Search results for "work"
showing 10 items of 14511 documents
Tailoring the Exchange Interaction in Covalently Linked Basic Carboxylate Clusters through Bridging Ligand Selection
2012
We are reporting new dimeric units of basic carboxylates bearing the {Fe III 2M IIO} motif for M = Co and Ni, covalently bound through the tetradentate bridging (LL) 2,2′-azopyiridine (azpy) and 2,3-di(2-pyridyl)quinoxaline ligands (dpq). We structurally characterized the hexanuclear clusters, and their magnetic properties have been fully analyzed. DFT calculations have been performed as a supplementary tool. All results evidence a weak antiferromagnetic interaction through the bridging ligands between isolated spin ground states arising from intra-Fe 2MO core exchange couplings. Together with the pioneer 2,2′-bipyrimidine bridged systems, the new complexes reported constitute a family of c…
Effects of Carbon-sp3 Bridging on the Electronic Properties of Oligothiophenes
1999
Abstract The electronic properties of rigidified, carbon sp 3 -bridged bithiophenes and terthiophenes have been investigated using density functional theory calculations, sp 3 Bridging has no effect on the bandgap other than that associated to the planarization of the system. Rigidification significantly improves the ability of oligothiophenes as electron donors but diminishes their electron accepting capacity. Grafting of substituents at the sp 3 bridging carbon slightly modifies the electronic properties.
Advances in Perovskite Optoelectronics: Bridging the Gap Between Laboratory and Fabrication
2020
In 2019, hybrid halide perovskites celebrated their 10th anniversary as a "wonder material" for optoelectronic applications. Although the parent perovskite structures were elucidated in the late 19th century, the seminal work by Miyasaka et al. exploiting organic‐inorganic hybrid halide perovskites sensitizers for visible‐light conversion in solar cells marked the revisit of these materials and has proven to be a game‐changer in this field. Extensive investigations were undertaken to develop new materials (all inorganic and organic‐inorganic hybrids, in the form of films or alternate morphologies) and deposition techniques, explore interfaces and in‐depth characterization, while engineering…
Fracture Toughness and Bridging Law of 3D Woven Composites
2003
ABSTRACT In the paper, the methodology of measuring G 1 c by using DCB specimens in the presence of large-scale bridging is adapted for investigating the delamination in 3D woven composites. The main novelties introduced in the DCB testing concern a) the loading device, b) the specimen geometry, c) the measurement scheme, and d) the determination of G 1 c and the bridging law from experimental data. The geometry-independent material characteristic G 1c as a function of the initial crack opening displacement (ICOD) is introduced. Typical values of the delamination fracture toughness of 3D glass and carbon composites are presented.
Growth of immobilized DNA by polymerase: bridging nanoelectrodes with individual dsDNA molecules.
2011
We present a method for controlled connection of gold electrodes with dsDNA molecules (locally on a chip) by utilizing polymerase to elongate single-stranded DNA primers attached to the electrodes. Thiol-modified oligonucleotides are directed and immobilized to nanoscale electrodes by means of dielectrophoretic trapping, and extended in a procedure mimicking PCR, finally forming a complete dsDNA molecule bridging the gap between the electrodes. The technique opens up opportunities for building from the bottom-up, for detection and sensing applications, and also for molecular electronics.
Investigating Centrality Measures in Social Networks with Community Structure
2021
Centrality measures are crucial in quantifying the influence of the members of a social network. Although there has been a great deal of work dealing with this issue, the vast majority of classical centrality measures are agnostic of the community structure characterizing many social networks. Recent works have developed community-aware centrality measures that exploit features of the community structure information encountered in most real-world complex networks. In this paper, we investigate the interactions between 5 popular classical centrality measures and 5 community-aware centrality measures using 8 real-world online networks. Correlation as well as similarity measures between both t…
Measuring the ‘Bridging’ versus ‘Bonding’ Nature of Social Networks: A Proposal for Integrating Existing Measures
2010
Recent research illustrates that two distinct interpretations and operationalizations of ‘bridging’ and ‘bonding’ social networks co-exist in the literature (based on links between diverse networks or between socio-economic groups within a given network, respectively), and that these do not coincide in empirical applications. The present contribution first confirms this conclusion using data from the United Kingdom. Then, we suggest a simple way to integrate both existing approaches into a more general measure of bridging and bonding. Applying this more general index to UK and Flemish data, a) provides stronger empirical support for the idea that memberships in bridging groups are more str…
Bridging the gap between research and practice : using phenomenographic findings to develop training for career practitioners
2021
AbstractThis study contends that phenomenography offers both a useful research method and practical tools for developing education and training for career practitioners. After introducing the basic principles of phenomenography, the study reviews previous research on its potential in developing pedagogical practices. It explores how the phenomenographic findings were utilized to design an online skills training programme for career practitioners. The study finds that phenomenographic research serves three practical pedagogical purposes: (1) revealing how learners understand certain concepts or phenomena, (2) elucidating how these understandings differ; and (3) identifying critical aspects i…
Air stable hybrid organic-inorganic light emitting diodes using ZnO as the cathode
2007
An air stable hybrid organic-inorganic light emitting device is presented. This architecture makes use of metal oxides as charge injecting materials into the light emitting polymer, avoiding the use of air sensitive cathodes commonly employed in organic light emitting diode manufacturing. We report the application of zinc oxide as a cathode in an organic light emitting device. This electroluminescent device shows high brightness levels reaching 6500 cd/m2 at voltages as low as 8 V. Compared to a conventional device using low workfunction metal cathodes, our device shows a lower turn-on voltage and it can operate in air.
Magnesium recovery from exhausted brine
2015
Mg and MgCO3 are among the 20 EU critical raw materials. Interestingly, Mg can be found at very high concentration in brines generated as waste stream from salt works. Literature works have demonstrated the feasibility of Mg extraction from brines [1–3] by reactive precipitation, for the production of Mg(OH)2. Here we present an overview of the experimental campaigns carried out using exhausted brine from real salt works (Italy) to produce Mg(OH)2 with high purity and conversion. Lab – and pilot-scale batch and semi-continuous CSTR crystallisers were developed and tested, eventually leading to a continuous process by a quasi-PFR pilot reactor. Different alkaline solutions have been adopted …