Search results for "synchrotron"

showing 10 items of 307 documents

Average versus local structure in K2NiF4-type LaSrAlO4: direct experimental evidence of local cationic ordering

2012

The long-range ordering of a crystalline material can be accurately determined by analyzing the Bragg intensities and positions. In contrast, direct observation of short-range ordering in crystalline materials, which is increasingly considered of fundamental importance to unravel the structure-property relationships that underpin their technological applications, is a challenging task. In this study we have investigated the structure of LaSrAlO4, a representative example of compounds with the K2NiF4-type structure. By the combined use of synchrotron and neutron diffraction, pair distribution function analysis, Al-27 MQMAS NMR and atomistic simulations we have highlighted differences between…

ChemistryNeutron diffractionCationic polymerizationStructure (category theory)Pair distribution function02 engineering and technologyGeneral Chemistry[CHIM.MATE]Chemical Sciences/Material chemistryType (model theory)010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesLocal structureSynchrotron0104 chemical scienceslaw.inventionCrystallographylawChemical physicsK2NiF4 neutron diffraction 27Al MAS NMR quadrupolar interaction local structureMaterials ChemistryRange (statistics)Local structure NMR0210 nano-technologyComputingMilieux_MISCELLANEOUS
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Nanoelectron spectroscopy for chemical analysis: a novel energy filter for imaging x-ray photoemission spectroscopy

2005

An ovel instrument for imaging ESCA is described. It is based on a tandem arrangement of two hemispherical energy analysers used as an imaging energy filter. The main spherical aberration (α 2 -term) of the analyser is corrected by the antisymmetry of the tandem configuration. The kinetic energy range useable for imaging extends up to 1.6 keV; this is compatible with Mg and Al Kα laboratory x-ray sources. First experiments on the chemical surface composition of a Cu0.98Bi0.02 polycrystal, a GaAs/AlGaAs heterostructure and Ag crystallites on Si(111) have been performed using synchrotron radiation. The results reveal an energy resolutio no f190 meV and a lateral resolution (edge resolution) o…

Chemistrybusiness.industryAnalyserBremsstrahlungAnalytical chemistrySynchrotron radiationCondensed Matter PhysicsKinetic energyElectron spectroscopySpherical aberrationOpticsX-ray photoelectron spectroscopyGeneral Materials ScienceSpectroscopybusinessJournal of Physics: Condensed Matter
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Time-of-flight photoemission electron microscopy – a new way to chemical surface analysis

2001

Abstract The time structure of synchrotron radiation at BESSY I (Berlin) was utilised to operate a photoemission electron microscope in the time-of-flight mode. The electrons that are emitted from the sample surface with different energies are dispersed in a drift tube subsequent to the imaging optics. Two ways of fast image detection have been explored, a fast gated intensified CCD camera (800 ps gate time) and a special counting electronics in combination with a 3D (x,y,t)-resolving delay line detector ( time resolution ps). The latter device has a lateral resolution of about 50 μm in the image plane being equivalent to 1000 pixels along the image diagonal. An energy resolution of 400 meV…

Chemistrybusiness.industryInverse photoemission spectroscopyResolution (electron density)Synchrotron radiationSurfaces and InterfacesElectronImage planeCondensed Matter PhysicsSurfaces Coatings and FilmsPhotoemission electron microscopyTime of flightOpticsMaterials ChemistryImage sensorbusinessSurface Science
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Fe 2p photoemission magnetic dichroism with linearly polarized synchrotron radiation and with unpolarized A1 Kα radiation

1997

We report on the measurements and analysis of Fe 2p magnetic dichroism in the angular distribution of the photoelectrons from remanently magnetized Fe(100)surfaces with unpolarized, monochromatized A1 Kα X-rays of 1486 eV energy (MDAD)and with linearly polarized synchrotron radiation of energy 800 eV (LMDAD). The two experiments verify the atomic photoionization model of (L)MDAD including the dichroism effect between field-averaged experiments of different chirality.

Chemistrybusiness.industryLinear polarizationSynchrotron radiationSurfaces and InterfacesPhotoionizationPhotoelectric effectRadiationDichroismCondensed Matter PhysicsSurfaces Coatings and FilmsOpticsX-ray photoelectron spectroscopyMaterials ChemistryAtomic physicsbusinessChirality (chemistry)Surface Science
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SHOCK-CLOUD INTERACTION AND PARTICLE ACCELERATION IN THE SOUTHWESTERN LIMB OF SN 1006

2014

The supernova remnant SN 1006 is a powerful source of high-energy particles and evolves in a relatively tenuous and uniform environment despite interacting with an atomic cloud in its northwestern limb. The X-ray image of SN 1006 reveals an indentation in the southwestern part of the shock front and the H I maps show an isolated (southwestern) cloud, having the same velocity as the northwestern cloud, whose morphology fits perfectly in the indentation. We performed spatially resolved spectral analysis of a set of small regions in the southwestern nonthermal limb and studied the deep X-ray spectra obtained within the XMM-Newton SN 1006 Large Program. We also analyzed archive H I data, obtain…

Ciencias FísicasAstrophysics::High Energy Astrophysical PhenomenaHadronSynchrotron radiationAstrophysicsSpectral lineISM: cloudIndentationSupernova remnantISM: individual objects (SN 1006)acceleration of particleISM: supernova remnantAstrophysics::Galaxy Astrophysicsacceleration of particlesPhysicssupernova remnants X-rays: ISM [ISM]Astronomy and AstrophysicsX-rays: ISMShock (mechanics)Particle accelerationAstronomíaSpace and Planetary Scienceindividual objects: SN 1006 [ISM]clouds [ISM]CIENCIAS NATURALES Y EXACTASFermi Gamma-ray Space Telescope
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Blue luminescence in ZnO single crystals, nanopowders, ceramic

2007

The luminescence spectra and luminescence decay processes were studied in a ZnO single crystal, nanopowders and ceramic at liquid helium and room temperature under VUV synchrotron radiation as well as under pulsed laser excitation. The exciton-exciton and exciton-multiphonon processes were compared in different ZnO nanopowders (commercial powder, powders obtained by vaporization-condensation technique) and ceramic. The possibility of luminescence decay time modification by Al3+ doping was shown.

Condensed Matter::Quantum GasesHistoryMaterials scienceCondensed Matter::Otherbusiness.industryLiquid heliumDopingSynchrotron radiationLuminescence spectraComputer Science ApplicationsEducationlaw.inventionCondensed Matter::Materials SciencelawCondensed Matter::Superconductivityvisual_artPhysics::Atomic and Molecular Clustersvisual_art.visual_art_mediumOptoelectronicsddc:530CeramicLuminescencebusinessSingle crystalExcitationJournal of Physics: Conference Series
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Non-circular rotating beams and CMB experiments

2002

This paper is concerned with small angular scale experiments for the observation of cosmic microwave background anisotropies. In the absence of beam, the effects of partial coverage and pixelisation are disentangled and analyzed (using simulations). Then, appropriate maps involving the CMB signal plus the synchrotron and dust emissions from the Milky Way are simulated, and an asymmetric beam --which turns following different strategies-- is used to smooth the simulated maps. An associated circular beam is defined to estimate the deviations in the angular power spectrum produced by beam asymmetry without rotation and, afterwards, the deviations due to beam rotation are calculated. For a cert…

Cosmic microwave background ; Cosmology theory ; Large-scale structure of the universe ; Numerical method ; Data analysis methodmedia_common.quotation_subjectCosmic microwave backgroundFOS: Physical sciencesAstrophysicsNumerical methodUNESCO::ASTRONOMÍA Y ASTROFÍSICAAstrophysicsRotationAsymmetryCosmic microwave backgroundlaw.inventionsymbols.namesakelawCosmology theoryLarge-scale structure of the universePlanckAnisotropymedia_commonPhysicsData analysis methodAstrophysics (astro-ph)Spectral densityAstronomy and Astrophysics:ASTRONOMÍA Y ASTROFÍSICA::Cosmología y cosmogonia [UNESCO]SynchrotronComputational physicsSpace and Planetary SciencesymbolsUNESCO::ASTRONOMÍA Y ASTROFÍSICA::Cosmología y cosmogonia:ASTRONOMÍA Y ASTROFÍSICA [UNESCO]Beam (structure)Astronomy & Astrophysics
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Radio data and synchrotron emission in consistent cosmic ray models

2011

It is well established that phenomenological two-zone diffusion models of the galactic halo can very well reproduce cosmic-ray nuclear data and the observed antiproton flux. Here, we consider lepton propagation in such models and compute the expected galactic population of electrons, as well as the diffuse synchrotron emission that results from their interaction with galactic magnetic fields. We find models in agreement not only with cosmic ray data but also with radio surveys at essentially all frequencies. Requiring such a globally consistent description strongly disfavors very large ($L\gtrsim 15$ kpc) and, even stronger, small ($L\lesssim 1$ kpc) effective diffusive halo sizes. This has…

Cosmology and Nongalactic Astrophysics (astro-ph.CO)Astrophysics::High Energy Astrophysical PhenomenaPopulationDark matterFOS: Physical sciencesSynchrotron radiationCosmic rayAstrophysics::Cosmology and Extragalactic AstrophysicsAstrophysics01 natural sciencesGalactic haloHigh Energy Physics - Phenomenology (hep-ph)0103 physical scienceseducation010303 astronomy & astrophysicsAstrophysics::Galaxy AstrophysicsPhysicseducation.field_of_studydark matter theorycosmic ray theory; dark matter theory010308 nuclear & particles physicsAstronomy and Astrophysicscosmic ray theoryAstrophysics - Astrophysics of GalaxiesHigh Energy Physics - PhenomenologyAntiprotonAstrophysics of Galaxies (astro-ph.GA)HaloAstrophysics - Cosmology and Nongalactic AstrophysicsRadio waveJournal of Cosmology and Astroparticle Physics
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Synchrotron Radiation-Based Micro-XANES and Micro-XRF Study of Unsuccessfully Produced Egyptian Blue from the Late Hellenistic Production Site of Kos…

2021

International audience; This paper examines the production technology of Egyptian blue, an ancient artificial pigment, through the investigation of an unsuccessfully produced pellet derived from the Hellenistic production site of Kos (Dodecanese, Greece). This heterogeneous material was investigated by a combination of laboratory and synchrotron radiation-based (SR) techniques: scanning electron microscopy coupled with energy-dispersive Xray spectrometry, micro-Raman spectroscopy, high-resolution SR micro-X-ray fluorescence spectroscopy, and SR micro-X-ray absorption near-edge structure spectroscopy (XANES), at the ID21 beamline of the European Synchrotron Radiation Facility. Principal comp…

CupriteAbsorption spectroscopyMineralogySynchrotron radiationLarge dataset01 natural sciencesFluorescence spectroscopyArticleAnalytical ChemistrySynchrotronEgyptian bluechemistry.chemical_compoundAbsorption spectroscopy0601 history and archaeology[SDV.BBM]Life Sciences [q-bio]/Biochemistry Molecular BiologyCopper oxideSpectroscopyFluorescence spectroscopyX ray absorption060102 archaeologyGreeceChemistryX ray absorption near edge structure spectroscopyOxide mineralSilicates010401 analytical chemistry06 humanities and the artsXANES0104 chemical sciencesX-Ray Absorption SpectroscopyBeamlinevisual_artvisual_art.visual_art_mediumScanning electron microscopyCopperSynchrotrons
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Monolayer Formation of Molybdenum Carbonyl on Cu(111) Revealed by Scanning Tunneling Microscopy and Density Functional Theory

2012

International audience; Molybdenum carbonyl Mo(CO)(6) was adsorbed on the Cu(111) surface at 160 K in the monolayer coverage range and studied by scanning tunneling microscopy. A well-ordered monolayer of hexacarbonyl molecules was observed experimentally for the first time. The monolayer has a hexagonal structure compatible with a (root 7 x root 7)R19 superlattice on the copper (111) plane. The arrangement and orientation of the molecules on the surface were determined by density functional theory calculations, including van der Waals interactions. The comparison of adsorption and cohesive energies reveals that the molecule-substrate interaction is stronger than the intermolecular one, whi…

DECOMPOSITIONADSORPTIONSuperlatticeAnalytical chemistrychemistry.chemical_element02 engineering and technologyHEXACARBONYL010402 general chemistry01 natural scienceslaw.inventionSYNCHROTRON-RADIATIONsymbols.namesakeAdsorptionlawMonolayerPhysical and Theoretical ChemistryMO(CO)(6)DEPOSITIONSPECTROSCOPYChemistryIntermolecular forceTIO2(110)PHOTODISSOCIATION021001 nanoscience & nanotechnologyMO0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographyGeneral EnergyMolybdenumsymbolsDensity functional theoryScanning tunneling microscopevan der Waals force0210 nano-technology
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