0000000001197939

AUTHOR

Marco Capodici

Bacterial Community Structure of an IFAS-MBRs Wastewater Treatment Plant

TIn this work, the bacterial community putatively involved in BNR events of a UCT-MBMBR pilot plant was elucidated by both culture-dependent and metagenomics DNA analyses. The presence of bacterial isolates belonging to Bacillus (in the anoxic compartment) and to Acinetobacter, Stenotrophomonas, Rhodococcus, Escherichia and Aeromonas (in the aerobic compartment) is in agreement with the nitrification/denitrification processes observed in the plant. Moreover, the study of bacterial community structure by NGS revealed a microbial diversity suggesting a biochemical complexity which can be further explored and exploited to improve UCT-MBMBR plant performance.

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Effect of biomass features on oxygen transfer in conventional activated sludge and membrane bioreactor systems

Abstract The aim of the present study was to compare the oxygen transfer efficiency in a conventional activated sludge and a membrane bioreactor system. The oxygen transfer was evaluated by means of the oxygen transfer coefficient and α-factor calculation, under different total suspended solids concentration, extracellular polymeric substances, sludge apparent viscosity and size of the flocs. The oxygen transfer coefficient and α-factor showed an exponential decreasing trend with total suspended solid, with a stronger oxygen transfer coefficient dependence in the conventional activated sludge compared to the membrane bioreactor. It was noted that the oxygen transfer coefficient in the conve…

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IL NOCCIOLINO DI OLIVE COME SUBSTRATO ORGANICO PER LA DENITRIFICAZIONE BIOLOGICA DELLE ACQUE DI FALDA

La denitrificazione biologica come trattamento in situ delle falde contaminate ha riscosso grande interesse negli ultimi decenni; coniuga l’efficacia di rimozione ai costi relativamente contenuti se , confrontati con altre metodiche di intervento. La resa di tale tecnologia di trattamento è fortemente condizionata dalla scelta del materiale reattivo che fornisce il carbonio organico necessario a sostenere il processo. Diversi studi hanno evidenziato la possibilità di operare la denitrificazione biologica a partire da substrati di natura legnosa (segatura, corteccia, etc.). In tale ottica, la nota presenta i risultati preliminari ottenuti utilizzando come substrato il nocciolino di olive tri…

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The effect of the solids and hydraulic retention time on moving bed membrane bioreactor performance

Abstract The aim of the present paper was to investigate the effect of solids (SRT) and hydraulic (HRT) retention time on Integrated Fixed Film Activated Sludge (IFAS) University of Cape Town (UCT) membrane Bioreactor (MBR). In particular, three different pairs of SRT and HRT values were analysed, namely, Phase I 56 d/30 h, Phase II 31 d/15 h and Phase III 7 d/13 h. The short-term effect of these three SRT/HRT conditions was assessed by analysing several system performance indicators: organic carbon and biological nutrient (nitrogen and phosphorus) removal, biomass respiratory activity, activated sludge filtration properties and membrane fouling. The results showed that the decrease of SRT/…

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Moving bed membrane bioreactors for carbon and nutrient removal: The effect of C/N variation

In this paper, an experimental campaign was carried out on a University of Cape Town Integrated Fixed Film Activated Sludge Membrane Bioreactor (UCT-IFAS-MBR) pilot plant. The aim of the study was to evaluate the effect of the influent C/N ratio on the system performance in terms of organic carbon, nitrogen and phosphorus removal, biomass viability (through respirometry), activated sludge features and membrane filtration properties. The experiments were organized into three phases, characterized by a variation of the C/N ratio (namely, Phase I: C/N= 5, Phase II: C/N =10; Phase III: C/N = 2). The results highlighted that the system performance was significantly affected by C/N ratio. The rem…

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BIOLOGICAL DENITRIFICATION OF GROUNDWATER: BIO-PRB COLUMN TEST PERFORMANCES EVALUATION

The occurrence of nitrates in groundwater is steadily raising concern due to possible health consequences of nitrate ingestion. Biological denitrification in BIO-PRB is the enhancement of a natural process that occurs naturally when bacteria live in an environment void of oxygen with carbon availability. Bio-PRB represent a perspective of development for PRB technique but, despite the fact that this technology has already been widely used for chlorinated solvents, data on denitrification PRBs are still scarce. This paper reports on the results of an experimental study carried out for 214 days on a bench-scale pilot column (10 cm in internal diameter and 100 cm in length with sampling ports …

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Pilot scale experiment with MBR operated in intermittent aeration condition: analysis of biological performance.

The effect of intermittent aeration (IA) on a MBR system was investigated. The study was aimed at ana- lyzing different working conditions and the influence of different IA cycles on the biological performance of the MBR pilot plant, in terms of organic carbon and ammonium removal as well as extracellular poly- meric substances (EPSs) production. The membrane modules were placed in a separate compartment, continuously aerated. This configuration allowed to disconnect from the filtration stage the biological phenomena occurring into the IA bioreactor. The observed results highlighted good efficiencies, in terms of organic carbon and ammonium removal. It was noticed a significant soluble micr…

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Biological groundwater denitrification systems: Lab-scale trials aimed at nitrous oxide production and emission assessment

Bio-trenches are a sustainable option for treating nitrate contamination in groundwater. However, a possible side effect of this technology is the production of nitrous oxide, a greenhouse gas that can be found both dissolved in the liquid effluent as well as emitted as off gas. The aim of this study was to analyze NO3 − removal and N2O production in lab-scale column trials. The column contained olive nut as organic carbon media. The experimental study was divided into three phases (I, II and III) each characterized by different inlet NO3 − concentrations (30, 50, 75 mg NO3-N L−1 respectively). Sampling ports deployed along the length of the column allowed to observe the denitrification pro…

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High salinity slops treatment through a biofilm-MBR inoculated with halophilic bacteria

Oily wastewater generated, in amounts of millions of tons per year, by ships mainly in engine-rooms (bilge waters) and by washing oil tanks (slops) create a major disposal problem throughout the world because of the persistence and accumulation of xenobiotic compounds in the environment. The high salinity levels (up to 25.000 p.p.m.) and the pollutants concentration limit the chances of discharge into the sewer systems and address the disposal to the sea. This situation severely lowers the discharge limits for most of the “sensible” parameters, such both COD and hydrocarbons. Slops are usually treated by ASP with pretreatment of oil/water separation. There are limited investigations on the …

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Respirometry for the Characterization of Heterotrophic Biomass Activity: Application to a MBR Pilot Plant Operated with Two Different Start-Up Strategies

A membrane bioreactor (MBR) pilot plant was operated in two subsequent experimental periods (namely, Periods I and II) with different start-up and sludge withdrawal strategies to study its peculiar biokinetic behavior by using respirometric techniques. Two extreme operational conditions were chosen to investigate the different biomass activity under dynamic or pseudostationary conditions during and after the start-up phases. Particularly, the MBR pilot plant was operated with the same volumetric loading rate (VLR) and permeate flux but differently managed during the start-up phase. In Period I, the MBR pilot plant was started up without sludge inoculum and operated without sludge withdrawal…

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Batch Test Evaluation of Four Organic Substrates Suitable for Biological Groundwater Denitrification

Nitrates pollution represents nowadays a serious issue related to the quality of groundwater; continuous growth of industrial-scale agricultures lead to an increase of nitrates content in groundwater in the last years. Several technologies have been validated as capable to promote in situ biological nitrates remediation, such as permeable reactive barriers (PRB), biotrench, biobarriers etc. These technologies are all characterised by the use of organic substrate that act as a slow release carbon source. In free dissolved oxygen absence, such organic carbon is further oxidised, by heterotrophic bacteria naturally present in soil, in compliance to anoxic metabolism by using nitrates bound oxy…

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Achievement of partial nitrification under different carbon-to-nitrogen ratio and ammonia loading rate for the co-treatment of landfill leachate with municipal wastewater

Abstract Partial nitrification (PN) is a technically and economically effective solution for the treatment of wastewater featuring low C/N ratio, allowing to achieve approximately 25% energy saving and 40% carbon source for denitrification. This study investigated the effect of different carbon to nitrogen ratio (C/N) and ammonia loading rate (ALR) on PN performances in a sequencing batch reactor (SBR) treating landfill leachate with municipal wastewater. The aim was to find an optimum range for C/N and ALR to maximize PN performances. Results demonstrated that a proper balancing between ALR and C/N is crucial to achieve high PN efficiency. The results highlighted the existence of an optimu…

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CO-TREATMENT OF LANDFILL LEACHATE IN SBR SYSTEM: LAB-SCALE CASE STUDY REPORT

SUMMARY: Landfill leachate represents nowadays one of the most controversial topics in the waste management cycle. A possible alternative for treating aged landfill leachate is represented by the co-treatment with municipal wastewater (MWW) that provides the necessary amount of biodegradable substances to enhance the development of bacteria metabolism. The correct tradeoff between landfill leachate and MWW represent a key factor in order to avoid inhibition of biomass activity. The paper reports the results of an experimental research carried out on two lab-scale Sequencing Batch Reactors (SBRs) fed with synthetic wastewater and landfill leachate in different percentages (SBR1 fed with 20% …

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Effect of chemical and biological surfactants on activated sludge of MBR system: Microscopic analysis and foam test

Abstract A bench-scale MBR unit was operated, under stressing condition, with the aim of stimulating the onset of foaming in the activated sludge. Possible synergies between synthetic surfactants in the wastewater and biological surfactants (Extra-Cellular Polymeric Substances, EPSs) were investigated by changing C/N ratio. The growth of filamentous bacteria was also discussed. The MBR unit provided satisfactory overall carbon removal overall efficiencies: in particular, synthetic surfactants were removed with efficiency higher than 90% and 95% for non-ionic and ionic surfactants, respectively. Lab investigation suggested also the importance to reduce synthetic surfactants presence entering…

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Uso del nocciolino di oliva come materiale di riempimento di biotrincee per la denitrificazione biologica in situ di acque di falda

Tra le varie possibilità di intervento per la rimozione dei nitrati dalle acque di falda, notevole interesse suscita il trattamento in situ dei plume contaminati mediante la realizzazione di biotrincee denitrificanti scavate in situ e naturalmente attraversate dalle acque di falda. Tra i materiali di origine organica che sono stati testati per tali applicazioni, il nocciolino di olive è risultato uno dei più idonei alle potenziali applicazioni di pieno campo. Tale tipo di materiale possiede un elevato contenuto di carbonio organico totale, prossimo al 50%, e una percentuale di lignina prossima al 45% in peso. Il lavoro proposto riporta i risultati di una campagna sperimentale eseguita media…

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Combination of the OSA process with thermal treatment at moderate temperature for excess sludge minimization

Abstract This study investigated the chance to couple the conventional Oxic Settling Anaerobic (OSA) process with a thermic treatment at moderate temperature (35 °C). The maximum excess sludge reduction rate (80%) was achieved when the plant was operated under 3 h of hydraulic retention time (HRT). Compared with the conventional OSA system, the thermic treatment enabled a further improvement in excess sludge minimization of 35%. The observed yield coefficient decreased from 0.25 gTSS gCOD−1 to 0.10 gTSS gCOD−1 when the temperature in the anaerobic reactor was increased to 35 °C, despite the lower HRT (3 h vs 6 h). Moreover, the thermic treatment enabled the decrease of filamentous bacteria,…

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Sequential Batch Membrane BioReactor treating saline wastewater

A sequential batch membrane bioreactor treating high strength salinity wastewater has been investigated. The salt effects on carbon and nutrient removal, fouling behaviour as well as biomass kinetics have been analysed. Salinity was increased at step of 2 g NaCl L-1 per week. The total COD removal efficiency was high (93%) along the entire experimental campaign. However, the biological contribution on the COD removal efficiency was reduced with the increase of salinity. The lowest nitrification removal efficiency (63%) was obtained at 10 g NaCl L-1 salinity due to the lower nitrifier activity. Regarding membrane fouling, the irreversible cake deposition was the predominant fouling mechanism…

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Analisi di processo e dinamica della comunità batterica nel trattamento di sedimenti marini con reattori bioslurry

Nella nota sono riportati i risultati di una sperimentazione condotta mediante la messa in esercizio di un reattore bioslurry per il trattamento di sedimenti marini contaminati da idrocarburi. Sono state valutate le performance di processo in termini di rimozione di TPH (86% con velocità di rimozione massima di 36 mgTPH kg-1 d-1) congiuntamente ad altre tipologie di indagini volte ad ottenere maggiori informazioni sulla natura dei processi che si sono sviluppati nel reattore. Nello specifico, è stato utilizzato un approccio di tipo microbiologico mediante l’adozione di una tecnica di sequenziamento di nuova generazione (NGS - Next Generation Sequencing). Dall’analisi dei dati biologici è st…

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The influence of solid retention time on IFAS-MBR systems: analysis of system behavior.

A University of Cape Town Integrated Fixed-Film Activated Sludge Membrane Bioreactor (UCT-IFAS-MBR) pilot plant was operated at different values of the sludge retention time (SRT). Three SRTs were investigated at different durations: indefinitely, 30 and 15 days. The organic carbon, nitrogen and phosphorus removal, kinetic/stoichiometric parameters, membrane fouling tendency and sludge filtration properties were assessed. The findings showed that by decreasing the SRT, the pilot plant could maintain excellent carbon removal efficiencies throughout the experiments. In contrast, the biological carbon removal showed a slight nitrification and was slightly affected by the decrease of the SRT, s…

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TREATMENT OF LANDFILL LEACHATE IN SBR SYSTEMS: ANALYSIS OF BIOMASS ACTIVITY BY MEANS OF RESPIROMETRIC TECHNIQUES

In the last decades landfilling has been the main method of municipal solid waste (MSW) disposal in many countries. MSW landfills are usually considered as a large biological reactor where the MSWs undergo anaerobic digestion producing gas and liquid emissions. Aged, or mature leachate, which is produced by older landfills, can be very refractory; for this reason mature leachate is difficult to treat alone, but it can be co-treated with sewage or domestic wastewater. The aim of the study was to investigate the feasibility of co-treatment of landfill leachate and synthetic wastewater in different percentages, in terms of process performance and biomass activity, by means of respirometric tec…

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Respirometric assessment of heterotrophic and autotrophic biomass activity in alternate oxic-anoxic MBR pilot plant

The paper reports the main results of an experimental study carried out on a Membrane Biological Reactor (MBR) pilot plant characterized by intermittent aeration. The effect of different aeration/non aeration ratio (TA/TNA) on biomass behavior, in terms of heterotrophic and autotrophic kinetic parameters and active biomass fraction, was studied. Moreover was proposed a method to evaluate the autotrophic active fraction, derived by a combination of the ASM1 model and biokinetic parameters directly evaluated by means of respirometry. The experimental observation outlined that TA/TNA in the cycle didn’t affect heterotrophic biomass kinetic and active fraction. This one instead, resulted strong…

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Sequential batch membrane bio-reactor for wastewater treatment: The effect of increased salinity

In this work, a sequential batch membrane bioreactor pilot plant is investigated to analyze the effect of a gradual increase in salinity on carbon and nutrient removal, membrane fouling and biomass kinetic parameters. The salinity was increased by 2 g NaCl L-1 per week up to 10 g NaCl L-1. The total COD removal efficiency was quite high (93%) throughout the experiment. A gradual biomass acclimation to the salinity level was observed during the experiment, highlighting the good recovery capabilities of the system. Nitrification was also influenced by the increase in salinity, with a slight decrease in nitrification efficiency (the lowest value was obtained at 10 g NaCl L-1 due to lower nitri…

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Biokinetic Behaviour of Autochthonous Halophilic Biomass at Different Salinity: Comparison Between Activated Sludge and Granular Sludge Systems

The main goal of this study was the evaluation of the impact of increasing salinity on halophilic biomass in forms of flocculent and granular sludge for the treatment of hypersaline fish-canning wastewater, focusing on the metabolic behavior of autotrophic biomass. For this purpose, two sequencing batch reactors, one with aerobic granular sludge (GSBR) and the other with flocculent activated sludge (SBR) were monitored. In both reactors, a halophilic biomass was cultivated from a real saline wastewater collected from a fish-canning industry. The salt concentration was stepwise increased (2 gNaCl L-1) from 30 gNaCl L-1 to 50 gNaCl L-1. Therefore, ammonia and nitrite uptake rates for granular…

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The sludge dewaterability in membrane bioreactors

The influence of the sludge origin on the dewaterability features has been investigated by comparing the experimental results of six membrane bioreactor pilot plants with different configurations. The capillary suction time (CST) and the specific resistance to filtration (SRF), identified as representative of sludge dewaterability features, were measured. The results were related to operational parameters, such as extracellular polymeric substances (EPS) and soluble microbial product (SMP), influent salinity and hydrocarbon, in order to elucidate the influence exerted on the dewaterability. Furthermore, the effect of biofilm and suspended biomass was also investigated. The results showed th…

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Membrane bioreactors for treatment of saline wastewater contaminated by hydrocarbons (diesel fuel): An experimental pilot plant case study

Abstract The paper reports the main results of an experimental campaign performed on a membrane bioreactor pilot plant designed to treat synthetic shipboard slops. The experimental campaign was divided into two phases: salinity acclimation up to 20 g NaCl L −1 (Phase I) and hydrocarbon (diesel fuel) dosing (Phase II). The observed results show that the carbon removal was not severely affected by the wastewater features. Conversely, respirometric tests showed that nitrification was strongly affected by the salinity (33% of nitrification efficiency at 20 g NaCl L −1 – Phase I) as a result of the salinity in the autotrophic biomass. Moreover, the sludge viscosity increased during Phase II due …

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Test in colonna per la denitrificazione delle acque di falda: studio del comportamento di tre differenti substrati organici

Il crescente impiego di fertilizzanti contenenti azoto ha avuto come effetto l'accumulo di nitrati nelle acque di falda. A causa della natura diffusa delle sorgenti di contaminazione, la necessità di individuare interventi di risanamento a basso costo e che richiedano attività gestionali ridotte è diventata prioritaria. In tale ottica, notevole interesse hanno recentemente riscosso i trattamenti biologici in situ, in grado di promuovere le denitrificazione delle acque di falda mediante la realizzazione di biobarriere. Nella nota vengono riportati i risultati di una ricerca sul processo di denitrificazione eterotrofa promosso utilizzando come fonte di carbonio tre materiali convenzionalmente…

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INCIDENZA SULL’ANALISI DI RISCHIO DELLE MODALITÁ DI MISURA DEI SOIL GAS: IL CASO DI UN S.I.N. SICILIANO

Il monitoraggio delle matrici aeriformi sta assumendo importanza crescente nell’ambito dei procedimenti di bonifica di siti contaminati, con riferimento sia all’esecuzione delle analisi di rischio, sia alla conseguente progettazione degli interventi di risanamento. L’utilizzo di misure dirette di campo si rivela di notevole interesse per la verifica di quelle indirette, ottenute con gli algoritmi implementati nei modelli matematici utilizzati per l’analisi di rischio. Obiettivo del lavoro presentato nella nota è stato quello di valutare l’influenza di misure dirette di soil gas e di flussi emissivi sull’analisi di rischio sanitaria. Come caso studio, si è considerato un S.I.N. nel territori…

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UCT-MBR vs IFAS-UCT-MBR for Wastewater Treatment: A Comprehensive Comparison Including N2O Emission

In this study the performance (in terms of carbon and nutrient removal) and N2O emission of two plant configurations adopting innovative technologies were investigated. With this regards, an University Cape Town (UCT) membrane bioreactor (MBR) plant and an Integrated Fixed Film Activated Sludge (IFAS) -UCT-MBR plant were monitored. Both plants treat real wastewater under two different values of the influent carbon nitrogen ratio (C/N = 5 mgCOD/mgN and C/N = 10 mgCOD/mgN). Results have shown the highest carbon and nutrients removal efficiencies for the IFAS-UCT-MBR configuration during both the two investigated C/N values. Furthermore, the lowest N2O emission occurred for the IFAS-UCT-MBR.

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Influence of carbon to nitrogen ratio on nitrous oxide emission in an Integrated Fixed Film Activated Sludge Membrane BioReactor plant

Abstract In this study a University of Cape Town (UCT) Integrated Fixed Film Activated Sludge (IFAS) Membrane BioReactor (MBR) wastewater treatment plant was monitored in terms of nitrous oxide (N2O) emissions. The short term effect on the N2O emission due to the influent carbon-to-nitrogen (C/N) ratio variation (C/N ratios of 2, 5 and 10 gCOD/gN) was evaluated. Since in a previous study, the effect of the C/N ratio was studied in the same system without biofilm (UCT-MBR configuration) the main aim here was to investigate the role of biofilms on N2O emissions. Under all the investigated C/N ratios, the N2O fluxes and the average emission factors were lower than that of previous studies with…

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Optimization of acetate production from citrus wastewater fermentation

Abstract Citrus wastewater is a sugar-rich waste stream suitable for the recovery of energy of material from its treatment. In this study, fermentation of citrus wastewater was carried out to assess the optimal conditions to maximize the bioconversion of the organic substrate into acetate. Unbalanced nutrient (C: N: P 200:0.1:0.1) enabled the highest acetate production. The presence of the particulate organic fraction enabled to obtain a higher acetate concentration regardless the initial COD concentration. Initial pH values higher than 5 did not cause substantial differences on the maximum bioconversion of COD into acetate in Trial 3, whereas pH lower than 5 hindered the hydrolysis process…

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Nitrous oxide emission from a moving bed membrane biofilm reactor: the effect of the sludge retention time

The aim of the present study was to investigate the nitrous oxide (N2O) emissions from a University of Cape Town (UCT) moving bed membrane bioreactor pilot plant. An experimental campaign was carried out during 60 days with three different sludge retention time (SRT). The pilot plant reactor was provided of funnel shape covers that guaranteed gas accumulation in the headspace. The results highlighted that N2O concentrations significantly increased when the biofilm concentrations increased within the aerobic and anoxic compartments. Furthermore, results have shown an increase of N2O with the decrease of SRT. Moreover, the MBR tank resulted the key emission source (up to 70% of the total N2O …

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Fate of aerobic granular sludge in the long-term: The role of EPSs on the clogging of granular sludge porosity

This work aims to investigate the stability of aerobic granular sludge in the long term, focusing on the clogging of the granular sludge porosity exerted by the extracellular polymeric substances (EPSs). The effects of different cycle lengths (short and long-term cycle) on the granular sludge stability were investigated. Results obtained outlined that during the short duration cycle, the formation and breakage of the aerobic granules were continuously observed. During this period, the excess of EPS production contributed to the clogging of the granules porosity, causing their breakage in the long run. During the long-duration cycle, the extended famine period entailed a greater EPSs consump…

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The influence of solid retention time on IFAS-MBR systems: Assessment of nitrous oxide emission

The aim of the present study was to investigate the nitrous oxide (N2O) emissions from a moving bed based Integrated Fixed Film Activated Sludge (IFAS) - membrane bioreactor (MBR) pilot plant, designed according to the University of Cape Town (UCT) layout. The experimental campaign had a duration of 110 days and was characterized by three different sludge retention time (SRT) values (∞, 30 d and 15 d). Results highlighted that N2O concentrations decreased when the biofilm concentrations increased within the aerobic reactor. Results have shown an increase of N2O with the decrease of SRT. Specifically, an increase of N2O-N emission factor occurred with the decrease of the SRT (0.13%, 0.21% …

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Integrated Fixed Film Activated Sludge (IFAS) membrane BioReactor: The influence of the operational parameters

Abstract The present paper investigated an Integrated Fixed Film Activated Sludge (IFAS) Membrane BioReactor (MBR) system monitored for 340 days. In particular, the short-term effects of some operational parameters variation was evaluated. Results showed a decrease of the removal rates under low C/N values. Respirometry results highlighted that activated sludge was more active in the organic carbon removal. Conversely, biofilm has a key role during nitrification. The major fouling mechanism was represented by the cake deposition (irreversible).

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Dewatering of excess sludge produced by CAS and MBR aerobic treatment plants. effects of biochemical stability and EPS composition

This paper investigates the behavior of different sludges from several treatment plants at full and pilot scale configured as Conventional Activated Sludge (CAS) and Membrane Bio Reactor (MBR) plants treating different kinds of wastewaters. The sludges collected were subjected to complete analytical and technological characterization in order to correlate the rheological properties that affect the dewatering behavior to the sludge chemical physical properties. In detail the EPS from the samples collected is extracted and characterized in terms of carbohydrates, proteins, uronic acids and humic acids content. Moreover, once characterized, the sludges were subjected to AD in order to assess t…

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Preliminary insights about the treatment of contaminated marine sediments by means of bioslurry reactor: Process evaluation and microbiological characterization

Abstract Contaminated marine sediments represent a critical threat towards human health and ecosystems, since they constitute a potential reservoir of toxic compounds release. In the present study, a bioslurry reactor was studied for the treatment of real marine sediments contaminated by petroleum hydrocarbons. The experimental campaign was divided in two periods: in the first period, microcosm trials were carried out to achieve useful indicators for biological hydrocarbon removal from sediments. The microcosm trials highlighted that the inoculum of halotolerant allochthonous bacteria provided the highest performance followed by autochthonous biomass. Based on the achieved results, in the s…

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High salinity wastewater treatment by membrane bioreactors

Abstract This chapter reviews the state of the art regarding the use of membrane bioreactor (MBR) systems for saline wastewater treatment. In particular, a comprehensive review is presented discussing the most adopted MBR configurations for the treatment of saline wastewater. Further, the chapter discusses the main effects of salinity on the biological performance, kinetic parameters, fouling development, sludge rheological features, and greenhouse gas (GHG) production. Literature results show that there is a significant effect of the salinity (and/or salinity variations) on the biological performance and membrane filtration. Specifically, it was found that a gradual salinity increase, carr…

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La denitrificazione biologica delle acque di falda: studio di tre differenti substrati organici

L’uso massiccio di fertilizzanti contenenti azoto è causa dei fenomeni di inquinamento diffuso delle acque di falda. In tale ottica, notevole interesse hanno recentemente riscosso i trattamenti biologici in situ, in grado di promuovere la denitrificazione delle acque di falda mediante la realizzazione di interventi che coniugano efficacia di rimozione e costi relativamente contenuti. Nella nota si riportano i risultati di una ricerca sul processo di denitrificazione eterotrofa, condotta utilizzando come fonte di carbonio tre materiali convenzionalmente considerati di scarto: corteccia di pino, sughero e sansa di olive. Lo studio è stato suddiviso in due fasi: la prima condotta in modalità b…

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Nitrous oxide from moving bed based integrated fixed film activated sludge membrane bioreactors

Abstract The present paper reports the results of a nitrous oxide (N 2 O) production investigation in a moving bed based integrated fixed film activated sludge (IFAS) membrane bioreactor (MBR) pilot plant designed in accordance with the University of Cape Town layout for biological phosphorous removal. Gaseous and liquid samples were collected in order to measure the gaseous as well as the dissolved concentration of N 2 O. Furthermore, the gas flow rate from each reactor was measured and the gas flux was estimated. The results confirmed that the anoxic reactor represents the main source of nitrous oxide production. A significant production of N 2 O was, however, also found in the anaerobic …

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Comparison between kinetics of autochthonous marine bacteria in activated sludge and granular sludge systems at different salinity and SRTs.

Biological nutrient removal performances and kinetics of autochthonous marine biomass in forms of activated sludge and aerobic granular sludge were investigated under different salinity and sludge retention time (SRT). Both the biomasses, cultivated from a fish-canning wastewater, were subjected to stepwise increases in salinity (+2 gNaCl L−1), from 30 gNaCl L−1 up to 50 gNaCl L−1 with the aim to evaluate the maximum potential in withstanding salinity by the autochthonous marine biomass. Microbial marine species belonging to the genus of Cryomorphaceae and of Rhodobacteraceae were found dominant in both the systems at the maximum salinity tested (50 gNaCl L−1). The organic carbon was remove…

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Shortcut nitrification-denitrification by means of autochthonous halophilic biomass in an SBR treating fish-canning wastewater

Abstract Autochthonous halophilic biomass was cultivated in a sequencing batch reactor (SBR) aimed at analyzing the potential use of autochthonous halophilic activated sludge in treating saline industrial wastewater. Despite the high salt concentration (30 g NaCl L −1 ), biological oxygen demand (BOD) and total suspended solids (TSS), removal efficiencies were higher than 90%. More than 95% of the nitrogen was removed via a shortcut nitrification-denitrification process. Both the autotrophic and heterotrophic biomass samples exhibited high biological activity. The use of autochthonous halophilic biomass led to high-quality effluent and helped to manage the issues related to nitrogen removal…

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Co-treatment of landfill leachate in laboratory-scale sequencing batch reactors: analysis of system performance and biomass activity by means of respirometric techniques

Aged or mature leachate, produced by old landfills, can be very refractory; for this reason mature leachate is difficult to treat alone, but it can be co-treated with sewage or domestic wastewater. The aim of the study was to investigate the feasibility of leachate co-treatment with synthetic wastewater, in terms of process performance and biomass activity, by means of respirometric techniques. Two sequencing batch reactors (SBRs), named SBR1 and SBR2, were fed with synthetic wastewater and two different percentages of landfill leachate (respectively 10% and 50% v v−1 in SBR1 and SBR2). The results showed good chemical oxygen demand (COD) removal efficiency for both reactors, with average C…

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Dewaterability of CAS and MBR Sludge: Effect of Biological Stability and EPS Composition

The dewaterability of sludge from two conventional activated sludge (CAS) and three membrane bioreactor (MBR)-based wastewater treatment plants is investigated prior to and after anaerobic digestion. The concentration and composition of extracellular polymeric substances (EPS) mostly affect the dewaterability of all raw sludge samples. Better sludge dewaterability is observed when the concentration of proteins, carbohydrates, uronic acids, and humic acids is below approximately 400, 250, 200, and 40 mg/L, respectively. In contrast, the specific resistance to filtration (SRF) increases in the sludge samples with a higher EPS concentration. The MBR results in a lower EPS production and a uron…

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Foaming in membrane bioreactor: identification of the causes

The biological foaming was related to the metabolism of certain microorganisms that synthesize and excrete hydrophobic compounds. Recently, by the attention of many researchers the biological foaming in the MBR has attracted, because MBR foam has been also observed in the absence of foam-forming microorganisms, contrarily to conventional activated sludge systems. In this paper the authors investigate the role of EPS and filamentous bacteria analyzing different samples from different MBR pilot plants. In particular, in order to define the macroscopic features and the role of EPS and filamentous bacteria a modified Scum Index (MSI) test was applied. Further a multiple classification of SI was…

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DENITRIFICAZIONE BIOLOGICA DELLE ACQUE DI FALDA MEDIANTE L’USO DI BARRIERE REATTIVE PERMEABILI

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Waste activated sludge dewaterability: comparative evaluation of sludge derived from CAS and MBR systems

Nowadays, sludge dewatering is one of the greatest operational cost to wastewater treatment cycle. Specifically, 1t of fresh sludge to be disposed is composed, on average, by 0.25 - 0.30t of suspended solids, with an average cost for treatment and disposal around 280 - 470 €/t of suspended solids. Despite several technologies have been developed with the focus to reduce also the specific sludge production, still mechanical dewatering represents a crucial step to limit the amount of sludge to be disposed. Many physical–chemical parameters influence the sludge dewaterability: floc structure, particle size, bound water content, surface charge and hydrophobicity, Extracellular Polymeric Substan…

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Influenza della copertura superficiale sulle emissioni diffuse di metano da discarica: analisi di casi studio

La quantizzazione delle emissioni di CH4 da discariche rappresenta un tema di rilievo nella gestione dei rifiuti. La capacità emissiva delle discariche, direttamente correlata alla decomposizione anaerobica della sostanza organica in esse smaltita, può durare per decine di anni sebbene la massima produzione di biogas si registra nei primi anni seguenti l’abbancamento dei rifiuti. Nella nota si riferisce dei risultati di alcune campagne di misura eseguite su discariche controllate per rifiuti urbani, dotate di differente tipo di copertura; in particolare, la prima discarica è dotata di capping definitivo, la seconda di capping temporaneo. I risultati ottenuti hanno evidenziato una significat…

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Assessment of landfill leachate biodegradability and treatability by means of allochthonous and autochthonous biomasses

Abstract The biodegradability and treatability of a young (3 years old) municipal landfill leachate was evaluated by means of chemical oxygen demand (COD) fractionation tests, based on respirometric techniques. The tests were performed using two different biomasses: one cultivated from the raw leachate (autochthonous biomass) and the other collected from a conventional municipal wastewater treatment plant after its acclimation to leachate (allochthonous biomass). The long term performances of the two biomasses were also studied. The results demonstrated that the amount of biodegradable COD in the leachate was strictly dependent on the biomass that was used to perform the fractionation tests…

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THE USE OF MBR SYSTEMS FOR THE TREATMENT OF REAL SHIPBOARD SLOPS: ANALYSIS OF BIOLOGICAL PERFORMANCE AND BIOMASS BIOKINETIC ACTIVITY

In order to prevent hydrocarbon discharge at sea from ships, the International Maritime Organization (IMO) enacted the MARPOL 73/78 convention in which any oil and oil residue discharged in wastewater streams must contain less than 5 ppm hydrocarbons. Effective treatment of this petroleum-contaminated water is essential prior to its release into the environment, in order to prevent pollution problem for marine ecosystems as well as for human health. The present paper reports the first results of a field gathering campaign aimed at gaining insight about the treatment of real shipboard slops with a MBR pilot plant, in terms of pilot performance and biomass biokinetic activity. The achieved re…

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Carbon and nutrient biological removal in a University of Cape Town membrane bioreactor: Analysis of a pilot plant operated under two different C/N ratios

Abstract The effect of the carbon-to-nitrogen (C/N) ratio variation in a University of Cape Town Membrane bioreactor (UCT-MBR) was investigated. The experimental campaign was divided into two phases, each characterized by a different C/N ratio (namely, 10 and 5, Phase I and Phase II, respectively). The UCT-MBR pilot plant was analysed in terms of carbon and nutrients removal, biomass respiratory activity, activated sludge features and membrane fouling. The results highlighted that the nutrients removal was significantly affected by the decrease of the C/N ratio during the Phase II. The biological carbon removal was also affected by the low C/N value during the Phase II. Indeed, the average …

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Treatment of Oily Wastewater with Membrane Bioreactor Systems

The aim of the present work was to investigate the behavior of a membrane bioreactor (MBR) system for the treatment of oily wastewater. A bench scale MBR was fed with synthetic wastewater containing diesel fuel. Organic carbon, hydrocarbon and ammonium removal, kinetic constants, extracellular polymeric substances production, and membrane fouling rates were monitored. The MBR plant was operated for more than 200 days, and the results highlighted good carbon removal and nitrification, suggesting a sort of biomass adaptation to hydrocarbons. Membrane fouling analysis showed an increase in total resistance, likely due to hydrocarbons, which caused an irreversible fouling (pore blocking) mainly…

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Nitrous oxide from integrated fixed-film activated sludge membrane bioreactor: Assessing the influence of operational variables

The influence of the main operational variables on N2O emissions from an Integrated Fixed Film Activated Sludge University of Cape Town membrane Bioreactor pilot plant was studied. Nine operational cycles (total duration: 340 days) were investigated by varying the value of the mixed liquor sludge retention time (SRT) (Cycles 1–3), the feeding ratio between carbon and nitrogen (C/N) (Cycles 4–6) and simultaneously the hydraulic retention time (HRT) and the SRT (Cycles 7–9). Results show a huge variability of the N2O concentration in liquid and off-gas samples (ranged from 10−1μg N2O-N L−1to 103μg N2O-N L−1). The maximum N2O concentration (1228 μg N2O-N L−1) in the off-gas sa…

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Greenhouse Gas Emissions from Membrane Bioreactors

Nowadays, it is widely accepted that wastewater treatment plants (WWTPs) are significant sources of greenhouse gas (GHG) emission, contributing to the anthropogenic sources. Among the GHG emitted from WWTPs, nitrous oxide (N2O) has been identified of having the major interest/concern, since its high global warming potential (GWP), is 298 times higher than that of CO2 and also to its capability to react with stratospheric ozone causing the layer depletion. Up to now, most of the experimental investigations have been carried out on conventional activated sludge (CAS) processes. The knowledge of N2O emission from advanced technologies such membrane bioreactors (MBRs) is still very limited. The…

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Solids and Hydraulic Retention Time Effect on N2O Emission from Moving-Bed Membrane Bioreactors

Biological nutrient removal was operated at different solids (SRT) and hydraulic retention times (HRT) in order to assess their influence on nitrous oxide (N2O) emission from a hybrid moving-bed membrane bioreactor. The observed results show that the N2O production decreased when the SRT/HRT was decreased. The maximum N2O gaseous concentration was measured in the aerobic reactor at the end of phase I, and it decreased through phases II and III. From mass balances over the reactors of the system, the aerated (aerobic and membrane) reactors were the largest producers of N2O, showing that the greater part of N2O was produced during the nitrification process.

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Integrated fixed-film activated sludge membrane bioreactors versus membrane bioreactors for nutrient removal: A comprehensive comparison

Abstract This research elucidates the pollutants (nutrients and carbon) removal performance and nitrous oxide (N2O) emissions of two pilot plants. Specifically, a University of Cape Town (UCT) Membrane Bioreactor (MBR) plant and an Integrated Fixed Film Activated Sludge (IFAS)-UCT-MBR plant were investigated. The plants were fed with real wastewater augmented with acetate and glycerol in order to control the influent carbon nitrogen ratio (C/N). The short-term effect of the inlet C/N ratio variation (C/N = 5 mgCOD/mgN and C/N = 10 mgCOD/mgN) on the behaviour of both plants was investigated. The results showed that the IFAS-UCT-MBR configuration provided the best performance in terms of poll…

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Towards a conceptual mathematical tool linking physical and biological processes for a reduction of ghg emissions from an mb-mbr plant

The current study explores the influence of the air flow rate on greenhouse gas (GHG) emissions (direct and indirect), the operational costs (OCs), the effluent quality index (EQI) and effluent fines (EF). An University Cape Town (UCT) moving bed (MB) membrane bioreactor (MBR) pilot plant has been considered as case study where the influence of the air flow rate on the biological and physical processes has been analyzed. Constitutive relationships between the air flow rate and some performance indicators (i.e., EQI, OCs, direct and indirect GHG emissions) have been identified. Results showed that the EQI increases at low flow rate likely due to the dissolved oxygen (DO) limitation in the bi…

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Nitrous oxide emission in a University of Cape Town membrane bioreactor: The effect of carbon to nitrogen ratio

Abstract The effect of the carbon-to-nitrogen (C/N) ratio in the influent on the nitrous oxide (N 2 O) emission from a University of Cape Town Membrane BioReactor pilot plant was investigated. The membrane was located in a separate tank to single out the production of N 2 O due to the biological processes from N 2 O stripping as a result of the extra aeration needed for the mitigation of membrane fouling. The experimental campaign was divided into two phases, each characterized by a different C/N ratio (namely, 10 and 5 mgCOD/mgTN, Phase I and Phase II, respectively). The decrease of the C/N ratio promoted the increase of N 2 O emissions in both gaseous and dissolved phases, mainly due to a…

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Greenhouse gas emissions and the links to plant performance in a fixed-film activated sludge membrane bioreactor - Pilot plant experimental evidence

The present study explores the interlinkages among the operational variables of a University of Cape Town (UCT) Integrated Fixed Film Activated Sludge (IFAS) membrane bioreactor (MBR) pilot plant. Specifically, dedicated experimental tests were carried out with the final aim to find-out a constitutive relationship among operational costs (OCs), effluent quality index (EQI), effluent fines (EF). Greenhouse gas (GHG) emissions were also included in the study. Results showed that the EQI increases at low flow rate likely due to the dissolved oxygen (DO) limitation in the biological processes. Direct GHGs increase with the increasing of the air flow due to the anoxic N2O contribution. Irreversi…

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An innovative respirometric method to assess the autotrophic active fraction: Application to an alternate oxic-anoxic MBR pilot plant

An innovative respirometric method was applied to evaluate the autotrophic active fraction in an alternate anoxic/oxic membrane bioreactor (MBR) pilot plant. The alternate cycle (AC) produces a complex microbiological environment that allows the development of both autotrophic and heterotrophic species in one reactor. The present study aimed to evaluate autotrophic and heterotrophic active fractions and highlight the effect of different aeration/non aeration ratios in a AC-MBR pilot plant using respirometry. The results outlined that the autotrophic active fraction values were consistent with the nitrification efficiency and FISH analyses, which suggests its usefulness for estimating the ni…

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Analisi Sperimentali su impianti MBR ad aerazione intermittente

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IL MONITORAGGIO DELLE EMISSIONI E DELLA QUALITÀ DELL’ARIA NELLA GESTIONE DELLE DISCARICHE

La corretta gestione delle discariche controllate, destinate allo smaltimento dei rifiuti urbani, in fase operativa e post‐operativa, richiede il controllo dei potenziali impatti che esse possono determinare nei vari comparti ambientali interessati. Fra questi, la produzione di biogas derivante dai processi metabolici di trasformazione della frazione organica dei rifiuti, richiede, da un lato, la realizzazione di efficaci sistemi di estrazione, mediante i quali è pure possibile produrre energia termica e/o elettrica, dall’altro, il controllo delle emissioni diffuse in atmosfera, che contribuiscono al peggioramento delle caratteristiche dell’aria ambiente circostante il sito della discarica,…

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The Influence of MSW Landfill Height in the Perched Leachate Formation

During the last decades, the largest part of municipal solid waste (MSW) generated world wide has been disposed of in landfills without any pre-treatment. The main environmental impacts of such landfills, containing high amounts of biodegradable organic matter, are caused by emissions of liq-uid effluents and landfill gas. With no collection and treatment, leachates from landfills pollute groundwater and soils locally. Furthermore, besides the biological processes, many physical phe-nomena occur inside the landfill body which negatively affect landfill management. Indeed, the waste settlement inside the landfill body, with a consequent increase of its density, corresponds to a proportional …

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Direct Measurement of Methane Emission Rates: Multiyear Application to a Municipal Landfill in Southern Italy

Municipal Solid Waste (MSW) landfills have been identified as one of the most important sources of methane (CH4) emission. MSW contains a certain amount of biodegradable organic matter which undergoes anaerobic degradation resulting in the production of the landfill gas (LFG), which main component is tipically represented by CH4. In order to minimise its negative effects on the envi-ronment, LFG recovery is a suitable tool to control CH4 emissions from a landfill site and the measurement of CH4 emissions represents a good way to evaluate the effectiveness of LFG recover-ing system in reducing biogas emission to the atmosphere. However, up to now few measurements of landfill CH4 emissions ha…

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Characterization of wastewater and biomass activity in a membrane bioreactor using respirometric techniques

Over the last two decades, Membrane Bioreactors (MBRs) emerged even more for wastewater treatment, ensuring high removal efficiencies as well as very small footprint required. Indeed, in this kind of process, a modification in biomass activity and viability can exist compared to that of a conventional activated sludge (CAS) process. In this context, respirometric analysis represents a reliable tool in order to evaluate the actual biomass kinetic parameters, to insert in mathematical models in the design phase, as well as to monitor the biomass viability, especially when these processes are operated with high sludge retention time (SRT) values. The paper presents some results of respirometri…

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Physical properties and Extracellular Polymeric Substances pattern of aerobic granular sludge treating hypersaline wastewater.

The modification of the physical properties of aerobic granular sludge treating fish-canning wastewater is discussed in this paper. The structure and composition of the Extracellular Polymeric Substances (EPSs) were analyzed at different salinity levels and related to granules stability. Results outlined that the total EPSs content increased with salinity, despite the EPSs increment was not proportional to the salt concentration. Moreover, the EPSs structure was significantly modified by salinity, leading to a gradual increase of the not-bound EPSs fraction, which was close to the 50% of the total EPSs content at 75 g NaCl L-1. The increasing salt concentration modified also the EPSs compos…

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REMOTE SENSING ANALYSIS COUPLED TO FIELD MEASUREMENTS FOR THE EVALUATION OF METHANE EMISSIONS FROM A LANDFILL SITE: A CASE STUDY

SUMMARY: the waste disposal in sanitary landfills generates landfill gas (LFG), mainly constituted by methane (CH4) and carbon dioxide (CO2), because of the anaerobic degradation of the organic matter contained in the disposed waste. It is worth mentioning that CH4 is recognized as one of the most important contributor to global warming and sanitary landfills for Municipal Solid Waste (MSW) have been found to be a significant source of CH4 generation and emission. The main aim of the present work was the evaluation of methane emissions from a Sicilian landfill site by coupling of direct field measurements and ground temperature data acquired through remote sensing techniques. It is worth me…

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A comprehensive comparison between halophilic granular and flocculent sludge in withstanding short and long-term salinity fluctuations

The effects of salinity fluctuations on the activity of autochthonous halophilic bacteria in aerobic granular sludge (AGS) and flocculent activated sludge (FAS) reactors were investigated. The response of nitrifiers and denitrifiers activity to drastic and moderate salinity shocks in the short-term (ST) and long-term (LT) was examined. The BOD5removal efficiency decreased only in the reactors subjected to the drastic LT salinity increase. Nevertheless, stable performances were achieved 18 days after the shock in the AGS-R1 (90%), whereas after 27 days in the FAS-R1 (82%). The loss in nitritation efficiency was higher in the FAS reactors and was proportional to the shock intensity. Nitritati…

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Membrane bioreactors sludge: From production to disposal

Abstract This chapter reviews the MBR activated sludge from production to disposal. Starting from sludge characterization, the chapter first presents the features of MBR sludge (morphology and EPS chemical composition), also in terms of differences with the activated sludge from conventional activated sludge plants. Sludge dewaterability is then discussed, focusing on the differences between aerobically and anaerobically digested sludge. An analysis of the costs related to MBR sludge treatment and disposal also is presented in order to provide a framework for a sustainable MBR sludge management.

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The role of EPS in the foaming and fouling for a MBR operated in intermittent aeration conditions

Abstract This work investigates the causes of foaming and fouling in an Intermittent Aerated – Membrane BioReactor (IA-MBR) used for wastewater treatment. The experiment was divided into three periods with different aerated regimes expressed with different t aeration /t cycle ratio (Period I: 60 min/180 min, Period II: 80 min/180 min, Period III: 30 min/90 min). The advanced foaming tests used allow the study of the role of extracellular polymeric substances (EPSs) on foaming and fouling. In general, in the Periods I and II, good correlations between the EPSs and the Modified Scum Index without purification (MSI 0 ) and the Foam Power were observed. The results shown that the filamentous mi…

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Bacterial community structure and removal performances in IFAS-MBRs: A pilot plant case study

Abstract The paper reports the results of an experimental campaign carried out on a University of Cape Town (UCT) integrated fixed-film activated sludge (IFAS) membrane bioreactor (MBR) pilot plant. The pilot plant was analysed in terms of chemical oxygen demand (COD) and nutrients removal, kinetic/stoichiometric parameters, membrane fouling and sludge dewaterability. Moreover, the cultivable bacterial community structure was also analysed. The pilot plant showed excellent COD removal efficiency throughout experiments, with average value higher than 98%, despite the slight variations of the influent wastewater. The achieved nitrification efficiency was close to 98% for most of the experimen…

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Greenhouse gases from membrane bioreactors: New perspectives on monitoring and mathematical modeling

Abstract The awareness that the wastewater sector represents a significant source of greenhouse gas emission has increased, and is the awareness is evident based on the numerous research papers published in technical literature in the last 10 years. This chapter is aimed at providing a timely overview on greenhouse gas production and emission from membrane bioreactors. Specifically, this chapter dedicates particular attention to nitrous oxide (N2O), considering both experimental and mathematical modeling approaches. Referring to the experimental data, the observed results highlighted the significant contribution of the aerated compartments toward nitrous oxide emission as well as the import…

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Greenhouse gas emissions from membrane bioreactors: analysis of a two-year survey on different MBR configurations

Abstract This study aimed at evaluating the nitrous oxide (N2O) emissions from membrane bioreactors (MBRs) for wastewater treatment. The study investigated the N2O emissions considering multiple influential factors over a two-year period: (i) different MBR based process configurations; (ii) wastewater composition (municipal or industrial); (iii) operational conditions (i.e. sludge retention time, carbon-to-nitrogen ratio, C/N, hydraulic retention time); (iv) membrane modules. Among the overall analysed configurations, the highest N2O emission occurred from the aerated reactors. The treatment of industrial wastewater, contaminated with salt and hydrocarbons, provided the highest N2O emission…

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Simultaneous nitritation-denitritation for the treatment of high-strength nitrogen in hypersaline wastewater by aerobic granular sludge

Abstract Fish processing industries produce wastewater containing high amounts of salt, organic matter and nitrogen. Biological treatment of such wastewaters could be problematic due to inhibitory effects exerted by high salinity levels. In detail, high salt concentrations lead to the accumulation of nitrite due to the inhibition of nitrite-oxidizing bacteria. The feasibility of performing simultaneous nitritation and denitritation in the treatment of fish canning wastewater by aerobic granular sludge was evaluated, and simultaneous nitritation–denitritation was successfully sustained at salinities up to 50 gNaCl L −1 , with a yield of over 90%. The total nitrogen concentration in the efflu…

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The sludge dewaterability in advanced wastewater treatment: a survey of four different Membrane BioReactor pilot plants

The wasted activated sludge dewaterability represents a major concern for Wastewater Treatment Plants (WWTPs) managers. Indeed, whereas the dewatered sludge could represents a re-usable matrix, the principal drawback related to the wasted sludge dewaterability is the high water content due to the presence of extracellular polymeric substances (EPS) that allow the trapping of water molecules within the bio sludge flocs. In order to provide an outlook of the dewaterability features of activated sludge derived from advanced WWTP, the present research reports a long term survey (over two years) aimed at assessing the principal dewaterability parameters of the sludge wasted from different Membra…

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THE INFLUENCE OF LANDFILL FEATURES AND SIDE SLOPES ON METHANE EMISSION RATES

Sanitary landfills for Municipal Solid Waste (MSW) disposal have been identified as one of the most important sources of methane (CH4) emissions; indeed, MSW contains a certain amount of biodegradable organic matter which undergoes anaerobic degradation resulting in the production of the so called landfill gas (LFG), which main component is typically represented by CH4. In general, LFG will escape through any faults in the landfill capping or in the LFG collection system. If the capping is not damaged, low quantities of LFG will be emitted through the permeable material that covers the disposed waste. On the other hand, some zones of the capping are often more permeable than others (e.g. si…

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Evaluation of biomass activity and wastewater characterization in a UCT-MBR pilot plant by means of respirometric techniques

Abstract Over the last two decades, Membrane Bioreactors (MBRs) emerged even more for wastewater treatment, ensuring high removal efficiencies as well as very small footprint requirements. Indeed, in this kind of process, a modification in biomass activity and viability can exist compared to that of a CAS process. In this context, respirometric analysis represents a reliable tool in order to evaluate the actual biomass kinetic parameters, to insert in mathematical models in the design phase, as well as to monitor the biomass viability, especially when these processes are operated with high SRT values. The paper presents some results of respirometric techniques applied for the characterisati…

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