Total CO2output from Vulcano island (Aeolian Islands, Italy)

[1] Total CO2 output from fumaroles, soil gas, bubbling gas discharges and water dissolved gases discharged from the island, was estimated for Vulcano island, Italy. The CO2 emission from fumaroles from the La Fossa summit crater was estimated from the SO2 crater output, while CO2 discharged through diffuse soil emission was quantified on the basis of 730 measurements of CO2 fluxes from the soil of the island, performed by using the accumulation chamber method. The results indicate an overall output of ≅500 t day−1 of CO2 from the island. The main contribution to the total CO2 output comes from the summit area of the La Fossa cone (453 t day−1), with 362 t day−1 from crater fumaroles and 91…

The role of the aquifer in soil CO2 degassing in volcanic peripheral areas: A case study of Stromboli Island (Italy)

Abstract The peripheral area of Stromboli Island, Italy, named “Scari”, was continuously studied between January 2009 and December 2010. Data on soil CO 2 flux and the partial pressure of CO 2 (pCO 2 ) in equilibrium with the thermal aquifer linked to the magmatic system are presented. Soil CO 2 fluxes range from 20 to 370 g m − 2  d − 1 and have been strongly affected by soil temperature variations. Soil CO 2 flux data were filtered with respect to the soil temperature and the calculated values, called “residuals”, were considered to detect changes induced by the magmatic system. The pCO 2 values change in a wide range from 0.03 to 0.6 (atm), showing rapid variations. The results of this s…

Development and application of active and passive DOAS instrumentation for the remote sensing measurement of volcanic gas emissions and continuous geochemical monitoring of degassing volcanoes

CO2 output discharged from Stromboli Island (Italy)

Abstract Total CO 2 output from soil gas and plume, discharged from the Stromboli Island, was estimated. The CO 2 emission of the plume emitted from the active crater was estimated on the basis of the SO 2 crater output and C/S ratio, while CO 2 discharged through diffuse soil emission was quantified on the basis of 419 measurements of CO 2 fluxes from the soil of the whole island, performed by using the accumulation chamber method. The results indicate an overall output of ≅ 416 t day − 1 of CO 2 from the island. The main contribution to the total CO 2 output comes from the summit area (396 t day − 1 ), with 370 t/day from the active crater and 26 t day − 1 from the Pizzo sopra La Fossa so…

Long-time variation of soil CO2 fluxes at the summit crater of Vulcano (Italy)

Here, we report the first continuous data of geochemical parameters acquired directly from the active summit crater of Vulcano. This approach provides a means to better investigate deep geochemical processes associated with the degassing system of Vulcano Island. In particular, we report on soil CO2 fluxes from the upper part of Vulcano, a closed-conduit volcano, from September 2007 to October 2010. Large variations in the soil CO2 and plume SO2 fluxes (order of magnitude), coinciding with other discontinuous geochemical parameters (CO2 concentrations in fumarole gas) and physical parameters (increase of shallow seismic activity and fumarole temperatures) have been recorded. The results fro…

Continuous SO2 flux measurements for Vulcano Island, Italy

<p>The La Fossa cone of Vulcano Island (Aeolian Archipelago, Italy) is a closed conduit volcano. Today, Vulcano Island is characterized by sulfataric activity, with a large fumarolic field that is mainly located in the summit area. A scanning differential optical absorption spectroscopy instrument designed by the Optical Sensing Group of Chalmers University of Technology in Göteborg, Sweden, was installed in the framework of the European project "Network for Observation of Volcanic and Atmospheric Change", in March 2008. This study presents the first dataset of SO<sub>2</sub> plume fluxes recorded for a closed volcanic system. Between 2008 and 2010, the SO<sub>2</…

Dissolved CO2 in natural waters: development of an automated monitoring system and first application to Stromboli volcano (Italy)

The study of geochemical parameters applied to natural systems has provided improved knowledge of geochemical mechanisms of gas/rock dissolution in natural waters that are linked to gas-water and/or water-rock interaction processes. Here we present the results of our studies focused on the development of an automated monitoring system for measuring the amount of dissolved CO2 in natural waters. The system is based on the principle of a dynamic equilibrium between water and the air as the host gas. The PCO2 measurements were carried out every four hours, and the equilibration time was around 20 minutes. Moreover, application to the thermal aquifer of Stromboli volcano during the 2009-2010 pe…

Effect of solid waste landfill organic pollutants on groundwater in three areas of Sicily (Italy) characterized by different vulnerability

The aim of this study was to obtain information on the presence and levels of hazardous organic pollutants in groundwater located close to solid waste landfills. Eighty-two environmental contaminants, including 16 polycyclic aromatic hydrocarbons (PAHs), 20 volatile organic compounds (VOCs), 29 polychlorinated biphenyls (PCBs), 7 dioxins (polychlorinated dibenzo-p-dioxins, PCDDs) and 10 furans (polychlorinated dibenzofurans, PCDFs) were monitored in areas characterised by different geological environments surrounding three municipal solid waste landfills (Palermo, Siculiana and Ragusa) in Sicily (Italy) in three sampling campaigns. The total concentrations of the 16 PAHs were always below t…

Groundwater radon measurements in the Mt. Etna area.

Radon levels were measured in 119 groundwater samples collected throughout the active volcanic area of Mt. Etna by means of a portable Lucas-type scintillation chamber. The measured activity values range from 1.8 to 52.7 Bq l(-1). About 40% of the samples exceed the maximum contaminant level of 11 Bq l(-1) proposed by the USEPA in 1991. The highest radon levels are measured in the eastern sector of the volcano, which is the seismically most active zone of the volcano. On the contrary the south-western sector, which is both seismically active and a site of intense magmatic degassing, display lower radon levels. This is probably due to the formation of a free gas phase (oversaturation of CO(2…