Search results for "urea"
showing 10 items of 888 documents
Organocatalytic Asymmetric Synthesis of 2,3′-Connected Bis-Indolinones by Mannich Reactions of N-Acetylindolin-3-ones with Isatin N-Boc Ketimines
2017
A highly diastereo- and enantioselective Mannich reaction of N-acetylindolin-3-ones with isatin N-Boc ketimines to form 2,3′-connected bis-indolinones is developed employing a low loading of a readily available bifunctional thiourea catalyst. The asymmetric synthesis connects two indolinones via a vic-diamine unit and generates two neighboring stereocenters.
Effects of climate change and land use intensification on regional biological soil crust cover and composition in southern Africa
2022
Biological soil crusts (biocrusts) form a regular and relevant feature in drylands, as they stabilize the soil, fix nutrients, and influence water cycling. However, biocrust forming organisms have been shown to be dramatically vulnerable to climate and land use change occurring in these regions. In this study, we used Normalized Difference Vegetation Index (NDVI) data of biocrust-dominated pixels (NDVIbiocrust) obtained from hyperspectral and LANDSAT-7 data to analyse biocrust development over time and to forecast future NDVIbiocrust development under different climate change and livestock density scenarios in southern Africa. We validated these results by analysing the occurrence and compo…
Arable-weed flora and its pollen representation: A case study from the eastern part of France
2007
International audience; Local pollen deposition in human-influenced vegetation types is studied with the aim of establishing the relationship between arable-weed vegetation and its pollen representation as an aid in interpreting human presence and impact on vegetation from pollen assemblages. The study area is located in the Franche-Comté region, eastern part of France. The presence of plants within 100 m2 plots and their pollen representation in moss samples within the same plots was recorded from different crops and annual fallows. Patterns in the vegetation and pollen assemblages were investigated separately using principal coordinate analysis (PCoA). Procrustean co-inertia analysis (PCI…
The problem of misidentification between edible and poisonous wild plants: Reports from the Mediterranean area
2018
Abstract Today, in many European countries, people are looking for wild edible plants to experience new tastes and flavors, by following the new trend of being green and environmentally friendly. Young borage and spinach leaves can be easily confused by inexpert pickers with those of other plants, including poisonous ones, such as Mandragora autumnalis Bertol. (mandrake) or Digitalis purpurea L. (foxglove), common in southern and northern Italy respectively. In the last twenty years, several cases of intoxication by accidental ingestion of mandrake and foxglove have been reported. The purpose of this work was to perform a pharmacognostic characterization of young leaves from borage, mandrak…
Soil legacy determines arbuscular mycorrhizal spore bank and plant performance in the low Arctic
2020
AbstractHuman impact is rapidly changing vegetation globally. The effect of plant cover that no longer exists in a site may still affect the development of future vegetation. We focused on a little studied factor—arbuscular mycorrhizal (AM) fungus spore bank—and its effect on three test plant species. In a low Arctic field site, plots were maintained for 6 years, devoid of any vegetation or with a Solidago virgaurea monoculture cover. We analysed the AM fungal morphospecies composition and identified 21 morphospecies in the field plots. The AM morphospecies community was dominated by members of Acaulosporaceae. Monoculturing under low Arctic field conditions changed the soil AM spore commun…
Types of names of taxa belonging to theCentaurea cinerariagroup (Compositae) described from Sicily
2016
The group of Centaurea (sect. Acrolophus) cineraria (Compositae) in Sicily includes four currently accepted species plus four taxa that have been considered, with some doubt, as subspecies of one of them (C. panormitana). In total, discounting recombinations and replacement names, 11 names (seven specific, three varietal, one of a forma), all based on Sicilian material, were published by past authors for these eight taxa. Two of the names had their holotype indicated upon publication; two have been lectotypified previously; six (C. busambarensis var. obtusiloba, C. cineraria var. soluntina, C. cineraria var. umbrosa, C. todaroi, C. todaroi f. seguenzae and C. ucriae) are lectotypified here;…
Notulae to the Italian native vascular flora: 5
2018
In this contribution, new data concerning the distribution of native vascular flora in Italy are presented. It includes new records and confirmations to the Italian administrative regions for taxa in the genera Allium, Arabis, Campanula, Centaurea, Chaerophyllum, Crocus, Dactylis, Dianthus, Festuca, Galanthus, Helianthemum, Lysimachia, Milium, Pteris, and Quercus. Nomenclature and distribution updates, published elsewhere, and corrections are provided as supplementary material.
Volatile Components from Aerial Parts of Centaurea diffusa and C. micrantha ssp. melanosticta and Their Biocidal Activity on Microorganisms Affecting…
2018
The chemical composition of the essential oils from aerial parts of two taxa of Centaurea belonging to subgenus Acrolophus, Centaurea diffusa Lam. and C. micrantha Hoff. ssp. melanosticta (Lange) Dostàl, respectively collected in Croatia and Spain, were evaluated by GC and GC-MS. The main components of C. diffusa were hexadecanoic acid (31.1%), ( Z,Z)-9,12-octadecadienoic acid (10.7%) and damascenone isomers (6.4%), whereas hexahydrofarnesyl acetone (27.8%), hexadecanoic acid (8.3%) and caryophyllene oxide (6.4%) were the most abundant components of C. micrantha ssp. melanosticta. The oils showed good antibacterial and antifungal activities against some microorganisms that infest historica…
Guaianolides from the Aerial Parts of Centaurea Hololeuca
2006
Seven guaianolides were isolated from the acetone extract of the aerial parts of Centaurea hololeuca Boiss. The antifeedant activity of the natural compounds (1–7) and of four chloro derivatives (8–11), synthesized from repin (1) and janerin (3) were tested against larvae of Spodoptera littoralis. Cebellin J (6) and chlorojanerin (11) showed significant antifeedant activity at 100 ppm, whereas at this concentration cebellin G (4) and 15-deschloro-15-hydroxychlorojanerin (7) stimulated feeding. Cebellin G (4) stimulated larvae of S. littoralis to feed at low concentration, but deterred feeding at high concentrations. The addition of chlorine to repin (1) resulted in an increase in antifeeda…
Phytotoxicity and metabolism of chlortoluron in two wheat varieties
1985
Abstract Varietal susceptibility of winter wheat to chlortoluron, 1-(3-chloro-4-methylphenyl)-3,3 dimethylurea, has been studied in two varieties, Corin (susceptible) and Clement (tolerant). After a 24-hr root absorption of the herbicide, phytotoxicity was estimated from growth measurements. When administered at 12 to 96 μM concentrations, the herbicide reduced the growth of both varieties. A significant selective effect was found at 96 μM. Measurements of chlorophyll fluorescence-induction kinetics allowed to discriminate between the two varieties treated with 12 to 48 μM chlortoluron. The metabolism of chlortoluron was studied following absorption of 24 μM solutions. Both varieties produc…