0000000000919370
AUTHOR
K. M. Kinnunen
Operation of transition-edge sensors with excess thermal noise
The superconducting transition-edge sensor (TES) is currently one of the most attractive choices for ultra-high resolution calorimetry in the keV x-ray band, and is being considered for future ESA and NASA missions. We have performed a study on the noise characteristics of Au/Ti bilayer TESs, at operating temperatures around ~100 mK, with the SQUID readout at 1.5 K. Experimental results indicate that without modifications the back-action noise from the SQUID chip degrades the noise characteristics significantly. We present a simple and effective solution to the problem: by installing an extra shunt resistor which absorbs the excess radiation from the SQUID input, we have reduced the excess …
Gold Nanoparticles on 3D-Printed Filters : From Waste to Catalysts
Three-dimensionally printed solid but highly porous polyamide-12 (PA12) plate-like filters were used as selective adsorbents for capturing tetrachloroaurate from acidic solutions and leachates to prepare PA12–Au composite catalysts. The polyamide-adsorbed tetrachloroaurate can be readily reduced to gold nanoparticles by using sodium borohydride, ascorbic acid, hydrogen peroxide, UV light, or by heating. All reduction methods led to polyamide-anchored nanoparticles with an even size distribution and high dispersion. The particle sizes were somewhat dependent on the reduction method, but the average diameters were typically about 20 nm. Particle sizes were determined by using a combination of…
Broadband Ultrahigh-Resolution Spectroscopy of Particle-Induced X Rays: Extending the Limits of Nondestructive Analysis
Nondestructive analysis (NDA) based on x-ray emission is widely used, for example, in the semiconductor and concrete industries. Here, we demonstrate significant quantitative and qualitative improvements in broadband x-ray NDA by combining particle-induced emission with detection based on superconducting microcalorimeter arrays. We show that the technique offers great promise in the elemental analysis of thin-film and bulk samples, especially in the difficult cases where tens of different elements with nearly overlapping emission lines have to be identified down to trace concentrations. We demonstrate the efficiency and resolving capabilities by spectroscopy of several complex multielement …
Transition-Edge Sensors for Particle Induced X-ray Emission Measurements
In this paper we present a new measurement setup, where a transitionedge sensor detector array is used to detect X-rays in particle induced X-ray emission measurements with a 2 MeV proton beam. Transition-edge sensors offer orders of magnitude improvement in energy resolution compared to conventional silicon or germanium detectors, making it possible to recognize spectral lines in materials analysis that have previously been impossible to resolve, and to get chemical information from the elements. Our sensors are cooled to the operation temperature (65 mK) with a cryogen-free adiabatic demagnetization refrigerator, which houses a specially designed X-ray snout that has a vacuum tight window…
Transition-edge microcalorimeters for X-ray space applications
Abstract In an European Space Agency funded research project, our goal is to develop microbolometer technology for X-ray and far-infrared detection for ESA's future scientific missions. We report results on the X-ray calorimeter, which is based on the superconducting transition of the Ti/Au thermometer strip at about 200 mK. Incident X-rays heat up a Bi absorber, deposited on top of the 400 μm ×400 μm thermometer. The temperature rise of the absorber is measured as a change of the thermometer current with a SQUID operating at 1 K.
Porous 3D Printed Scavenger Filters for Selective Recovery of Precious Metals from Electronic Waste
Selective laser sintering (SLS) 3D printing is used to fabricate highly macroporous ion scavenger filters for recovery of Pd and Pt from electronic waste. The scavengers are printed by using a mixture of polypropylene with 10 wt% of type‐1 anion exchange resin. Porosities and the flow‐through properties of the filters are controlled by adjusting the SLS printing parameters. The cylinder‐shaped filters are used in selective recovery of Pd and Pt from acidic leachate of electronic waste simply by passing the solution through the object. Under such conditions, the scavenger filters are able to capture Pd and Pt as anionic complexes with high efficiency from a solution containing mixture of dif…
Fluctuation superconductivity limited noise in a transition-edge sensor
In order to investigate the origin of the until now unaccounted excess noise and to minimize the uncontrollable phenomena at the transition in X-ray microcalorimeters we have developed superconducting transition-edge sensors into an edgeless geometry, the so-called Corbino disk (CorTES), with superconducting contacts in the centre and at the outer perimeter. The measured rms current noise and its spectral density can be modeled as resistance noise resulting from fluctuations near the equilibrium superconductor-normal metal boundary
Fluctuation-Limited Noise in a Superconducting Transition-Edge Sensor
In order to investigate the origin of the until now unaccounted excess noise and to minimize the uncontrollable phenomena at the transition in x-ray microcalorimeters we have developed superconducting transition-edge sensors into an edgeless geometry, the so-called Corbino disk, with superconducting contacts in the center and at the outer perimeter. The measured rms current noise and its spectral density can be modeled as resistance noise resulting from fluctuations near the equilibrium superconductor-normal metal boundary. Peer reviewed
Normal metal - insulator - superconductor thermometers and coolers with titanium-gold bilayer as the normal metal
We have fabricated superconductor - insulator - normal metal - insulator - superconductor (SINIS) tunnel junctions in which Al acts as the superconductor, AlOx is the insulator, and the normal metal consists of a thin Ti layer (5 nm) covered with a thicker Au layer (40 nm). We have characterized the junctions by measuring their current-voltage curves between 60 mK and 750 mK. For comparison, the same measurements have been performed for a SINIS junction pair whose normal metal is Cu. The Ti-Au bilayer decreases the SINIS tunneling resistance by an order of magnitude compared to junctions where Cu is used as normal metal, made with the same oxidation parameters. The Ti-Au devices are much mo…
Coulomb blockade-based nanothermometry in strong magnetic fields
We have performed experiments to test for the susceptibility to strong magnetic fields of electron tunneling in normal metal -based nanostructures for Coulomb blockade primary thermometry. We have confirmed that, to within our accuracy of about ±1%, the single electron charging -induced zero bias differential resistance maximum is unaffected by the field up to 23 T at temperatures of 0.4–4.2 K. We discuss the simple theoretical basis of this immunity. We also report on the practical limitation at low temperatures imposed by superconductivity of aluminium in small magnetic fields.
Development of an Inductive NIS Thermometer
We have studied an inductive readout for normal metal-insulator-superconductor (NIS) tunnel junctions by using on-chip planar inductors and a DC SQUID (superconducting quantum interference device) to develop a sensitive and fast thermometer for studies of nanoscale heat conduction and bolometry. Our initial results show the feasibility of the concept, with a good sensitivity for temperatures below 1 K for aluminum as the superconductor when voltage biased close to the superconductor energy gap. peerReviewed
Large 256-Pixel X-ray Transition-Edge Sensor Arrays With Mo/TiW/Cu Trilayers
We describe the fabrication and electrical characterization of 256-pixel X-ray transition-edge sensor (TES) arrays intended for materials analysis applications. The processing is done on 6-in wafers, providing capabilities on a commercial scale. TES films were novel proximity coupled Mo/TiW/Cu trilayers, where the thin TiW layer in between aims to improve the stability of the devices by preventing unwanted effects such as Mo/Cu interdiffusion. The absorber elements were electrodeposited gold of thickness 2 μm. The single-pixel design discussed here is the so-called Corbino geometry. Most design goals were successfully met, such as the critical temperature, thermal time constant, and transit…
Simultaneous Noise and Impedance Fitting to Transition-Edge Sensor Data Using Differential Evolution
We discuss a robust method to simultaneously fit a complex multi-body model both to the complex impedance and the noise data for transition-edge sensors. It is based on a differential evolution (DE) algorithm, providing accurate and repeatable results with only a small increase in computational cost compared to the Levenberg–Marquardt (LM) algorithm. Test fits are made using both DE and LM methods, and the results compared with previously determined best fits, with varying initial value deviations and limit ranges for the parameters. The robustness of DE is demonstrated with successful fits even when parameter limits up to a factor of 10 from the known values were used. It is shown that the…
Beating Darwin-Bragg losses in lab-based ultrafast x-ray experiments
The use of low temperature thermal detectors for avoiding Darwin-Bragg losses in lab-based ultrafast experiments has begun. An outline of the background of this new development is offered, showing the relevant history and initiative taken by this work. (C) 2017 Author(s). Funding Agencies|Knut and Alice Wallenberg Foundation; ERC [226136]; Finnish Funding Agency for Technology and Innovation TEKES; Academy of Finland [260880]; NIST Innovations in Measurement Science program; DOE Office of Basic Energy Sciences
Sub-kelvin current amplifier using DC-SQUID
Abstract We have set up a system where a low-noise DC-SQUID is used as a current amplifier. The SQUID output is read using a wide band electronics unit based on the noise cancellation scheme. The SQUID has been installed in a compact Nanoway PDR50 dilution refrigerator, and superconducting transitions of Ti/Au thermometer strips for X-ray calorimeter applications have been measured. We can operate at 100 mK using a SQUID with Pd shunt resistors. Noise and bandwidth results of the setup are presented.