0000000000194793
AUTHOR
G. Godefroy
Ion implantation effects in BaTiO3 single crystals
Abstract Thermally controlled helium implantation has been used to produce planar waveguides in BaTiO3 without noticeable depoling effects in the samples. Profiles for the ordinary and extraordinary refractive index are deduced from optical mode measurements. No annealing procedure is required. We report the effects of different ion fluences and energies in the MeV range on the waveguide properties.
Light Sensitive Lattice Defects In BaTiO 3 Containing Fe
Electron spin resonance spectra, which can consistently be explained by the models Fe4+ - Vo and Fe5+ - vBa, have been observed with BaTiO3 containing Fe. Also Fe3+ and - Fe3+ - Vo have been identified. All these centers as well as several unidentified ones are observed to change their charge states under illumination. They thus are possibly in involved in photorefractive processes in BaTiO3 containing Fe.
Alkaline cavities and tetrahedra in and solid solutions
Seven different crystals were grown with 0 < x < 2 while seven different crystals were grown with , the limit value x = 1 corresponding to the clearly defined compound. A crystallographic study of these solid solutions was performed by comparison with the pure crystal. Structures were solved in the Pnma space group for the rubidium solid solutions and in the space group for the potassium ones. It was shown that the distribution of Cs and Rb, or Cs and K, among the two cationic sites called and was not random: Rb and K exhibit a higher affinity for the smallest cavity, the site. While the phase transition of and can be interpreted as rotations of the rigid tetrahedra mainly around the a dire…
Raman measurements in the intermediate phase of [N(CH3)4]2ZnI4
Abstract Raman spectra and deviation angle of the indicatrix have been measured in the intermediate phase, between the two transition temperatures T c1 = 255 K and T c2 = 217 K. The results are consistent with the existence, in this phase, of large domains, piled up along the c-axis (Pnma notation).
ESR of Nd3+ in BaTiO3
Afin d'identifier les defauts responsables de l'effet photo-refractif dans BaTiO 3 , on etudie ces cristaux. Les echantillons contiennent generalement divers etats de charge et des associations de Fe, Cr, ainsi que des trous de O − induits par le rayonnement. On trouve un nouveau centre qui doit etre attribue a Nd 3+ . Dans la presente etude, l'echantillon utilise n'est pas dope, et on l'etudie dans la phase rhomboedrique a T∼77 K. Il apparait que Na est une impurete courante dans BaTiO 3 probablement incorporee avec le materiau de depart, BaCO 3
Proton implanted waveguides in LiNbO3, KNbO3and BaTiO3
Abstract By using a Van De Graaf accelerator, planar waveguides in LiNbO3, KNbO3, and BaTiO3 are fabricated (at 300 K) by thermally controlled proton implantation. The waveguide properties are investigated by dark line mode spectroscopy. The reconstructed profiles closely follow the ion concentration profiles as determined by simulation (TRIM).
Experimental study of the crystals [N(CH3)4]2Znl4by Raman spectroscopy and optical measurements; comparison with isomorph compounds
Abstract Raman spectra and rotation angle of the indicatrix have been measured in the intermediate phase of the crystal [N(CH3)4]2Znl4 The results are consistent with the existence of large ferroelastric domains piled up along the a axis in a monoclinic phase P1121/a (Pnma notation in the paraelectric phase). The phase sequence (Pnma-P1121/a-P21ca) in this compound is different from other members of [N(CH3)4]2BX4 family.
Crystallographic study of a family of Cs2BX4compounds
Abstract Five compounds of the Cs2BX4 family with B = Zn, Co, Cu and X = Cl, Br were grown and studied. They belong to Pnma space group with 4 formula units per cell. From the full determination of the structure it appears that the ZnX4 tetrahedra are almost regular while the CuX4 tetrahedra are strongly distorted. This seems to be due to a strong Jahn-Teller effect induced by the Cu ions. This remark is extended to other compounds of the general family A2BX4.
Crystal growth and hysteresis phenomena of rubidium tetrachlorozincate Rb2ZnCl4
Abstract Phase transitions in Rb2ZnCl4 crystals grown by various methods are examined with differential scanning calorimetry and dielectric measurements. For most of the studied samples the permittivity along the ferroelectric axis shows a large thermal hysteresis over a wide temperature range including the incommensurate phase and the lock-in point. This hysteresis depends on the presence of different defects which appear during crystal growth or after a thermal and mechanical treatment. It is shown that dielectric measurements are quite well suited to characterize the crystals exhibiting on incommensurate phase and a ferroelectric phase.
Conductivity and light-induced absorption in BaTiO3
A charge transport model including deep and shallow traps explains both the nonlinear relation between photoconductivity and light intensity and the light-induced absorption in BaTiO3. A correlation between measurements of photoconductivity and light-induced absorption as a function of temperature yields parameters for the shallow center, among them thermal activation energy and generation rate.
Crystal growth and phase transitions of solid solutions in [N(CH3)4]2MX4 isomorph class
Abstract Homogeneous single crystals of tetramethylammonium tetrahalogenometallate solid solutions have been grown: a temperature difference growth method with thermally enforced convection was used during the material transport from an equilibrated feed material to the growing crystals. The smallest crystals were mostly studied by differential scanning calorimetry and X-ray crystallography. Some bigger crystals were available for dielectric measurements and Raman scattering. The temperature-concentration phase diagrams of solid solutions look like the temperature-pressure phase diagrams of pure tetramethylammonium salts. The progressive substitution seems equivalent to a change of the pres…
On the phase diagram of[N(CH3)4]2ZnCl4under uniaxial stress
Abstract Optical measurement and microscopic observations have been performed of single crystals of (TMA)2ZnCl4 with the aim to establish its phase diagram in the coordinates temperature-uniaxial stress σ. Stress-induced shifts of transition temperatures have been evaluated. For stresses exceeding 4.5 MPa two new monoclinic phases are reported, tentatively labeled as VIII and IX, both with the monoclinic axis b.
Niobium implantation effects in BaTiO3 and SrTiO3
Abstract Single crystals of BaTiO3 and SrTiO3 have been implanted at room temperature with 150 keV Nb+ ions to doses ranging from 1014 to 1017 ions cm2. The structure and the oxidation state of the damaged layer have been investigated by Rutherford backscattering-ion channeling and electron spectroscopy, respectively. SrTiO3 is rendered amorphous at relatively low doses of 2 × 1015 ions cm−2, but the damage is efficiently annealed at 450°C for 1 2 h. For both materials, the oxidation state of niobium varies from + 5 to + 2 along the depth. Moreover, a considerable chemical shift (2.3 eV) is observed for barium in BaTiO3.
DiP223: Strongly temperature dependent electro-optic coefficients in BaTiO3
Abstract By means of a Senarmont set up and a very sensitive method, electrooptic coefficients in BaTiO3 are accurately determined from the phase measurement of the retardation Γ due to the electric field induced birefringence of the crystal. Electro-optic properties are investigated as a function of temperature around room temperature. A very large value of the coefficient r42 is found, in agreement with previous investigations. In addition, this coefficient is shown to be very sensitive to the temperature even for a very small change. The importance of both the thermo-optic effect and the thermal variation of electro-optic properties is pointed out for device applications of BaTiO3.
Theoretical study of Fe doping and oxidation–reduction influence on the photorefractive effect in BaTiO_3
We numerically solve charge-transport and Poisson equations for photorefractive BaTiO3 single crystals with a band model, using four impurity levels, Fe2+–Fe3+, Fe3+–Fe4+, VO••–VO•, and VO•-VOx. Densities and photoinduced spatial distributions of each population are computed as a function of annealing O partial pressure. Space-charge field and beam-coupling gain are also computed as a function of annealing O partial pressure, temperature, Fe concentration, grating wave vector, and light intensity. We discuss the intervening mechanism of impurity centers and the correlations between experimental conditions of crystal growth, oxidation–reduction treatments, and measurement parameters.