0000000000648711

AUTHOR

Rodolfo Canet-albiach

showing 3 related works from this author

Optical Contrast and Raman Spectroscopy Techniques Applied to Few-Layer 2D Hexagonal Boron Nitride

2019

The successful integration of few-layer thick hexagonal boron nitride (hBN) into devices based on two-dimensional materials requires fast and non-destructive techniques to quantify their thickness. Optical contrast methods and Raman spectroscopy have been widely used to estimate the thickness of two-dimensional semiconductors and semi-metals. However, they have so far not been applied to two-dimensional insulators. In this work, we demonstrate the ability of optical contrast techniques to estimate the thickness of few-layer hBN on SiO2/Si substrates, which was also measured by atomic force microscopy. Optical contrast of hBN on SiO2/Si substrates exhibits a linear trend with the number of h…

Materials sciencePhononGeneral Chemical Engineering02 engineering and technologySubstrate (electronics)010402 general chemistry01 natural sciencesArticlelcsh:ChemistryCondensed Matter::Materials Sciencesymbols.namesakeAb initio quantum chemistry methodsMonolayerGeneral Materials Scienceoptical contrasttwo-dimensional materialsSpectroscopybusiness.industry021001 nanoscience & nanotechnologyHexagonal boron nitride0104 chemical sciencesSemiconductorlcsh:QD1-999Raman spectroscopysymbolsOptoelectronics0210 nano-technologyRaman spectroscopybusinessLayer (electronics)Nanomaterials
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Two-Dimensional Indium Selenide for Sulphur Vapour Sensing Applications

2020

Surface-to-volume ratio in two-dimensional (2D) materials highlights among their characteristics as an inherent and intrinsic advantage taking into account their strong sensitivity to surface effects. For this reason, we have proposed in this work micromechanically exfoliated 2D nanosheets of InSe as an optical vapour sensor. As a proof of concept, we used 2-mercaptoethanol as the chemical analyte in vapour phase to monitor the change of the InSe photoluminescence (PL) before and after exposure to the analyte. For short vapour exposure times (at low analyte concentration), we found a PL enhancement of InSe nanosheets attributed to the surface localization of Se defects. For long vapour expo…

AnalyteMaterials sciencePhotoluminescencePassivationGeneral Chemical EngineeringDiffusionAnalytical chemistrychemistry.chemical_elementIII-VI semiconductors02 engineering and technology010402 general chemistry01 natural sciencesArticlelcsh:Chemistrychemistry.chemical_compoundPhase (matter)Selenidevapour sensingGeneral Materials ScienceNanosheet021001 nanoscience & nanotechnologytwo-dimensional semiconductors0104 chemical scienceschemistrylcsh:QD1-999InSephotoluminescence0210 nano-technologyIndiumchemical sensorNanomaterials
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Extrinsic Effects on the Optical Properties of Surface Color Defects Generated in Hexagonal Boron Nitride Nanosheets

2021

Hexagonal boron nitride (hBN) is a wide-band gap van der Waals material able to host light-emitting centers behaving as single photon sources. Here, we report the generation of color defects in hBN nanosheets dispersed on different kinds of substrates by thermal treatment processes. The optical properties of these defects have been studied using microspectroscopy techniques and far-field simulations of their light emission. Using these techniques, we have found that subsequent ozone treatments of the deposited hBN nanosheets improve the optical emission properties of created defects, as revealed by their zero-phonon linewidth narrowing and reduction of background emission. Microlocalized co…

QuenchingMaterials sciencePhotoluminescencecolor defectsbusiness.industryThermal treatmentSubstrate (electronics)Dielectric2D materialshexagonal boron nitride; 2D materials; color defects; photoluminescence;interfacessymbols.namesakesymbolsOptoelectronicsphotoluminescenceGeneral Materials ScienceLight emissionhexagonal boron nitridevan der Waals forcePhotonicsbusinessResearch Article
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