0000000000307239
AUTHOR
J. Maul
Optical magnetic circular dichroism in threshold photoemission from a magnetite thin film
Threshold photoemission excited by polarization-modulated ultraviolet femtosecond laser light is exploited for phase-sensitive detection of magnetic circular dichroism (MCD) for a magnetite thin film. Magnetite (Fe(3)O(4)) shows a magnetic circular dichroism of ∼(4.5 ± 0.3) × 10(-3) for perpendicularly incident circularly polarized light and a magnetization vector switched parallel and antiparallel to the helicity vector by an external magnetic field. The asymmetry in threshold photoemission is discussed in comparison to the magneto-optical Kerr effect. The optical MCD contrast in threshold photoemission will provide a basis for future laboratory photoemission studies on magnetic surfaces.
Inspection of EUVL mask blank defects and patterned masks using EUV photoemission electron microscopy
We report on recent developments of an "at-wavelength" full-field imaging technique for inspection of multilayer mask blank defects and patterned mask samples for extreme ultraviolet lithography (EUVL) by EUV photoemission electron microscopy (EUV-PEEM). A bump-type line defect with a width of approximately 35nm that is buried beneath Mo/Si multilayer has been detected clearly, and first inspection results obtained from a patterned TaN absorber EUVL mask sample is reported. Different image contrast of a similar width of multilayer-covered substrate line defect and on top TaN absorber square has been observed in the EUV-PEEM images, and origin of the difference in their EUV-PEEM image contra…
Magnetic Circular Dichroism in Two-Photon Photoemission
We report the observation of magnetic circular dichroism (MCD) in two-photon photoemission (2PPE). The Heusler alloys Ni2MnGa and Co2FeSi were investigated by excitation with femtosecond laser light, showing MCD asymmetries of A=(3.5+/-0.5)x10;{-3} for Ni2MnGa and of A=(2.1+/-1.0)x10;{-3} for Co2FeSi, respectively. A theoretical explanation is provided based on local spin-density calculations for the magnetic dichroic response; the computed 2PPE MCD agrees well with the experiment. The observed 2PPE magnetic contrast represents an interesting alternative for future time-resolved photoemission studies on surface magnetism practicable in the laboratory.
DIRECT EVIDENCE FOR CONDENSATION IN THE EARLY SOLAR SYSTEM AND IMPLICATIONS FOR NEBULAR COOLING RATES
We have identified in an acid resistant residue of the carbonaceous chondrite Murchison a large number (458) of highly refractory metal nuggets (RMNs) that once were most likely hosted by Ca,Al-rich inclusions (CAIs). While osmium isotopic ratios of two randomly selected particles rule out a presolar origin, the bulk chemistry of 88 particles with sizes in the submicron range determined by energy dispersive X-ray (EDX) spectroscopy shows striking agreement with predictions of single-phase equilibrium condensation calculations. Both chemical composition and morphology strongly favor a condensation origin. Particularly important is the presence of structurally incompatible elements in particl…
Actinic inspection of sub-50 nm EUV mask blank defects
A new actinic mask inspection technology to probe nano-scaled defects buried underneath a Mo/Si multilayer reflection coating of an Extreme Ultraviolet Lithography mask blank has been implemented using EUV Photoemission Electron Microscopy (EUV-PEEM). EUV PEEM images of programmed defect structures of various lateral and vertical sizes recorded at around 13 nm wavelength show that 35 nm wide and 4 nm high buried line defects are clearly detectable. The imaging technique proves to be sensitive to small phase jumps enhancing the visibility of the edges of the phase defects which is explained in terms of a standing wave enhanced image contrast at resonant EUV illumination.
Water Influences on the Copper Active Site in Hemocyanin
Active metal sites play a key role in the biochemistry of oxygen transport by hemocyanins. Observing the changes in the local electronic structure of the copper sites upon oxygenation is thus essen...
At-wavelength inspection of sub-40 nm defects in extreme ultraviolet lithography mask blank by photoemission electron microscopy.
A new at-wavelength inspection technology to probe nanoscale defects buried underneath Mo/Si multilayers on an extreme ultraviolet (EUV) lithography mask blank has been implemented using EUV photoemission electron microscopy (EUV-PEEM). EUV-PEEM images of programmed defect structures of various lateral and vertical sizes recorded at an ~13.5 nm wavelength show that 35 nm wide and 4 nm high buried line defects are clearly detectable. The imaging technique proves to be sensitive to small phase jumps, enhancing the edge visibility of the phase defects, which is explained in terms of a standing wave enhanced image contrast at resonant EUV illumination.
The miniaturised Mössbauer spectrometer MIMOS IIA: Increased sensitivity and new capability for elemental analysis
The Miniaturised Mossbauer Spectrometers MIMOS II on board the two Mars Exploration Rovers (MER) have now been collecting valuable scientific data for more than five years. Mossbauer Spectrometers are part of two future missions: Phobos Grunt (Russian Space Agency) and a joint ESA—NASA Rover in 2018. The new advanced MIMOS IIA instrument described in this paper uses Silicon Drift Detectors (SDD) allowing also X-ray fluorescence chemical analysis (XRF) simultaneously to Mossbauer acquisitions. This paper highlights the features and technological improvements of the new spectrometer MIMOS IIA.
Cluster calibration in mass spectrometry: laser desorption/ionization studies of atomic clusters and an application in precision mass spectrometry.
For accurate mass measurements and identification of atomic and molecular species precise mass calibration is mandatory. Recent studies with laser desorption/ionization and time-of-flight analysis of cluster ion production by use of fullerene and gold targets demonstrate the generation of atomic clusters for calibration purposes. Atomic ion results from the Penning trap mass spectrometer ISOLTRAP, in which a carbon cluster ion source has recently been installed, are presented as an application in the field of precision mass spectrometry.
Bimodal velocity distribution of atoms released from nanosecond ultraviolet laser ablation
We have investigated the velocity distributions of atoms released from a metallic gadolinium surface by UV laser ablation. The fluences of the nanosecond laser pulses were chosen for a pure release of neutrals and at a higher fluence level for the release of both neutrals and ions. In both cases a thermal Maxwell-Boltzmann slope has been observed for the low velocities, whereas for high velocities strong deviations from a thermal distribution have been seen. The observed velocity distribution has been explained by a bimodal structure including a thermal phase and a shockwave driven ``blow-off'' phase.
In-situ Mössbauer Spectroscopy with MIMOS II at Rio Tinto, Spain
The Rio Tinto, located in southwest Spain, exhibits a nearly constant, acidic pHvalue along its course. Due to the formation of sulfate minerals, Rio Tinto is considered a potential analogue site for sulfate-rich regions on Mars, in particular at the landing site of the Mars Exploration Rover Opportunity, where the ferric sulfate mineral jarosite was identified with Opportunity's Mössbauer spectrometer. Primary and secondary mineralogy was investigated in situ with portable Raman and Mössbauer spectrometers at four different Rio Tinto sampling sites. The two techniques analyse different sample portions due to their specific field of view and sampling depth and provide complementar…
Phase defect inspection of multilayer masks for 13.5 nm optical lithography using PEEM in a standing wave mode
We report on recent developments of an "at wavelength" full-field imaging technique for defect inspection of multilayer mask blanks for extreme ultraviolet lithography (EUVL). Our approach uses photoemission electron microscopy (PEEM) in a near normal incidence mode at 13.5 nut wavelength to image the photoemission induced by the EUV wave field on the multilayer blank surface. We analyze buried defects on Mo/Si multilayer samples down to a lateral size of 50 nm and report on first, results obtained from a six inches mask blank prototype as prerequisite for industrial usage. (c) 2007 Elsevier B.V. All rights reserved.
Nondestructive full-field imaging XANES-PEEM analysis of cosmic grains
For chemical analysis of submicron particles, mass spectrometric methods have the disadvantage of being destructive. Thus, a nondestructive elemental and chemical mapping with a high spatial resolution prior to mass analysis is extremely valuable to precharacterize the sample. Here, first results are presented of combined XANES (x-ray absorption near-edge structure) and PEEM (photoemission electron microscopy) measurements on a cosmic grain fraction from the Murchison meteorite. This nondestructive full-field imaging method is well suited for a quantitative analysis and for a preselection prior to detailed mass spectrometric investigations with isotopic resolution/selectivity. A spectral un…
Three-dimensional characterization of extreme ultraviolet mask blank defects by interference contrast photoemission electron microscopy
A photoemission electron microscope based on a new contrast mechanism "interference contrast" is applied to characterize extreme ultraviolet lithography mask blank defects. Inspection results show that positioning of interference destructive condition (node of standing wave field) on surface of multilayer in the local region of a phase defect is necessary to obtain best visibility of the defect on mask blank. A comparative experiment reveals superiority of the interference contrast photoemission electron microscope (Extreme UV illumination) over a topographic contrast one (UV illumination with Hg discharge lamp) in detecting extreme ultraviolet mask blank phase defects. A depth-resolved det…
Measurement of nanoparticle mass distributions by laser desorption/ionization time-of-flight mass spectrometry.
In this paper, access to the mass distribution analysis of nanoparticles is described based on laser desorption/ionization and time of flight mass spectrometry. Two examples are given, demonstrating the accurate mass distribution analysis of nanoparticles fabricated both ex situ and in situ during the laser-assisted desorption process. The potentials and the limitations of the method are discussed, with special emphasis on carbonaceous clusters and molecules.
Trace element analysis in pre-solar stardust grains via full-field imaging XPS (Nano-ESCA)
An acid-resistant, SiC-rich, residue from the Murchison meteorite was investigated by means of a novel imaging XPS instrument. The micrometer-sized grains were deposited on a Si wafer from an aqueous suspension. Energy filtered ESCA images have been taken in the kinetic energy range from the threshold up to about 400 eV for various photon energies. A lateral resolution of the order of 120 nm along with a high energy resolution in the range of 100 meV provides the basis for chemical trace element analysis with maximum sensitivity. Apart from major (Si, C) and minor (N, Mg, Al, Fe) elements, the energy filtered images and local microspectra revealed the presence of a variety of heavy trace el…
Periodic unmixing of a binary metallic vapor
We report on a type of surface structuring after short pulse laser ablation of a binary alloy. We observe the emergence of a concentric ring structure with changing elemental composition. The composition changes are interpreted by condensation of the ambient ablation vapor due to stress wave excitations in the ablation spot.
Statistical mechanics of fullerene coalescence growth
Among the different carbon allotropes fullerenes are exceptionally intriguing for their spheroidal topology out of pentagons and hexagons. However, the dominant formation mode is still ambiguous. Here, we analyze the fullerene formation process by the statistical analysis of fullerene sizes produced in a laser-induced microplasma finding that a simple two-parameter lognormal distribution describes impressively well the cluster frequencies under various conditions. Our findings clearly reveal coalescent growth following a classical collision dynamics and disagree with several earlier assumptions.
Multi-color resonance ionization of laser ablated gadolinium at high laser power
Abstract Spectroscopic and analytical properties of a trace analytical method using multi-step resonance ionization at high laser intensities (>kW/cm 2 ) have been investigated with gadolinium as a test element. Strongly saturated transitions are observed, which have been used for a temperature determination of the atoms in the laser ablated plume. Regimes of multi-step resonance ionization and multiphoton ionization could be distinguished. Analytical performances due to resonance enhancement and resulting discrimination against non-resonant background, precision in isotope ratio determination and overall detection efficiency are discussed.
A laser desorption/resonance enhanced photoionisation TOF-system for the spatially resolved trace analysis of elements
Abstract A novel method for direct and spatially resolved elemental trace analysis with high sensitivity and elemental selectivity is presented. The concept is based on the combination of a commercial MALDI-TOF mass spectrometer with a pulsed laser system for resonant postionisation of neutrals. While the MALDI method is usually applied for investigations of large organic compounds and biomolecules, the technique discussed here concerns the low mass range around 1 ⩽ A ⩽ 300. The analytical performances of the setup with respect to mass analysis, spatial resolution and overall detection efficiency are discussed.