Search results for "ta216"
showing 10 items of 63 documents
Assembly of citrate gold nanoparticles on hydrophilic monolayers
2016
Abstract Self-assembled monolayers (SAMs) as model surfaces were linked onto planar gold films thorough lipoic acid or disulfide groups. The molecules used were polyethylene glycol (EG-S-S), N -[tris-(hydroxymethyl)methyl]acrylamide polymers with and without lipoic acid (Lipa-pTHMMAA and pTHMMAA) and a lipoic acid triazine derivative (Lipa-MF). All the layers, but Lipa-MF with a primary amino group were hydroxyl terminated. The layers were characterized by contact angle measurements and atomic force microscopy, AFM. Citrate stabilized nanoparticles, AuNPs in water and phosphate buffer were allowed to assemble on the layers for 10 min and the binding was followed in real-time with surface pl…
Atomic layer deposition of Ti-Nb-O thin films onto electrospun fibers for fibrous and tubular catalyst support structures
2018
Here, the authors report on the preparation of core-shell carbon-ceramic fibrous as well as ceramic tubular catalyst supports utilizing electrospinning and atomic layer deposition (ALD). In this paper, ALD of Ti-Nb-O thin films using TiCl4, Nb(OEt)5, and H2O as precursors is demonstrated. According to the time-of-flight-elastic recoil detection analysis and Rutherford backscattering spectrometry, carbon and hydrogen impurities were relatively low, but depend on the pulsing ratio of the precursors. Optimized ALD process was used for coating of sacrificial electrospun polyvinyl alcohol (PVA) template fibers to yield tubular Ti-Nb-O structures after thermal or solution based PVA removal. Anoth…
Three-Dimensional Printing of Nonlinear Optical Lenses.
2018
In the current paper, a series of nonlinear optical (NLO) active devices was prepared by utilizing stereolithographic three-dimensional printing technique. Microcrystalline NLO active component, urea, or potassium dihydrogen phosphate was dispersed in a simple photopolymerizable polyacrylate-based resin and used as the printing material to fabricate highly efficient transparent NLO lenses. The nonlinear activity of the printed lenses was confirmed by second-harmonic generation measurements using a femtosecond laser-pumped optical parametric amplifier operating at a wavelength of 1195 nm. The three-dimensional printing provides a simple method to utilize a range of NLO active compounds witho…
Optimization and analysis of processes with moving materials subjected to fatigue fracture and instability
2013
We study systems of traveling continuum modeling the web as a thin elastic plate of brittle material, traveling between a system of supports at a constant velocity, and subjected to bending, in-plane tension and small initial cracks. We study crack growth under cyclic in-plane tension and transverse buckling of the web analytically. We seek optimal in-plane tension that maximizes a performance vector function consisting of the number of cycles before fracture, the critical velocity and process effectiveness. The present way of applying optimization in the studies of fracture and stability is new and affords an analytical tool for process analysis. peerReviewed
Why are hydrogen ions best for MeV ion beam lithography?
2013
The exposure characteristics of poly-(methyl methacrylate) (PMMA) for 2MeV ^1H^+, 3MeV ^4He^2^+ and 6MeV ^1^2C^3^+ have been investigated. The samples were characterised using Atomic Force Microscopy (AFM), optical microscopy and Raman spectroscopy. Development was carried out using a 7:3 propan-2-ol:H"2O mixture to determine clearing and cross-linking fluences. It was found that protons had a considerably wider tolerance to exposure variations and a smaller span of doses within the ion track. Furthermore, the void formation and consequent stress-induced surface roughening were smaller for protons. For all ions, the C?C bond Raman signal increased continuously with dose and fluence, even we…
Properties of AlN grown by plasma enhanced atomic layer deposition
2011
Abstract The influence of growth parameters on the properties of AlN films fabricated by plasma-enhanced atomic layer deposition using trimethylaluminum and ammonia precursors was investigated. The atomic concentrations, refractive index, mass density, crystallinity and surface roughness were studied from the films grown in the temperature range of 100–300 °C with plasma discharge times between 2.5 and 30 s. The AlN films were shown to be hydrogen rich having H concentrations in the range of 13–27 at.% with inverse dependence on the growth temperature. The carbon and oxygen concentrations in the films were less than 2.6% and 0.2%, respectively. The refractive index and mass density of the f…
Solvothermal synthesis derived Co-Ga codoped ZnO diluted magnetic degenerated semiconductor nanocrystals
2018
Authors kindly acknowledge to the Estonian Research Council ( PUT1096 , IUT2-25 , PUT735 ), the Estonian Centre of Excellence in Research project “Advanced materials and high-technology devices for sustainable energetics, sensorics and nanoelectronics (TK141), and the financial support of HZB. We are grateful to the staff of BESSY II for the assistance and co-operation during the synchrotron-based measurements.
Sorption properties of torrefied wood and charcoal
2014
AbstractPre-treating biomass by torrefaction is assumed to improve the material's storage properties because of reducing hydrophilicity. In order to assess the effect of sorption on storage properties, the adsorption of water vapour and capillary absorption of liquid water in torrefied and charred spruce and birch were studied. In addition, the chemical changes were evaluated through Fourier Transform Infrared (FT-IR) spectroscopy. Adsorption decreased notably as severity of treatment increased, as was expected due to degradation of the wood constituents, namely hemicelluloses and amorphous cellulose. Capillary absorption increased with increasing severity in spruce samples while birch show…
Infrared pulsed laser deposition of niobium nitride thin films
2011
We have successfully fabricated superconducting niobium nitride thin films on single crystals of magnesium oxide using a pulsed laser deposition technique where 1064 nm (photon energy ~1.16 eV) laser pulses from an Nd:YAG laser were used for ablation. A correlation between the superconducting transition temperature, the nitrogen base pressure during deposition and the lattice parameter of the produced NbN films was observed. Superconductor-insulator-normal metal junctions fabricated using these NbN films as the superconductor revealed nonlinear electrical characteristics at 4.2 K associated with quasiparticle tunneling.
X-ray micro-tomography based FEM modelling of hygroexpansion in PLA composites reinforced with birch pulp fibres
2017
This article presents a microscale modelling approach coupled with X-ray computed micro-tomography for the evaluation of material properties of polylactic acid (PLA) reinforced by birch pulp fibers under the effect of moisture. The results in terms of elastic moduli and hygroexpansion deformation were found in good agreement with the measurements taken at different levels of water uptake.