Search results for "yttria-stabilized zirconia"
showing 10 items of 30 documents
Large scale synthesis of nanostructured zirconia-based compounds from freeze-dried precursors
2013
Nanocrystalline zirconia powders have been obtained at the multigram scale by thermal decomposition of precursors resulting from the freeze-drying of aqueous acetic solutions. This technique has equally made possible to synthesize a variety of nanostructured yttria or scandia doped zirconia compositions. SEM images, as well as the analysis of the XRD patterns, show the nanoparticulated character of those solids obtained at low temperature, with typical particle size in the 10–15 nm range when prepared at 673 K. The presence of the monoclinic, the tetragonal or both phases depends on the temperature of the thermal treatment, the doping concentration and the nature of the dopant. In addition,…
Manufacturing and testing of a metal supported Ni-YSZ/YSZ/La2NiO4 IT-SOFC synthesized by physical surface deposition processes
2017
International audience; The manufacture of the last generation metal supported IT-SOFC complete cell by dry surface deposition pro-cesses is really challenging. Atmospheric Plasma Spraying (APS) and Reactive Magnetron Sputtering (RMS) processes are respectively adapted to deposit Ni-YSZ anode and YSZ electrolyte layers. RMS is also used to coat a thin and dense La2NiO4 (LNO) cathode layer. In this work, we have realized a complete cell on metallic support (ITM) produced by PLANSEE SE. The innovative LNO cathode layer was compared with screen-printed LNO layers, with and without RMS bonding layer. Electrochemical and Voltammetry tests were performed on these samples. It reveals lower perform…
Elaboration of Nickel Aluminide Diffusion Coatings: Application to Oxidation Resistance
2008
Aluminide diffusion coatings are widely used in aeronautic domain. Nickel based superalloys present good mechanical properties and creep resistance at high temperature but their corrosion resistance is somewhat poor. In order to enhance their lifetime at high temperature, aluminide coatings can be applied on alloy surface. Aluminium present on material surface can form, at high temperature, alumina scale which is a protective oxide scale. In the present study, nickel aluminide coatings were carried out by aluminisation in a single step pack cementation process on nickel based superalloys 600 and AM1. Ni-Al intermetallic was obtained in each case. Oxidation tests were carried out at 900°C in…
In-situ nano-silica deposition and air-abrasion with Bioglass 45S5 or aluminium oxide: Effects on methacrylate bonding to yttria-tetragonal zirconia …
2015
This study aimed at assessing the bonding performance after water storage (24 h/6-month) of a methacrylate-based cement applied onto Yttria-Tetragonal Zirconia Polycrystal(Y-TZP) pre-treated using an innovative in-situ silica nanoparticle deposition method and/or air-abrasion with Bioglass 45S5 (BAG) or aluminium oxide (AlO). Pre-sintered blocks of Y-TZP were coated with nano-silica using an experimental in-situ deposition method or used as received (control/silica-free). Air-abrasion was performed with AlO or BAG particles both on silica-coated and control Y-TZP specimens. All the specimens were then analysed using SEM– EDX. Further specimens were treated as described above, bonded using a…
Microwave synthesis of yttria stabilized zirconia
2005
Yttria stabilised zirconia (YSZ) nanocrystals, with a mean size between 5 and 10 nm, were prepared by microwave flash synthesis. Flash synthesis was performed in alcoholic solutions of yttrium, zirconium chloride and sodium ethoxide (EtONa) using a microwave autoclave (RAMO system) specially designed by authors. Energy dispersive X-ray analysis (EDX), X-ray powder diffraction (XRD), BET adsorption technique, photon correlation spectroscopy (PCS) transmission and scanning electron microscopy (TEM and SEM) are used to characterized these nanoparticles. Compared with conventional synthesis, nanopowders can be produced in a short period (e.g. 10 s), both high purity and stoechiometric control a…
Structure formation and properties of corundum ceramics based on metastable aluminium oxide doped with stabilized zirconium dioxide
2021
Abstract The work presents a successful example of the use of YSZ binary systems for production of composite ceramic materials based on θ-Al2O3 with improved physical and mechanical characteristics which was previously considered an unpromising material. It was first obtained result of extreme nature of dependence of physical and mechanical properties of Al2O3+YSZ on the concentration of YSZ (ZrO2–3mol% of Y2O3) additive. The sintering temperature was decreased on 250 °C (from 1800 to 1550 °C). The phase composition of powders and the structure of ceramics of the Al2O3 + YSZ system were investigated depending on the amount of YSZ dopant, the structure-properties relationship was established…
Resistive state relaxation time in ZrO2(Y)-based memristive devices under the influence of external noise
2022
The effects of external digitally synthesized Gaussian noise on the resistive state relaxation time of a ZrO2(Y)-based memristive device when switching from a low resistance state to a high resistance state have been experimentally investigated. A nonmonotonic dependence of the resistive state relaxation time on the external noise intensity is found. This behavior is interpreted as a manifestation of the noise-enhanced stability effect previously observed in various complex systems with metastable states. It is shown that the experimental results agree satisfactorily with the theoretical ones. The presented results indicate the constructive role of external noise and its possible use as a m…
ODS ferritic steels obtained from gas atomized powders through the STARS processing route: Reactive synthesis as an alternative to mechanical alloying
2018
Authors acknowledge ALBA synchrotron (Spain) for the provision of beamtime on the beam line BL22-CLAESS (Proposal 2016081797). Transmission electron microscopy observations were accomplished at Centro Nacional de Microscopía Electrónica, CNME-UCM. This work has been carried out within the framework of the EUROfusion Consortium and has received funding from the Euratom research and training programme 2014–2018 under grant agreement No 633053. The views and opinions expressed herein do not necessarily reflect those of the European Commission. Financial support from Basque Government through the ELKARTEK ACTIMAT 2016 project is also acknowledged.
BST ceramics: Effect of attrition milling on dielectric properties
2004
Abstract The effect of grain size on the dielectric properties of Ba0.6Sr0.4TiO3 (BST) ceramics is investigated. Attrition milling is chosen to obtain nanometre particle size from micrometre particle size powders. Fine grained ceramics are obtained by hot uniaxial pressing (HUP). Additionally, the present study is focused on the effect of the nature of milling balls on loss tangent and permittivity. For that, three kinds of balls are tested: calcia, yttria or ceria stabilised zirconia balls. The properties of these samples are evaluated in the range of MHz. The balls induce an involuntary doping of powders which modifies the dielectric properties, especially the Curie temperature and loss t…
Crystallographic changes and thermal properties of lanthanum?strontium ferromanganites between RT and 700 �C
2005
Abstract X-ray powder diffraction was used to determine the crystallographic changes between room temperature (RT) and 700 °C of the (La 0.8 Sr 0.2 )(Mn 1− y Fe y )O 3± δ perovskites with y =0.2, 0.5, 0.8, 1 which can be considered as possible cathode materials for the ITSOFCs. For y =0.2, the rhombohedral symmetry was preserved in the whole temperature range. For y =1, a transition from orthorhombic to rhombohedral symmetry occurred at 290 °C. The compounds with y =0.5 and 0.8 were found to be diphasic at RT by combination of both rhombohedral and orthorhombic symmetries. They became only rhombohedral at 80 and 160 °C, respectively. This reversible transition is discussed in terms of iron …