0000000001298795
AUTHOR
F. Teixidor
Synthesis of small carboranylsilane dendrons as scaffolds for multiple functionalizations.
Small carbosilane dendrons in which a closo-carborane is located at the focal point have been prepared by a sequence of steps involving hydrosilylation and reduction reactions. These compounds are used as scaffolds for peripheral functionalization with styrene, chlorovinylstyrene, or suitable carboranes, while keeping the C(cluster)-Si (C(c)-Si) bond. Modification of the core by reduction of the carborane with Mg/BrCH2CH2Br was also achieved.
Synthesis of Boron-Iodinated o-Carborane Derivatives. Water Stability of the Periodinated Monoprotic Salt
Boron periodination of o-carborane has been achieved by taking account of the fact that B atoms in the cluster are of two types, i.e., those adjacent to both C atoms and the remainder. The high number of nonequivalent leaving groups opens the possibility through B-C coupling to materials with novel possibilities and to self-assembling due to the enhanced polarizability of the C-H bond. Periodination has accentuated the acidity of the carborane, and monoprotic salts are stable in water.
Modular Construction of Neutral and Anionic Carboranyl-Containing Carbosilane-Based Dendrimers
A modular construction of new carbosilane dendrimers, which contain four and eight peripheral carborane derivatives and propyl linkages between the C cluster and the Si atoms, has been developed using different methodologies. Regiospecific hydrosilylation of 1-C 6 H 5 -2-(CH 2 CH=CH 2 )-1,2-closo-C 2 B 10 H 10 (1) and 1-CH 3 -2-(CH 2 CH=CH 2 )-1,2-closo-C 2 B 10 H 10 (2) offers an efficient route to molecular precursors and building blocks that can provide both divergent and convergent strategies for dendritic growth. First generations of neutral carboranyl-containing dendrimers were constructed by two approaches: (a) a divergent approach via hydrosilylation of 1 and 2 with the first genera…
Formation of New η5-Rhodium(III) Complexes from η5-Rh(I) Rhodacarborane-Containing Charge-Compensated Ligands
A series of new Rh(I) half-sandwich complexes of formula [3,3-(PPh 3 ) 2 -8-L-closo-3,1,2-RhC 2 B 9 H 1 0 )] (L = SMe 2 (2a), SEt 2 (2b), S(CH 2 ) 4 (2c), SEtPh (2d)) and [1-Me-3,3-(PPh 3 ) 2 -8-L-closo-3,1,2-RhC 2 B 9 H 9 )] (L = SMe 2 (2e), SEt 2 (2f)) have been prepared by reaction of the respective monoanionic charge-compensated ligands [10-L-nido-7,8-C 2 B 9 H 1 0 ] - and [7-Me-10-L-7,8-C 2 B 9 H 9 ] - with [RhCl(PPh 3 ) 3 ]. Complex [3,3-(cod)-8-SMe2-closo-3,1,2-RhC 2 B 9 H 1 0 ] (3) has also been prepared by reaction of K[10-SMe 2 -nido-7,8-C 2 B 9 H 1 0 ] with [RhCl(cod)] 2 . Rh(I) complexes 2a-d may be easily oxidized to the corresponding Rh(III) complexes 4a-d under N 2 atmosphere…
Approaches to the preparation of carborane-containing carbosilane compounds.
[Structure: see text] A novel type of carborane cluster assembly has been successfully prepared using carbosilane derivatives as a scaffold. Two synthetic routes have been used: One involves the reaction of a carbosilane containing terminal Si-Cl functions with the lithium salt of the phenyl-o-carborane, and the second one consists of a highly efficient hydrosilylation of tetravinylsilane with the corresponding carboranylsilane. The crystal structure of this carborane-containing carbosilane compound has been determined by X-ray diffraction.
Formation of Bridging Alkene and Conjugated Dialkenes Exclusively Generated from Alkynes on the [3,3‘-Co(1,2-C2B9H11)2]- Platform. The Unique Hydroboration Role of [3,3‘-Co(1,2-C2B9H11)2]-
The unprecedented metal-mediated transformation of an alkyne into a B,B' bridging alkene is reported. Also, the unprecedented synthesis of a conjugated dialkene derivative of [3,3'-Co(1,2-C2B9H11)2]- generated only from an alkyne, contrary to the usual case where an alkyne and an alkene are needed, is described. This has been possible through the singular capacity of a B-H to produce hydroboration.
Designed Synthesis of New ortho-Carborane Derivatives: from Mono- to Polysubstituted Frameworks
The use of nucleophilic and electrophilic processes allow the designed synthesis of several B-iodinated derivatives of o-carborane. Because of the straightforward Pd-catalyzed conversion of B-I to B-C bond with Grignard reagents, such as methylMgBr and biPhenylMgBr, both, symmetrical 3,6-R 2-1,2- closo-C 2B 10H 10 and asymmetrical 3-I-6-Me-1,2- closo-C 2B 10H 10 could be obtained. Not only conventional reactions in solution have been studied but also a highly efficient, clean and fast solvent-free procedure has provided successful results to regioselectively produce B-iodinated o-carborane derivatives by a careful control of the reaction conditions. The high number of nonequivalent leaving …
Methylation and Demethylation in Cobaltabis(dicarbollide) Derivatives
B(8)−R and B(8‘)−R (R = alkyl) disubstituted derivatives of the cobaltabis(dicarbollide) anion [3,3‘-Co(C2B9H11)2]- are reported. The synthesis was achieved by application of a modified Kumada reac...
CCDC 206029: Experimental Crystal Structure Determination
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CCDC 206027: Experimental Crystal Structure Determination
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CCDC 827097: Experimental Crystal Structure Determination
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CCDC 263594: Experimental Crystal Structure Determination
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CCDC 168130: Experimental Crystal Structure Determination
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CCDC 662828: Experimental Crystal Structure Determination
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CCDC 215768: Experimental Crystal Structure Determination
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CCDC 611426: Experimental Crystal Structure Determination
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CCDC 234461: Experimental Crystal Structure Determination
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CCDC 212591: Experimental Crystal Structure Determination
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CCDC 827094: Experimental Crystal Structure Determination
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CCDC 241028: Experimental Crystal Structure Determination
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CCDC 635883: Experimental Crystal Structure Determination
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CCDC 729739: Experimental Crystal Structure Determination
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CCDC 725202: Experimental Crystal Structure Determination
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CCDC 241030: Experimental Crystal Structure Determination
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CCDC 216064: Experimental Crystal Structure Determination
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CCDC 662716: Experimental Crystal Structure Determination
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CCDC 185388: Experimental Crystal Structure Determination
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CCDC 241029: Experimental Crystal Structure Determination
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CCDC 214180: Experimental Crystal Structure Determination
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CCDC 177729: Experimental Crystal Structure Determination
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CCDC 616221: Experimental Crystal Structure Determination
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CCDC 837895: Experimental Crystal Structure Determination
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CCDC 641600: Experimental Crystal Structure Determination
Related Article: G.Barbera, A.Vaca, F.Teixidor, R.Sillanpaa, R.Kivekas, C.Vinas|2008|Inorg.Chem.|47|7309|doi:10.1021/ic800362z
CCDC 663536: Experimental Crystal Structure Determination
Related Article: F.Teixidor, A.Laromaine, R.Kivekas, R.Sillanpaa, C.Vinas, R.Vespalec, H.Horakova|2008|Dalton Trans.||345|doi:10.1039/b715362g
CCDC 804982: Experimental Crystal Structure Determination
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CCDC 608729: Experimental Crystal Structure Determination
Related Article: F.Teixidor, G.Barbera, C.Vinas, R.Sillanpaa, R.Kivekas|2006|Inorg.Chem.|45|3496|doi:10.1021/ic060124y
CCDC 725261: Experimental Crystal Structure Determination
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CCDC 630892: Experimental Crystal Structure Determination
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CCDC 725259: Experimental Crystal Structure Determination
Related Article: A.V.Puga, F.Teixidor, R.Sillanpaa, R.Kivekas, C.Vinas|2009|Chem.-Eur.J.|15|9764|doi:10.1002/chem.200900926
CCDC 630889: Experimental Crystal Structure Determination
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CCDC 837896: Experimental Crystal Structure Determination
Related Article: A.Pepiol, F.Teixidor, R.Sillanpaa, M.Lupu, C.Vinas|2011|Angew.Chem.,Int.Ed.|50|12491|doi:10.1002/anie.201105668
CCDC 263592: Experimental Crystal Structure Determination
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CCDC 168131: Experimental Crystal Structure Determination
Related Article: O.Tutusaus, F.Teixidor, R.Nunez, C.Vinas, R.Sillanpaa, R.Kivekas|2002|J.Organomet.Chem.|657|247|doi:10.1016/S0022-328X(02)01541-3
CCDC 630896: Experimental Crystal Structure Determination
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CCDC 616223: Experimental Crystal Structure Determination
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CCDC 227792: Experimental Crystal Structure Determination
Related Article: I.Rojo, F.Teixidor, R.Kivekas, R.Sillanpaa, C.Vinas|2003|J.Am.Chem.Soc.|125|14720|doi:10.1021/ja037279e
CCDC 641601: Experimental Crystal Structure Determination
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CCDC 659301: Experimental Crystal Structure Determination
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CCDC 168258: Experimental Crystal Structure Determination
Related Article: J.Llop, C.Masalles, C.Vinas, F.Teixidor, R.Sillanpaa, R.Kivekas|2003|Dalton Trans.||556|doi:10.1039/b211860m
CCDC 627237: Experimental Crystal Structure Determination
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CCDC 800463: Experimental Crystal Structure Determination
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CCDC 226432: Experimental Crystal Structure Determination
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CCDC 802843: Experimental Crystal Structure Determination
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CCDC 616222: Experimental Crystal Structure Determination
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CCDC 202047: Experimental Crystal Structure Determination
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CCDC 234462: Experimental Crystal Structure Determination
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CCDC 616224: Experimental Crystal Structure Determination
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CCDC 830363: Experimental Crystal Structure Determination
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CCDC 652273: Experimental Crystal Structure Determination
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CCDC 662714: Experimental Crystal Structure Determination
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CCDC 276992: Experimental Crystal Structure Determination
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CCDC 830365: Experimental Crystal Structure Determination
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CCDC 206028: Experimental Crystal Structure Determination
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CCDC 663537: Experimental Crystal Structure Determination
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CCDC 725260: Experimental Crystal Structure Determination
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CCDC 889022: Experimental Crystal Structure Determination
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CCDC 830364: Experimental Crystal Structure Determination
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CCDC 627239: Experimental Crystal Structure Determination
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CCDC 234460: Experimental Crystal Structure Determination
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CCDC 202045: Experimental Crystal Structure Determination
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CCDC 804983: Experimental Crystal Structure Determination
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CCDC 263595: Experimental Crystal Structure Determination
Related Article: A.Laromaine, F.Teixidor, R.Kivekas, R.Sillanpaa, R.Benakki, B.Gruner, C.Vinas|2005|Dalton Trans.||1785|doi:10.1039/b502328a
CCDC 1507870: Experimental Crystal Structure Determination
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CCDC 725257: Experimental Crystal Structure Determination
Related Article: A.V.Puga, F.Teixidor, R.Sillanpaa, R.Kivekas, C.Vinas|2009|Chem.-Eur.J.|15|9764|doi:10.1002/chem.200900926
CCDC 663535: Experimental Crystal Structure Determination
Related Article: F.Teixidor, A.Laromaine, R.Kivekas, R.Sillanpaa, C.Vinas, R.Vespalec, H.Horakova|2008|Dalton Trans.||345|doi:10.1039/b715362g
CCDC 1507874: Experimental Crystal Structure Determination
Related Article: A. Ferrer-Ugalde, J. Cabrera-González, E. J. Juárez-Pérez, F. Teixidor, E. Pérez-Inestrosa, J. M. Montenegro, R. Sillanpää, M. Haukka, R. Núñez|2017|Dalton Trans.|46|2091|doi:10.1039/C6DT04003A
CCDC 1507875: Experimental Crystal Structure Determination
Related Article: A. Ferrer-Ugalde, J. Cabrera-González, E. J. Juárez-Pérez, F. Teixidor, E. Pérez-Inestrosa, J. M. Montenegro, R. Sillanpää, M. Haukka, R. Núñez|2017|Dalton Trans.|46|2091|doi:10.1039/C6DT04003A
CCDC 662713: Experimental Crystal Structure Determination
Related Article: J.Bould, A.Laromaine, N.J.Bullen, C.Vinas, M.Thornton-Pett, R.Sillanpaa, R.Kivekas, J.D.Kennedy, F.Teixidor|2008|Dalton Trans.||1552|doi:10.1039/b715845a
CCDC 662715: Experimental Crystal Structure Determination
Related Article: J.Bould, A.Laromaine, N.J.Bullen, C.Vinas, M.Thornton-Pett, R.Sillanpaa, R.Kivekas, J.D.Kennedy, F.Teixidor|2008|Dalton Trans.||1552|doi:10.1039/b715845a
CCDC 216061: Experimental Crystal Structure Determination
Related Article: I.Rojo, F.Teixidor, C.Vinas, R.Kivekas, R.Sillanpaa|2004|Chem.-Eur.J.|10|5376|doi:10.1002/chem.200400361
CCDC 186442: Experimental Crystal Structure Determination
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CCDC 263591: Experimental Crystal Structure Determination
Related Article: A.Laromaine, F.Teixidor, R.Kivekas, R.Sillanpaa, R.Benakki, B.Gruner, C.Vinas|2005|Dalton Trans.||1785|doi:10.1039/b502328a
CCDC 215767: Experimental Crystal Structure Determination
Related Article: B.Gruner, J.Backovsky, R.Sillanpaa, R.Kivekas, I.Cisarova, F.Teixidor, C.Vinas, B.Stibr|2004|Eur.J.Inorg.Chem.||1402|doi:10.1002/ejic.200300686
CCDC 1507873: Experimental Crystal Structure Determination
Related Article: A. Ferrer-Ugalde, J. Cabrera-González, E. J. Juárez-Pérez, F. Teixidor, E. Pérez-Inestrosa, J. M. Montenegro, R. Sillanpää, M. Haukka, R. Núñez|2017|Dalton Trans.|46|2091|doi:10.1039/C6DT04003A
CCDC 652272: Experimental Crystal Structure Determination
Related Article: E.J.Juarez-Perez, C.Vinas, A.Gonzalez-Campo, F.Teixidor, R.Sillanpaa, R.Kivekas, R.Nunez|2008|Chem.-Eur.J.|14|4924|doi:10.1002/chem.200702013
CCDC 216063: Experimental Crystal Structure Determination
Related Article: I.Rojo, F.Teixidor, C.Vinas, R.Kivekas, R.Sillanpaa|2004|Chem.-Eur.J.|10|5376|doi:10.1002/chem.200400361
CCDC 662826: Experimental Crystal Structure Determination
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CCDC 263593: Experimental Crystal Structure Determination
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