0000000000013883

AUTHOR

Graziella Malandrino

0000-0001-7483-3070

showing 5 related works from this author

Core-shell Zn-doped TiO2-ZnO nanofibers fabricated via a combination of electrospinning and metal-organic chemical vapour deposition

2010

Zn-doped TiO2 nanofibers shelled with ZnO hierarchical nanoarchitectures have been fabricated combining electrospinning of TiO2 (anatase) nanofibers and metal-organic chemical vapor deposition (MOCVD) of ZnO. The proposed hybrid approach has proven suitable for tailoring both the morphology of the ZnO external shell as well as the crystal structure of the Zn-doped TiO2 core. It has been found that the Zn dopant is incorporated in calcined electrospun nanofibers without any evidence of ZnO aggregates. Effects of different Zn doping levels of Zn-doped TiO2 fibers have been scrutinized and morphological, structural, physico-chemical and optical properties evaluated before and after the hierarc…

AnataseMaterials scienceSettore ING-IND/22 - Scienza e Tecnologia dei MaterialiNanotechnologyCathodoluminescenceChemical vapor depositionNANOWIRESNANOSTRUCTURESZN-DOPINGTITANIA; ELECTROSPINNING; NANOFIBERS; CHEMICAL VAPOUR DEPOSITION ZN-DOPINGROUTEXPSGeneral Materials ScienceMetalorganic vapour phase epitaxyZINC-OXIDENanocompositeDopantELECTROSPINNINGPHOTOCATALYTIC ACTIVITYGeneral ChemistryOPTICAL-PROPERTIESCondensed Matter PhysicsNANOCOMPOSITESElectrospinningCHEMICAL VAPOUR DEPOSITIONNanofiberTITANIAPHOTOLUMINESCENCESENSITIZED SOLAR-CELLSSENSITIZED SOLAR-CELLS; ZINC-OXIDE; PHOTOCATALYTIC ACTIVITY; OPTICAL-PROPERTIES; PHOTOLUMINESCENCE; NANOSTRUCTURES; NANOCOMPOSITES; NANOWIRES; ROUTE; XPSNANOFIBERS
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Colloidal lithography and Metal-Organic Chemical Vapor Deposition process integration to fabricate ZnO nanohole arrays

2010

A complete set up of optimal process conditions for an effective colloidal lithography/catalyst assisted MOCVD process integration is presented. It mainly focuses on the determination of the deposition temperature threshold for ZnO Metal-Organic Chemical Vapour Deposition (MOCVD) as well as the concentration of metal-organic silver (Ag) catalyst. Indeed, the optimization of such process parameters allows to tailor the ZnO film morphology in order to make the colloidal lithography/catalyst assisted MOCVD approach a valuable bottom up method to fabricate bi-dimensional ordered ZnO nanohole arrays. (C) 2010 Elsevier B.V. All rights reserved.

Materials sciencezinc oxide; Nanowires and nanohole arrays; Colloidal lithographyMetals and AlloysNanowirezinc oxideNanotechnologyZnO; Catalyst; Nanowires; Nanohole array; Colloidal lithography; MOCVDSurfaces and InterfacesChemical vapor depositionSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCatalysisNanowireNanohole arrayScientific methodProcess integrationMOCVDMaterials ChemistryNanowires and nanohole arraysZnOColloidal lithographyMetalorganic vapour phase epitaxyCatalystThin filmLithography
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Effects of Metal-Organic Chemical Vapour Deposition grown seed layer on the fabrication of well aligned ZnO nanorods by Chemical Bath Deposition

2011

Well aligned, long and uniform ZnO nanorods have been reproducibly fabricated adopting a two-steps Metal-Organic Chemical Vapour Deposition (MOCVD) and Chemical Bath Deposition (CBD) fabrication approaches. Thin (<100 nm) ZnO buffer layers have been seeded on silicon substrates by MOCVD and ZnO layers have been subsequently grown, in form of well textured nanorods, using CBD. It has been found that the structure and thickness of the seed layer strongly influence the final morphology and the crystal texturing of ZnO nanorods as well as the CBD growth rate. There is, in addition, a strong correlation between morphologies of CBD grown ZnO nanorods and those of the seed layer underneath. Thus, …

Metal-Organic Chemical Vapour Deposition; Chemical Bath Deposition; Zinc oxideMetal-Organic Chemical Vapour Deposition; Chemical Bath Deposition; Zinc oxide; Nanorods; Scanning Electron MicroscopyMaterials scienceFabricationScanning electron microscopeChemical Bath DepositionMetals and Alloyschemistry.chemical_elementNanotechnologySurfaces and InterfacesChemical vapor depositionZincNanorodSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialschemistryZinc oxideMaterials ChemistryNanorodMetalorganic vapour phase epitaxyScanning Electron MicroscopyLayer (electronics)Metal-Organic Chemical Vapour DepositionChemical bath deposition
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ZnO nanorod arrays fabrication via chemical bath deposition: Ligand concentration effect study

2010

A new ligand, N, N, N', N'-tetramethylethylenediamine, has been used to grow ZnO nanorods on silicon substrates via a two steps approach. A preliminary seeding on silicon substrates has been combined with chemical bath deposition using a Zinc acetate - N, N, N', N'-tetramethylethylenediamine aqueous solution. The used diamino ligand has been selected as Zn(2+) complexing agent and the related hydrolysis generates the reacting ions (Zn(2-) and OH(-)) responsible for the ZnO growth. The seed layer has been annealed at low temperature (<200 degrees C) and the ZnO nanorods have been grown on this ZnO amorphous layer. There is experimental evidence that the ligand concentration (ranging from 5 t…

Aqueous solutionMaterials scienceSiliconLigandInorganic chemistryConcentration effectchemistry.chemical_elementLigandNanotechnologyNanorodZincCondensed Matter PhysicsSolution growthZnO; CBD; Nanorods; Ligand; Solution growthchemistryZnOCBDGeneral Materials ScienceNanorodElectrical and Electronic EngineeringLayer (electronics)Chemical bath depositionSuperlattices and Microstructures
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Sb-implanted ZnO ultra-thin films

2017

Mild heating of the Zn(C5F6HO2)(2)center dot 2H(2)O center dot CH3(OCH2CH2)(2)OCH3 precursor allowed MOCVD deposition of ZnO films, in a low-pressure horizontal hot-wall reactor, on ITO substrates. The ZnO films were subsequently implanted with Sb ions. XRD measurements provided evidence that they consist of hexagonal, (002) and (101) oriented, crystals. UV-vis spectra showed that the transmittance of these films in the visible region is about 90%. The Sb implanted ZnO film showed a current-voltage characteristic that resembles that of a rectifying diode. This study represents the first example of Sb-implantation in ZnO films obtained by MOCVD.

AntimonyMaterials scienceCondensed Matter Physic02 engineering and technology010402 general chemistrySettore ING-INF/01 - Elettronica01 natural sciencesSettore FIS/03 - Fisica Della MateriaSpectral lineIonTransmittanceZnO filmDeposition (phase transition)Mechanics of MaterialGeneral Materials ScienceMetalorganic vapour phase epitaxyThin filmFilmDiodeDiodeHexagonal crystal systembusiness.industryMechanical Engineering021001 nanoscience & nanotechnologyCondensed Matter Physics0104 chemical sciencesMechanics of MaterialsMOCVDZnOZnO film; antimony; diodeOptoelectronicsMaterials Science (all)0210 nano-technologybusinessMaterials Science in Semiconductor Processing
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