Search results for "supporting"
showing 10 items of 82 documents
Electrochemical impedance spectroscopy of polyelectrolyte multilayer modified gold electrodes: influence of supporting electrolyte and temperature.
2005
Electrochemical impedance spectroscopy and cyclic voltammetry are employed to characterize poly(styrenesulfonate)/poly(allylamine hydrochloride) multilayers assembled onto cysteamine-modified gold surfaces. The influence of the supporting electrolyte and temperature on the impedance response is studied because of both its practical interest and the need to test further the capillary membrane model recently developed by Barreira et al. [J. Phys. Chem. B 2004, 108, 17973]. The results obtained are interpreted quite satisfactorily in terms of this model, thus providing additional support to its usefulness for the description of ionic transport through polyelectrolyte multilayers. It is observe…
Electrochemical reduction of carbon dioxide to formic acid at a tin cathode in divided and undivided cells: effect of carbon dioxide pressure and oth…
2016
Abstract The reduction of carbon dioxide to formic acid at a tin cathode was studied in both divided and undivided cells. In the first stage of the study, the effect of some operating parameters, including the working potential and the nature of the supporting electrolyte and of the cathode, on both the cathodic reduction of CO2 and the anodic oxidation of formic acid was investigated in a divided cell. In a second stage, the reduction of carbon dioxide was performed in an undivided cell with the aim of studying the effect on the generation of formic acid of various operating parameters such as current density, cathode to anode area ratio, mixing rate and nature of the anode and of the supp…
Ion transport through polyelectrolyte multilayers under steady-state conditions
2004
Abstract The permeability of a self-assembled polyelectrolyte multilayer to small ions under the influence of an applied potential difference is studied as a function of the number of layers and the nature of the supporting electrolyte. The multilayer is described as a series of homogeneously charged membranes with alternating sign of their fixed charge. Ion transport is described on the basis of the diffusion equation and the assumption of (Donnan) electrochemical equilibrium at the boundaries between layers. The calculated steady-state current–voltage curves are found to be in good agreement with experimental linear sweep voltammograms (at low sweep rate). The permeability of polystyrenes…
Pannello precompresso di vetromattoni assemblati a secco per la realizzazione di involucri traslucidi
2012
L’invenzione riguarda la realizzazione di un pannello di vetromattoni montati “a secco” -da impiegare per la realizzazione di involucri edilizi traslucidi anche nel caso di edifici alti- che è in grado di rispondere adeguatamente alle sollecitazioni orizzontali (quali quelle dovute a vento e sisma) grazie all’applicazione della tecnica della precompressione mondirezionale. Per offrire una risposta ai limiti imposti dalla tecnica di assemblaggio tradizionale dei vetromattoni (“ad umido”), l’applicazione della precompressione consente, infatti, di dare ai pannelli preassemblati “a secco” una rigidezza adeguata anche in direzione normale al loro piano di posa, sfruttando le buone caratteristic…
SIMHE-ohjaus moninaisten koulutus- ja urapolkujen tukena
2021
Electrochemical and Spectroelectrochemical Properties of Free-Base Pyridyl- and N -Alkyl-4-Pyridylporphyrins in Nonaqueous Media
2015
International audience; Twelve structurally related pyridyl and meso-N-methylpyridylporphyrin derivatives are investigated electrochemically in different nonaqueous media. The UV/Vis spectrum of each newly investigated porphyrin was measured before and after electro-reduction and, based on this data, the site of electron transfer is proposed. An interaction occurs between the meso-pyridyl or meso-N-alkyl-4-pyridyl substituents and the porphyrin p-ring system, the magnitude of which depends upon the number of linked pyridyl or N-alkyl-4-pyridyl groups in the compound, the solvent, the supporting electrolyte, and/or other anions added to the solution.
Die aufschlußfreie Bestimmung von Schwermetallen (Zn, Cd, Pb, Cu) in Getränken (Wein) durch inverse Voltammetrie in einer Durchflußzelle
1987
Digestion-free determination of trace-metals (Zn, Cd, Pb, Cu) in beverages by inverse voltammetry in a flow-through cell equipped with a mercury film-electrode is described. Optimal enrichment potentials are obtained by inspection of the pseudopolarograms of the elements in the original diluted sample solution. After the deposition step in the untreated sample solution stripping is effected in a proper supporting electrolyte after medium exchange. Values obtained by this techniques with various samples compare well with those obtained by usual procedures including wet digestion of the samples.
Synthesis of cyanoacetic acid by carbon dioxide and electrogenerated acetonitrile anion in undivided cells equipped with sacrificial anodes
2008
The electrochemical synthesis of cyanoacetic acid was performed by cathodic reduction of tetraalkylammonium salts (R4NX) in acetonitrile in undivided cells equipped with sacrificial anodes with concomitant or subsequent addition of carbon dioxide. These syntheses avoid the use of dangerous reagents, yield cyanoacetic acid in moderate faradic yields and confirm that the cathodic reduction of tetraalkylammonium salts in the presence of acetonitrile leads to the formation of the anion CNCH2-.
Electrochemical technology for the treatment of real washing machine effluent at pre-pilot plant scale by using active and non-active anodes
2018
Abstract Real effluent of washing machine is one of the major sources of microplastics and fabrics in municipal and surface water. The effluents constitute large volume of wastewater with different surfactants since every household and industries nowadays use washing machine rather than traditional hand washing. In this work, a real effluent of washing machine was treated by electrooxidation (EO) in a pre-pilot plant scale electrochemical flow reactor using active (Ti/Pt) or non-active (boron doped diamond (BDD)) anodes and Ti cathode. The effect of anode material (Ti/Pt or BDD) and the applied current density (16.6, 33.3 and 66.6 mA cm−2) on the decay of the organic matter, in terms of che…
Electrochemical synthesis of sulfamides.
2021
Herein we demonstrate the first electrochemical synthesis protocol of symmetrical sulfamides directly from anilines and SO2 mediated by iodide. Sulfamides are an emerging functional group in drug design. Highlights are the direct use of SO2 from a stock solution and no necessity of any supporting electrolyte. Overall, the reaction has been demonstrated for 15 examples with yields up to 93%.