. Starting from the definition of the topology of inductive power transfer system, we propose and analyze a design procedure for the pads of the inductive power system. In the second part of the paper, an optimal integration strategy for the correct size of on-board supercapacitors and the power of the inductive energy transfer are proposed. The results obtained by means of numerical simulations are discussed. © 2018 IEEE.
Hybrid magnetic materials based on layered double hydroxides: from the chemistry towards the applications
2014
Layered double hydroxides (LDHs) are the leitmotiv of this dissertation. Contradicting the assertion that “any past was better”, LDHs have been continuously revisited from the middle of the twentieth century, and represent an excellent example of the never-ending beauty of Chemistry. New synthetic perspectives are giving a new impetus to LDH chemistry, which among hybrid materials, are finding their heyday. This is resulting in novel materials and also paving the way for new fundamental and practical insights. This dissertation is focused on magnetic LDHs, and for the sake of clarity it is organized in three main parts: we will move from basic synthetic and physical aspects of LDHs, through…
Design of a Battery/Ultracapacitor Energy Storage System for Electric Vehicle Applications
2018
The battery/ultracapacitors (UCs) integration is able to provide notable advantages in the power management of an electric vehicle (EV), in terms of capability of both high energy storage and readiness to deal with fast load variations. In order to manage the charge (or discharge) of the UCs from (or towards) a DC voltage bus, a proper bi-directional converter is required. In this paper, a bi-directional DC-DC converter in connection with a stack of UCs is described and some power simulation results are provided. The proposed converter is a B2R (buck-boost regulator) type. The load is represented by a 40kW peak power, kept for a time window of 3s, as required by the Worldwide harmonized Lig…