Search results for "yttria-stabilized zirconia"
showing 10 items of 30 documents
New preparation of ceramic coatings by low-pressure plasma spray
2018
As an advanced thermal spray technology, low-pressure plasma spray (LPPS) allows obtaining high-quality coatings and can bridge the thickness gap between conventional thermal spray technologies and standard thin film processes. Moreover, LPPS permits to build uniform coatings with various microstructures; deposition takes place not only from liquid splats but also from nano-sized clusters as well as from the vapor phase depending on operational conditions. In order to further improve and develop the LPPS process, this research aims to combine it with the emerging suspension plasma spray and reactive plasma spray processes. It was expected to both provide two novel integrated processes and a…
Effect of sintering process on color parameters of nano-sized yttria partially stabilized tetragonal monolithic zirconia
2018
Background Sintering process is responsible for aesthetic of zirconia restoration. This study evaluated the effect of different sintering temperatures and sintered-holding times on color parameters of monolithic zirconia. Material and Methods One hundred and thirty five zirconia bar specimens (width-length-thickness = 10×20×1.5 mm) were prepared from yttria-stabilized tetragonal zirconia polycrystalline (Y-TZP) ceramic and randomly divided into nine groups to be sintered at different temperatures [decreasing- (SD, 1350°C), regular- (SR, 1450°C), and increasing- (SI, 1550°C) sintering temperature] and different sintered-holding times [shortening- (HS, 60 min), regular- (HR, 120 min), and pro…
Influence of different veneering techniques and thermal tempering on flexural strength of ceramic veneered yttria partially stabilized tetragonal zir…
2019
Background Different technique for ceramic veneering and thermal tempering process are expected to be a reason for alteration in strength of ceramic veneered zirconia. This study evaluates the effect of different veneering technique and varied thermal tempering process on flexural strength of ceramic veneered zirconia. Material and Methods Ceramic veneered zirconia bars (25 mm length, 4 mm width, 0.7&1.0mm of zirconia & ceramic thickness) were prepared from zirconia block (e.max® ZirCAD), sintered at 1500°C for 4 hours, and veneered with ceramics with different techniques including CAD-fused using e.max CAD® (C), Pressed-on using e.max® Zirpress (P), and layering using e.max® ceram (L), wit…
Yttria-stabilized zirconia in-flight particle characteristics under vacuum plasma spray conditions
2009
This paper deals with the diagnostic yttria-stabilized zirconia (YSZ) in-flight particles in Vacuum Plasma Spray (VPS) process using an optical measurement device. Particle velocity, temperature and diameter were correlated to spray distance under a fixed chamber pressure of about 14 kPa. Experiments were carried out with a two-color pyrometer. Results show that correlations can be satisfactory described with linear relationships. Particle velocity and temperature decrease when increasing spray distance whereas particle diameter exhibits a linear increase with the spray distance.
Experimental investigations of local stochastic resistive switching in yttria stabilized zirconia film on a conductive substrate
2020
We report on the results of the experimental investigations of the local resistive switching (RS) in the contact of a conductive atomic force microscope (CAFM) probe to a nanometer-thick yttria stabilized zirconia (YSZ) film on a conductive substrate under a Gaussian noise voltage applied between the probe and the substrate. The virtual memristor was found to switch randomly between the low resistance state and the high resistance state as a random telegraph signal (RTS). The potential profile of the virtual memristor calculated from its response to the Gaussian white noise shows two local minima, which is peculiar of a bistable nonlinear system.
X-ray Absorption under Operating Conditions for Solid-Oxide Fuel Cells Electrocatalysts: The Case of LSCF/YSZ
2019
We describe a novel electrochemical cell for X-ray absorption spectroscopy (XAS) experiments during electrical polarization suitable for high-temperature materials such as those used in solid oxide fuel cells. A half-cell LSCF/YSZ was then investigated under cathodic and anodic conditions (850 °
MOCVD deposition of YSZ on stainless steels
2003
Abstract Yttria stabilized zirconia was deposited on stainless steel using the metal–organic chemical vapor deposition (MOCVD) technique, from β-diketonate precursors. The variation of the evaporation temperatures of yttrium and zirconium precursor allowed to control the level of Y within the film. Over the temperature range 125–150 °C, the Y content increased from 2.5 to 17.6 at.%. X-ray diffraction (XRD) analyses evidenced tetragonal phase of zirconia when the Y content was below 8 at.%, and cubic phase for higher concentration. Sputtered neutral mass spectrometry (SNMS) profiles confirmed that the control and stability of Y precursor temperature were of major importance to guarantee the …
Structural Infrared Analysis of Ultra Nanosized Crystals of Yttria-Stabilized Zirconia
2017
This paper describes the characterization of ultra nanosized crystals as monoclinic, tetragonal, cubic or mixed phases of ZrO2. Nanopowders are produced using the microwave method, which allows control of the ratio of zirconium to yttrium to yield various crystallographic structures. The synthesized ultra nanosized particles have very broad XRD peaks. In particular, the similarity of the XRD peaks of tetragonal and cubic nanocrystals makes it difficult to distinguish between these two crystals. In this paper, tetragonal and cubic nanocrystals were clearly distinguished using infrared spectroscopy (IR). An infrared spectroscopic method to quantitatively analyse the percentage distribution be…
Resistive switching in memristors based on yttria-stabilized zirconia
2021
Effect of pulse amplitude on depression and potentiation of ZrO2(Y)-based memristive synaptic device
2022
The effect of the amplitude of depressing and potentiating pulses on the synaptic plasticity (potentiation and depression) of a memristive device based on the Ta/ZrO2(Y)/Pt stack has been experimentally studied. It is shown that the amplitude of depressing and potentiating pulses affects the synaptic plasticity, namely, the value of current passing through the memristive device. The presented results demonstrate the prospects of using the ZrO2(Y)-based memristive devices as stable and low-power elements of neuromorphic systems.