6533b871fe1ef96bd12d114c

RESEARCH PRODUCT

Extrinsic Effects on the Optical Properties of Surface Color Defects Generated in Hexagonal Boron Nitride Nanosheets

Setatira GorjiJuan P. Martínez-pastorHamid PashaeiadlRodolfo Canet-albiachGuillermo Muñoz-matutanoMilos NesladekMarie KreĉmarováJuan F. Sánchez-royo

subject

QuenchingMaterials sciencePhotoluminescencecolor defectsbusiness.industryThermal treatmentSubstrate (electronics)Dielectric2D materialshexagonal boron nitride; 2D materials; color defects; photoluminescence;interfacessymbols.namesakesymbolsOptoelectronicsphotoluminescenceGeneral Materials ScienceLight emissionhexagonal boron nitridevan der Waals forcePhotonicsbusinessResearch Article

description

Hexagonal boron nitride (hBN) is a wide-band gap van der Waals material able to host light-emitting centers behaving as single photon sources. Here, we report the generation of color defects in hBN nanosheets dispersed on different kinds of substrates by thermal treatment processes. The optical properties of these defects have been studied using microspectroscopy techniques and far-field simulations of their light emission. Using these techniques, we have found that subsequent ozone treatments of the deposited hBN nanosheets improve the optical emission properties of created defects, as revealed by their zero-phonon linewidth narrowing and reduction of background emission. Microlocalized color defects deposited on dielectric substrates show bright (approximate to 1 MHz) and stable room-temperature light emission with zero-phonon line peak energy varying from 1.56 to 2.27 eV, being the most probable value 2.16 eV. In addition to this, we have observed a substrate dependence of the optical performance of the generated color defects. The energy range of the emitters prepared on gold substrates is strongly reduced, as compared to that observed in dielectric substrates or even alumina. We attribute this effect to the quenching of low-energy color defects (these of energies lower than 1.9 eV) when gold substrates are used, which reveals the surface nature of the defects created in hBN nanosheets. Results described here are important for future quantum light experiments and their integration in photonic chips. Horizon 2020 research and innovation program through the S2QUIP [8204023]; Spanish MINECO [TEC2017-86102-C2-1-R]; S2QUIP project [CPI-18-404, CPI-18-418]; Generalitat Valenciana European Commission; NanoSense through the Flemish Scientific Foundation (FWO)FWOGeneral Electric; Spanish Ministry of Science MICINN AEI [RTI2018-099015-J-I00]; FWOFWO [G0E7417N, G0A0520N]; Quantum Flagship project ASTERIQS [820394]; QuantERA project Q-

yearjournalcountryeditionlanguage
2021-01-01
10.1021/acsami.1c11060http://hdl.handle.net/1942/35923