0000000001298920

AUTHOR

Maria-gabriela Alexandru

showing 71 related works from this author

Heterotrimetallic coordination polymers: {Cu(II)Ln(III)Fe(III)} chains and {Ni(II)Ln(III)Fe(III)} layers: synthesis, crystal structures, and magnetic…

2015

The use of the [Fe(III) (AA)(CN)4](-) complex anion as metalloligand towards the preformed [Cu(II) (valpn)Ln(III)](3+) or [Ni(II) (valpn)Ln(III) ](3+) heterometallic complex cations (AA=2,2'-bipyridine (bipy) and 1,10-phenathroline (phen); H2 valpn=1,3-propanediyl-bis(2-iminomethylene-6-methoxyphenol)) allowed the preparation of two families of heterotrimetallic complexes: three isostructural 1D coordination polymers of general formula {[Cu(II) (valpn)Ln(III) (H2O)3 (μ-NC)2 Fe(III) (phen)(CN)2 {(μ-NC)Fe(III) (phen)(CN)3}]NO3 ⋅7 H2O}n (Ln=Gd (1), Tb (2), and Dy (3)) and the trinuclear complex [Cu(II) (valpn)La(III) (OH2 )3 (O2 NO)(μ-NC)Fe(III) (phen)(CN)3 ]⋅NO3 ⋅H2O⋅CH3 CN (4) were obtained …

ChemistryLigandOrganic ChemistryInorganic chemistryGeneral ChemistryCrystal structureCatalysisMagnetizationchemistry.chemical_compoundBipyridineCrystallographyX-ray crystallographyMoleculeIsostructuralAcetonitrileChemistry (Weinheim an der Bergstrasse, Germany)
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{CoIIIMnIII}ncorrugated chains based on heteroleptic cyanido metalloligands

2015

The use of the cyanide-bearing complexes PPh4[CoIII(4,4′-dmbipy)(CN)4] and PPh4[CoII(dmphen)(CN)3] as metalloligands towards [Mn(salen)(H2O)]ClO4 affords one-dimensional coordination polymers with the formulas {[MnIII(salen)(μ-NC)2CoIII(4,4-dmbipy)(CN)2]·H2O}n (1) and {[MnIII(salen)(μ-NC)2CoIII(dmphen)(CN)2]}n (2) [PPh4+ = tetraphenylphosphonium cation, 4,4′-dmbipy = 4,4′-dimethyl-2,2′-bipyridine, dmphen = 2,9-dimethyl-1,10-phenanthroline and H2salen = N,N′-ethylenebis(salicylideneimine)]. Compounds 1 and 2 were structurally characterized. Their structures consist of neutral chains with regular alternating [Mn(salen)]+ and [CoIII(4,4′-dmbipy)(CN)4]− (1)/[CoIII(dmphen)(CN)4]− (2) moieties, t…

Single ionStereochemistryGeneral Chemical EngineeringCyanidechemistry.chemical_elementGeneral ChemistryAtmospheric temperature rangeIonchemistry.chemical_compoundMagnetizationCrystallographychemistryMagnetic relaxationCobaltCyanide ligandRSC Advances
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Three different types of bridging ligands in a 3d-3d'-3d'' heterotrimetallic chain.

2017

A one-pot synthesis of a 3d–3d′–3d′′ heterotrimetallic coordination polymer with double diphenoxido, single cyanido and bis-bidentate oxalate as alternating bridges which exhibits an overall antiferromagnetic behaviour has been developed.

Inorganic Chemistrychemistry.chemical_compoundCrystallographyBridging (networking)chemistry010405 organic chemistryCoordination polymer010402 general chemistry01 natural sciencesOxalate0104 chemical sciencesDalton transactions (Cambridge, England : 2003)
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Field-induced single ion magnet behaviour of discrete and one-dimensional complexes containing [bis(1-methylimidazol-2-yl)ketone]-cobalt(II) building…

2021

International audience; We describe herein the first examples of six-coordinate CoII single-ion magnets (SIMs) based on the β-diimine Mebik ligand [Mebik = bis(1-methylimidazol-2-yl)ketone]: two mononuclear [CoII(Rbik)2L2] complexes and one mixed-valence {CoIII2CoII}n chain of formulas [CoII(Mebik)(H2O)(dmso)(μ-NC)2CoIII2(μ-2,5-dpp)(CN)6]n·1.4nH2O (3) [L = NCS (1), NCSe (2) and 2,5-dpp = 2,5-bis(2-pyridyl)pyrazine (3)]. Two bidentate Mebik molecules plus two monodentate N-coordinated pseudohalide groups in cis positions build somewhat distorted octahedral surroundings around the high-spin cobalt(II) ions in 1 and 2. The diamagnetic [CoIII2(μ-2,5-dpp)(CN)8]2− metalloligand coordinates the pa…

DenticityMaterials sciencePyrazine010405 organic chemistrychemistry.chemical_element010402 general chemistry01 natural sciences0104 chemical scienceslaw.inventionInorganic ChemistryMagnetizationCrystallographyParamagnetismMagnetic anisotropychemistry.chemical_compoundchemistrylaw[CHIM]Chemical SciencesMoleculeElectron paramagnetic resonanceCobaltDalton transactions (Cambridge, England : 2003)
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Cyanido‐Bearing Cobalt(II/III) Metalloligands – Synthesis, Crystal Structure, and Magnetic Properties

2014

New examples of cyanido-bearing cobalt(III/II) complexes have been obtained by treatment of CoCl2·6H2O with bidentate nitrogen donors and potassium cyanide in a methanol/water mixture. Depending on the chelating ligand, the cobalt(III) complexes PPh4[Co(en)(CN)4] (1, en = ethylenediamine), PPh4[Co(ampy)(CN)4]·1.5H2O [2, ampy = 2-(aminomethyl)pyridine], and PPh4[Co(phen)(CN)4]·CH3OH·0.25H2O (3, phen = 1,10-phenanthroline) and the cobalt(II) complex PPh4[Co(dmphen)(CN)3]·3H2O (4, dmphen = 2,9-dimethyl-1,10-phenanthroline) were obtained. The complexes were characterized by single-crystal X-ray diffraction and variable-temperature magnetic measurements. They are all mononuclear species with six…

DenticityCyanideInorganic chemistrychemistry.chemical_elementEthylenediamineCrystal structurelaw.inventionInorganic ChemistryCrystallographychemistry.chemical_compoundchemistryUnpaired electronlawPyridineElectron paramagnetic resonanceCobaltEuropean Journal of Inorganic Chemistry
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Two-Dimensional Coordination Polymers Constructed by [NiIILnIII] Nodes and [WIV(bpy)(CN)6]2– Spacers: A Network of [NiIIDyIII] Single Molecule Magnets

2013

Three isomorphous two-dimensional (2D) coordination polymers of general formula {[Ni(II)(valpn)Ln(III)(NO3)(H2O)(μ-NC)4W(IV)(bipy)(CN)2]·xH2O·yCH3CN}n have been synthesized by reacting Ph4P[W(V)(CN)6(bipy)] with the heterodinuclear [Ni(II)Ln(III)(valpn)(O2NO)3] complexes [H2valpn = 1,3-propanediyl-bis(2-iminomethylene-6-methoxyphenol), bipy = 2,2'-bipyridine, and Ln = Gd (1), Dy (2), and Tb (3) with x = 2 (1), 3.9 (2), and 3.35 (3) and y = 2.50 (1), 2 (2), and 1.8 (3)]. Their crystal structures consist of [Ni(II)Ln(III)] 3d-4f nodes which are connected by [W(IV)(bipy)(CN)6](2-) diamagnetic linkers resulting from the reduction of W(V) to W(IV) during the reaction process. The Ni(II) and Ln(I…

Inorganic Chemistrychemistry.chemical_classificationCrystallographyOxygen atomChemistryLigandStereochemistryMoleculePolymerCrystal structurePhysical and Theoretical ChemistryIonInorganic Chemistry
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Cyanido-bridged {FeIIILnIII} heterobimetallic chains assembled through the [FeIII{HB(pz)3}(CN)3]−complex as metalloligand: synthesis, crystal structu…

2021

A new series of cyanido-bridged {FeIIILnIII} heterobimetallic chains of general formula {[(NC)FeIII{HB(pz)3}(μ-CN)2LnIII(bpdo)(NO3)2(H2O)]·CH3CN}n [HB(pz)3− = hydrotris(pyrazol-1-yl)borate, bpdo = 2,2′-bipyridine-N,N′-dioxide and Ln = Gd (1), Tb (2), Dy (3) and Ho (4)], were obtained by using the low-spin [Fe{HB(pz)3}(CN)3]− complex as a metalloligand towards the preformed [Ln(bdpo)(NO3)2(H2O)]+ species. Single-crystal X-ray diffraction shows that 1–4 are isostructural compounds that crystallize in the monoclinic P21/c space group. Their crystal structure consists of neutral 1D coordination polymers where the [Fe{HB(pz)3}(CN)3]− fragment adopts a bis-monodentate coordination mode, through t…

Ligand field theoryLanthanideCrystallographyMaterials scienceCoordination sphereOctahedronLigandGeneral Materials ScienceGeneral ChemistryCrystal structureIsostructuralCondensed Matter PhysicsMonoclinic crystal systemCrystEngComm
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Cyanido-Bridged {LnIIIWV} Heterobinuclear Complexes: Synthesis and Magneto-Structural Study

2017

A new series of cyanido-bridged {LnIIIWV} heterobinuclear complexes of formula [LnIII(pyim)2(i-PrOH)(H2O)2(μ-CN)WV(CN)7]·2H2O [Ln = Gd (1), Tb (2), Dy (3), Ho (4), and Er (5); pyim = 2-(1H-imidazol-2-yl)-pyridine) and i-PrOH = isopropyl alcohol] were synthesized by one-pot reaction between (NH3Bu)3[W(CN)8] and [Ln(pyim)2]2+ complexes (generated in situ by mixing the corresponding LnIII ions and the pyim ligand). Compounds 1–5 are isomorphous and crystallize in the monoclinic system P21/n space group. Their crystal structure consists of binuclear units in which the octacyanotungstate(V) anion coordinates to the corresponding LnIII ion through a single cyanide ligand. The tungsten(V) and lant…

Lanthanide010405 organic chemistryChemistryStereochemistryLigandCrystal structure010402 general chemistry01 natural sciences0104 chemical sciencesIonSquare antiprismInorganic ChemistryDodecahedronCrystallographyAntiferromagnetismPhysical and Theoretical ChemistryMonoclinic crystal systemInorganic Chemistry
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A novel octacyanido dicobalt(iii) building block for the construction of heterometallic compounds

2019

The first bimetallic octacyanido complex of CoIII, (PPh4)2[Co2(μ-2,5-dpp)(CN)8] (1), was synthesized and used as a metalloligand with [Mn(MAC)(H2O)2]Cl2·4H2O to give a new {CoIIIMnII} heterometallic chain of formula [MnII(MAC)(μ-NC)2Co2III(μ-2,5-dpp)(CN)6]n·7nH2O (2) (PPh4+ = tetraphenylphosphonium cation; 2,5-dpp = 2,5-bis(2-pyridyl)pyrazine and MAC = 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo-[12.3.1]octadeca-1(18),2,12,14,16-pentaene). Both compounds were characterized by single-crystal X-ray diffraction. Compound 1 contains a diamagnetic 2,5-dpp-bridged dicobalt(III) unit with four peripheral cyanide ligands at each cobalt center achieving a six-coordinate surrounding, the electroneutral…

PyrazineCyanidechemistry.chemical_element02 engineering and technologyGeneral ChemistryManganeseAtmospheric temperature range010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesCatalysis0104 chemical sciencesIonCrystallographychemistry.chemical_compoundPentagonal bipyramidal molecular geometrychemistryMaterials Chemistry0210 nano-technologyCobaltBimetallic stripNew Journal of Chemistry
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Magnetism in Heterobimetallic and Heterotrimetallic Chains Based on the Use of [W V (bipy)(CN) 6 ] – as a Metalloligand

2018

Inorganic ChemistryCrystallography010405 organic chemistryChemistryMagnetismSelf-assembly010402 general chemistry01 natural sciences0104 chemical sciencesEuropean Journal of Inorganic Chemistry
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Synthesis, crystal structure and magnetic properties of a cyanide-bridged heterometallic {CoIIMnIII} chain

2017

The assembly reaction between the low-spin [CoII(dmphen)(CN)3]- metalloligand and the [MnIII(salen)(H2O)]+ complex cation yielded the one-dimensional compound {[MnIII(salen)(μ-NC)2CoII(dmphen)(CN)]·2H2O}n (1), which behaves as a ferrimagnetic chain, the intrachain magnetic coupling being J = -1.71(1) cm-1.

010405 organic chemistryStereochemistryCyanideCrystal structure010402 general chemistry01 natural sciencesInductive coupling0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryChain (algebraic topology)FerrimagnetismDalton Transactions
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In situ generation of Ph3PO in cyanido-bridged heterometallic {FeIIILnIII}2 molecular squares (Ln = Eu, Sm)

2019

Two new examples of cyanido-bridged {FeIIILnIII}2 molecular squares, with pyim and PPh3O as capping ligands at the LnIII sites, exhibit weak antiferromagnetic interactions [Ln = Eu (1), Sm (2), pyim = 2-(1H-imidazol-2-yl)pyridine, PPh3PO = triphenylphosphine oxide].

Inorganic ChemistryIn situCrystallographychemistry.chemical_compound010405 organic chemistryChemistryPyridineAntiferromagnetism010402 general chemistry01 natural sciencesTriphenylphosphine oxide0104 chemical sciencesDalton Transactions
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Slow relaxation of the magnetization in a {CoIIIMnIII} heterometallic brick-wall network

2021

Abstract The use of the cyanide-bearing dicobalt(III) complex (PPh4)2[Co2III(μ−2,5-dpp)(CN)8] as a metalloligand towards [Mn(salen)(H2O)]ClO4 afforded the heterobimetallic two-dimensional compound of formula [{MnIII(salen)}2{(μ-NC)4Co2III(μ−2,5-dpp)(CN)4}]n (1) [PPh4+ = teraphenylphosphonium cation, 2,5-dpp = 2,5-bis(2-pyridyl)pyrazine and H2salen = N,N’-ethylenebis(salicylideneimine)] whose structure has been determined by single crystal X-ray diffraction. Compound 1 exhibits a neutral brick-wall structure, where each [Co2III(μ−2,5-dpp)(CN)8]2− unit adopts a tetrakis-monodentate bridging mode towards four {MnIII(salen)}+ fragments through four of its eight cyanide ligands. Each cobalt(III)…

Pyrazine010405 organic chemistryChemistryRelaxation (NMR)chemistry.chemical_elementManganese010402 general chemistry01 natural sciences0104 chemical sciencesIonInorganic ChemistryMagnetizationchemistry.chemical_compoundCrystallographyOctahedronMaterials ChemistryMoleculePhysical and Theoretical ChemistrySingle crystalPolyhedron
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Synthesis, Crystal Structures, and Magnetic Properties of Two Novel Cyanido-Bridged Heterotrimetallic {CuIIMnIICrIII} Complexes

2017

The self-assembly process between the heteroleptic [CrIII(phen)(CN)4]− and [CrIII(ampy)(CN)4]− metalloligands and the heterobimetallic {CuII(valpn)MnII}2+ tecton afforded two heterotrimetallic complexes of formula [{CuII(valpn)MnII(μ-NC)2CrIII(phen)(CN)2}2{(μ-NC)CrIII(phen)(CN)3}2]·2CH3CN (1) and {[CuII(valpn)MnII(μ-NC)2CrIII(ampy)(CN)2]2·2CH3CN}n (2) [phen = 1,10-phenanthroline, ampy = 2-aminomethylpyridine, and H2valpn = 1,3-propanedyilbis(2-iminomethylene-6-methoxyphenol)]. The crystal structure of 1 consists of neutral CuII2MnII2CrIII4 octanuclear units, where two [Cr(phen)(CN)4]− anions act as bis-monodentate ligands through cyanide groups toward two manganese(II) ions from two [CuII(v…

010405 organic chemistryStereochemistryCoordination polymerCyanidechemistry.chemical_elementCrystal structureManganese010402 general chemistry01 natural sciencesCopper0104 chemical sciencesIonInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryPhysical and Theoretical ChemistryInorganic Chemistry
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Design of 3d–4f molecular squares through the [Fe{(HB(pz)3)}(CN)3]− metalloligand

2018

A new series of {FeIII2LnIII2} heterobimetallic squares of general formula [FeIII{HB(pz)3}(CN)(μ-CN)2Ln(pyim)x(NO3)2(H2O)y]2·zH2O [Ln = La (1), Gd (2), Tb (3) and Dy (4); {HB(pz)3}− = hydrotris(pyrazolyl)borate and pyim = 2-(1H-imidazol-2-yl)pyridine; x = 2, y = 0 (1), x = y = 1 (2–4) and z = 10 (1), 6 (2), 2.76 (3), 4 (4)] were synthesized by reacting the low-spin [FeIII{HB(pz)3}(CN)3]− complex anion with the preformed [LnIII(pyim)x(NO3)2(H2O)y]+ complex cation [formed in situ by mixing the lanthanide(III) salt and the pyim ligand]. Single-crystal X-ray diffraction shows that 1–4 crystallize in the P triclinic space group, 2–4 being isomorphous. In all cases, the structure comprises neutra…

LanthanideLigand field theory010405 organic chemistryLigandHydrogen bondSupramolecular chemistry010402 general chemistry01 natural sciencesMagnetic susceptibility0104 chemical sciencesInorganic ChemistryCrystallographychemistry.chemical_compoundchemistryOctahedronPyridineDalton Transactions
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Slow Relaxation of the Magnetization in a {Co <sup>III</sup>Mn <sup>III</sup>} Heterometallic Brick-Wall Network

2021

The use of the cyanide-bearing dicobalt(III) complex (PPh 4 ) 2 [Co 2 III (m-2,5-dpp)(CN) 8 ] as a metalloligand towards [Mn(salen)(H 2 O)]ClO 4 afforded the heterobimetallic two-dimensional compound of formula [{Mn III (salen)} 2 {(m-NC) 4 Co 2 III (m-2,5-dpp)(CN) 4 }] n (1) [PPh 4 + = teraphenylphosphonium cation, 2,5-dpp = 2,5-bis(2-pyridyl)pyrazine and H 2 salen = N,N’ -ethylenebis(salicylideneimine)] whose structure has been determined by single crystal X-ray diffraction. Compound 1 exhibits a neutral brick-wall structure, where each [Co 2 III (m-2,5-dpp)(CN) 8 ] 2- unit adopts a tetrakis-monodentate bridging mode towards four {Mn III (salen)} + fragments through four of its eight cyan…

chemistry.chemical_compoundCrystallographyMagnetizationMaterials scienceOctahedronPyrazinechemistryRelaxation (NMR)chemistry.chemical_elementMoleculeManganeseSingle crystalCobaltSSRN Electronic Journal
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Synthesis, Crystal Structure and Magnetic Properties of Three {Cr III Mn II } Heterodimetallic Complexes Based on Heteroleptic Cyanido‐Bearing Cr III…

2017

The use of the heteroleptic [CrIII(AA)(CN)4]- complex as a ligand towards the preformed [MnII(tptz)]2+ and [MnII(pyim)2]2+ species afforded the heterometallic compounds: [MnII(tptz)(H2O)(NO3)(-NC)CrIII(ampy)(CN)3]CH3CN (1), [MnII(tptz)(H2O)(NO3)(-NC)CrIII(phen)(CN)3]H2O (2) and {[MnII(pyim)2][(-NC)Cr(phen)(CN)3]2}3H2O (3) [AA = 2-aminomethylpyridine (ampy) and 1,10-phenanthroline (phen), tptz = 2,4,6-tris(2-pyridyl)-1,3,5-triazine and pyim = 2-(1H-imidazol-2-yl)pyridine]. 1 and 2 are neutral heterodinuclear complexes where a [CrIII(AA)(CN)4]- building block acts as a monodentate ligand through one cyanide group towards a seven coordinate MnII ion. Compound 3 is a neutral heterotrinuclear co…

Denticity010405 organic chemistryChemistryLigandStereochemistryCyanidechemistry.chemical_elementManganeseCrystal structure010402 general chemistry01 natural sciences0104 chemical sciencesIonInorganic ChemistryCrystallographychemistry.chemical_compoundChromiumPyridineEuropean Journal of Inorganic Chemistry
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[W(bipy)(CN)6]−: A Suitable Metalloligand in the Design of Heterotrimetallic Complexes. The First CuIILnIIIWV Trinuclear Complexes

2012

The first 3d-4f-5d heterotrimetallic complexes using [W(V)(bipy)(CN)(6)](-) as a metalloligand were synthesized (bipy = 2,2'-bipyridine). The structural and magnetic properties of three [Cu(II)Ln(III)W(V)] complexes (Ln = Gd, Ho, Tb) are discussed.

Inorganic ChemistryCrystallographyChemistryPhysical and Theoretical ChemistryInorganic Chemistry
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A rare isostructural series of 3d–4f cyanido-bridged heterometallic squares obtained by assembling [FeIII{HB(pz)3}(CN)3]− and LnIII ions: synthesis, …

2021

A new series of cyanido-bridged {FeIIILnIII}2 neutral molecular squares of general formula [Fe{HB(pz)3}(CN)(μ-CN)2Ln(NO3)2(pyim)(Ph3PO)]2·2CH3CN [Ln = Ce (1), Pr (2), Nd (3), Gd (4), Tb (5), Dy (6) and Er (7); {HB(pz)3}− = hydrotris(pyrazolyl)borate, pyim = 2-(1H-imidazol-2-yl)pyridine and Ph3PO = triphenylphosphine oxide] were obtained by reacting the low-spin [Fe{HB(pz)3}(CN)3]− species with the preformed [LnIII(pyim)(NO3)2(pyim)(Ph3PO)]+ complex anions (generated in situ by mixing the nitrate salt of each Ln(III) ion with pyim and Ph3PO molecules). Single-crystal X-ray diffraction studies show that 1–7 are isostructural compounds that crystallize in the triclinic P space group. Their cry…

Inorganic ChemistryLanthanideLigand field theoryCrystallographyMaterials scienceOctahedronSupramolecular chemistryMoleculeCrystal structureIsostructuralMagnetic susceptibilityDalton Transactions
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CCDC 995944: Experimental Crystal Structure Determination

2015

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Marius Andruh, Nadia Marino, Donatella Armentano, Joan Cano, Francesc Lloret, Miguel Julve|2015|Chem.-Eur.J.|21|5429|doi:10.1002/chem.201406088

Space GroupCrystallographyCrystal System(mu-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-bis(mu-cyano)-bis(110-phenanthroline)-tetra-aqua-hexacyano-copper-di-iron-terbium nitrate heptahydrateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 995946: Experimental Crystal Structure Determination

2015

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Marius Andruh, Nadia Marino, Donatella Armentano, Joan Cano, Francesc Lloret, Miguel Julve|2015|Chem.-Eur.J.|21|5429|doi:10.1002/chem.201406088

Space GroupCrystallography(mu-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-nitrato-tetra-aqua-copper-lanthanum (110-phenanthroline)-tetracyano-iron nitrate acetonitrile solvate monohydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1582396: Experimental Crystal Structure Determination

2018

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Willian X. C. Oliveira, Francesc Lloret, Miguel Julve|2018|Dalton Trans.|47|6005|doi:10.1039/C8DT00895G

Space GroupCrystallographytetrakis(mu-cyano)-bis(cyano)-bis(hydrogen tris(pyrazolyl)borate)-bis(2-(1H-imidazol-2-yl)pyridine)-tetrakis(nitrato)-diaqua-di-iron(iii)-di-terbium(iii) hydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1520091: Experimental Crystal Structure Determination

2017

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Marius Andruh, Francesc Lloret, Miguel Julve|2017|Inorg.Chem.|56|2258|doi:10.1021/acs.inorgchem.6b02966

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-22'-[propane-13-diylbis(azanylylidenemethylylidene)]bis(6-methoxyphenolato))-hexakis(mu-cyano)-tetrakis(110-phenanthroline)-decacyano-diaqua-di-copper(ii)-tetra-chromium(iii)-di-manganese(ii) acetonitrile solvateExperimental 3D Coordinates
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CCDC 995943: Experimental Crystal Structure Determination

2015

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Marius Andruh, Nadia Marino, Donatella Armentano, Joan Cano, Francesc Lloret, Miguel Julve|2015|Chem.-Eur.J.|21|5429|doi:10.1002/chem.201406088

Space GroupCrystallographyCrystal SystemCrystal Structure(mu-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-bis(mu-cyano)-bis(110-phenanthroline)-tetra-aqua-hexacyano-copper-di-iron-gadolinium nitrate heptahydrateCell ParametersExperimental 3D Coordinates
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CCDC 1969476: Experimental Crystal Structure Determination

2021

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Beatrice Cula, Sergiu Shova, Renato Rabelo, Nicolás Moliner, Francesc Lloret, Joan Cano, Miguel Julve|2021|Dalton Trans.|50|14640|doi:10.1039/D1DT02512K

Space GroupCrystallographytetrakis(mu-cyano)-dicyano-bis(hydrogen tripyrazolylborate)-bis(2-(2-pyridyl)imidazole)-tetrakis(nitrato)-bis(triphenylphosphine oxide)-di-dysprosium-di-iron acetonitrile solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1520092: Experimental Crystal Structure Determination

2017

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Marius Andruh, Francesc Lloret, Miguel Julve|2017|Inorg.Chem.|56|2258|doi:10.1021/acs.inorgchem.6b02966

Space GroupCrystallographycatena-((mu-22'-[propane-13-diylbis(azanylylidenemethylylidene)]bis(6-methoxyphenolato))-tris(mu-cyano)-pentacyano-bis(1-(pyridin-2-yl)methanamine)-copper(ii)-di-chromium(iii)-manganese(ii) acetonitrile solvate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2096753: Experimental Crystal Structure Determination

2021

Related Article: Juan-Ram��n Jim��nez, Buqing Xu, Hasnaa El Said, Yanling Li, Jurgen von Bardeleben, Lise-Marie Chamoreau, Rodrigue Lescou��zec, Sergiu Shova, Diana Visinescu, Maria-Gabriela Alexandru, Joan Cano, Miguel Julve|2021|Dalton Trans.|50|16353|doi:10.1039/D1DT02441H

bis[bis(1-methyl-1H-imidazol-2-yl)methanone]-bis(isoselenocyanato)-cobaltSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 995947: Experimental Crystal Structure Determination

2015

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Marius Andruh, Nadia Marino, Donatella Armentano, Joan Cano, Francesc Lloret, Miguel Julve|2015|Chem.-Eur.J.|21|5429|doi:10.1002/chem.201406088

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[bis(mu-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-tris(mu-cyano)-(110-phenanthroline)-dinitrato-aqua-cyano-iron-nickel-gadolinium acetonitrile solvate monohydrate]Cell ParametersExperimental 3D Coordinates
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CCDC 1969477: Experimental Crystal Structure Determination

2021

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Beatrice Cula, Sergiu Shova, Renato Rabelo, Nicolás Moliner, Francesc Lloret, Joan Cano, Miguel Julve|2021|Dalton Trans.|50|14640|doi:10.1039/D1DT02512K

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstetrakis(mu-cyano)-dicyano-bis(hydrogen tripyrazolylborate)-bis(2-(2-pyridyl)imidazole)-tetrakis(nitrato)-bis(triphenylphosphine oxide)-di-erbium-di-iron acetonitrile solvateExperimental 3D Coordinates
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CCDC 2073773: Experimental Crystal Structure Determination

2021

Related Article: Diana Visinescu, Maria-Gabriela Alexandru, Dan G. Dumitrescu, Sergiu Shova, Nicolás Moliner, Francesc Lloret, Miguel Julve|2021|CrystEngComm|23|4615|doi:10.1039/D1CE00626F

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-cyano)-(hydrogen tris(pyrazolyl)borate)-(22'-bipyridine-NN'-dioxide)-dinitrato-cyano-aqua-gadolinium(iii)-iron(iii) acetonitrile solvate]Experimental 3D Coordinates
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CCDC 995948: Experimental Crystal Structure Determination

2015

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catena-[(mu-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-tris(cyano)-(110-phenanthroline)-dinitrato-aqua-cyano-iron-nickel-terbium acetonitrile solvate monohydrate]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1907945: Experimental Crystal Structure Determination

2019

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tetrakis(mu-cyano)-tetranitrato-dicyano-bis(triphenylphosphine oxide)-bis(2-(pyridin-2-yl)imidazolyl)-bis(hydrogen tris(pyrazolyl)borate)-di-iron-di-samarium acetonitrile solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 989258: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersTetraphenylphosphonium tetracyano-(ethane-12-diamine)-cobalt(iii)Experimental 3D Coordinates
researchProduct

CCDC 1969470: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstetrakis(mu-cyano)-dicyano-bis(hydrogen tripyrazolylborate)-bis(2-(2-pyridyl)imidazole)-tetrakis(nitrato)-bis(triphenylphosphine oxide)-di-cerium-di-iron acetonitrile solvateExperimental 3D Coordinates
researchProduct

CCDC 1582395: Experimental Crystal Structure Determination

2018

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tetrakis(mu-cyano)-bis(cyano)-bis(hydrogen tris(pyrazolyl)borate)-bis(2-(1H-imidazol-2-yl)pyridine)-tetrakis(nitrato)-diaqua-di-iron(iii)-di-dysprosium(iii) tetrahydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2073771: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-cyano)-(hydrogen tris(pyrazolyl)borate)-(22'-bipyridine-NN'-dioxide)-dinitrato-cyano-aqua-dysprosium(iii)-iron(iii) acetonitrile solvate]Experimental 3D Coordinates
researchProduct

CCDC 2096752: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis[bis(1-methyl-1H-imidazol-2-yl)methanone]-bis(isothiocyanato)-cobaltExperimental 3D Coordinates
researchProduct

CCDC 989260: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyTetraphenylphosphonium tetracyano-(110-phenanthroline)-cobalt(iii) methanol solvate hydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1892383: Experimental Crystal Structure Determination

2019

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bis(tetraphenylphosphonium) [mu-25-bis(pyridin-2-yl)pyrazine]-octacyano-di-cobalt dihydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1567349: Experimental Crystal Structure Determination

2017

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(mu-cyano)-diaqua-heptacyano-bis[2-(1H-imidazol-2-yl)pyridine]-(propan-2-ol)-erbium-tungsten dihydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1969471: Experimental Crystal Structure Determination

2021

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tetrakis(mu-cyano)-dicyano-bis(hydrogen tripyrazolylborate)-bis(2-(2-pyridyl)imidazole)-tetrakis(nitrato)-bis(triphenylphosphine oxide)-di-iron-di-neodymium acetonitrile solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 995949: Experimental Crystal Structure Determination

2015

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catena-[(mu-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-tris(mu-cyano)-(22'-bipyridine)-dinitrato-aqua-cyano-iron-nickel-dysprosium acetonitrile monohydrate]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1524159: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-cyano)-hexacyano-bis(110-phenanthroline)-bis(2-(1H-imidazol-2-yl)pyridine)-di-chromium(iii)-manganese(ii) trihydrateExperimental 3D Coordinates
researchProduct

CCDC 2073772: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[bis(mu-cyano)-(hydrogen tris(pyrazolyl)borate)-(22'-bipyridine-NN'-dioxide)-dinitrato-cyano-aqua-terbium(iii)-iron(iii) acetonitrile solvate]Cell ParametersExperimental 3D Coordinates
researchProduct

CCDC 953096: Experimental Crystal Structure Determination

2013

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Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[(mu~2~-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-tetrakis(mu~2~-cyano)-(22'-bipyridine)-aqua-(nitrato)-bis(cyano)-nickel-terbium-tungsten acetonitrile solvate hydrate]Cell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1574907: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-cyano)-tetracyano-bis(2-(1H-imidazol-2-yl)pyridine)-(22'-bipyridine)-manganese(ii)-tungsten(v) (22'-bipyridine)-hexacyano-tungsten(v)]Experimental 3D Coordinates
researchProduct

CCDC 2073774: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographycatena-[bis(mu-cyano)-(hydrogen tris(pyrazolyl)borate)-(22'-bipyridine-NN'-dioxide)-dinitrato-cyano-aqua-holmium(iii)-iron(iii) acetonitrile solvate]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1582397: Experimental Crystal Structure Determination

2018

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tetrakis(mu-cyano)-bis(cyano)-bis(hydrogen tris(pyrazolyl)borate)-bis(2-(1H-imidazol-2-yl)pyridine)-tetrakis(nitrato)-diaqua-di-iron(iii)-di-gadolinium(iii) hexahydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 989261: Experimental Crystal Structure Determination

2014

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Tetraphenylphosphonium tricyano-(29-dimethyl-110-phenanthroline)-cobalt(ii) trihydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 953097: Experimental Crystal Structure Determination

2013

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Space GroupCrystallographyCrystal Systemcatena-[(mu~2~-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-tetrakis(mu~2~-cyano)-(22'-bipyridine)-nitrato-aqua-dicyano-dysprosium-nickel-tungsten acetonitrile solvate hydrate]Crystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 2072597: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographycatena-(bis(mu-cyano)-(mu-25-bis(pyridin-2-yl)pyrazine)-aqua-hexacyano-(dimethyl sulfoxide)-(bis(1-methyl-1H-imidazol-2-yl)methanone)-tri-cobalt hydrate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1567346: Experimental Crystal Structure Determination

2017

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Space GroupCrystallographyCrystal System(mu-cyano)-diaqua-heptacyano-bis[2-(1H-imidazol-2-yl)pyridine]-(propan-2-ol)-gadolinium-tungsten dihydrateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1582340: Experimental Crystal Structure Determination

2017

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Space GroupCrystallographyCrystal SystemCrystal Structurecatena-(hexakis(mu-cyano)-(mu-oxalato)-tetrakis(mu-22'-[propane-13-diylbis(azanylylidenemethylylidene)]bis(6-methoxyphenolato))-tetra-aqua-hexacyano-di-chromium-tetra-copper-tetra-manganese hexahydrate)Cell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1585318: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographytetrakis(mu-cyano)-bis(cyano)-bis(hydrogen tris(pyrazolyl)borate)-tetrakis(2-(1H-imidazol-2-yl)pyridine)-tetrakis(nitrato)-di-iron(iii)-di-lanthanum(iii) decahydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1567347: Experimental Crystal Structure Determination

2017

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-cyano)-diaqua-heptacyano-bis[2-(1H-imidazol-2-yl)pyridine]-(propan-2-ol)-terbium-tungsten dihydrateExperimental 3D Coordinates
researchProduct

CCDC 989259: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D CoordinatesTetraphenylphosphonium tetracyano-(1-(pyridin-2-yl)methanamine)-cobalt(iii) sesquihydrate
researchProduct

CCDC 1567348: Experimental Crystal Structure Determination

2017

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(mu-cyano)-diaqua-heptacyano-bis[2-(1H-imidazol-2-yl)pyridine]-(propan-2-ol)-dysprosium-tungsten dihydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1969473: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstetrakis(mu-cyano)-dicyano-bis(hydrogen tripyrazolylborate)-bis(2-(2-pyridyl)imidazole)-tetrakis(nitrato)-bis(triphenylphosphine oxide)-di-iron-di-terbium acetonitrile solvateExperimental 3D Coordinates
researchProduct

CCDC 1892384: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(bis(mu-cyano)-(mu-25-bis(pyridin-2-yl)pyrazine)-hexacyano-(213-dimethyl-3691218-penta-azabicyclo[12.3.1]octadeca-1(18)2121416-pentaene)-di-cobalt-manganese heptahydrate)Experimental 3D Coordinates
researchProduct

CCDC 1403663: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-cyano)-bis(cyano)-(29-dimethyl-110-phenanthroline)-(22'-(ethane-12-diylbis(nitrilomethylylidene))diphenolato)-cobalt-manganese]Experimental 3D Coordinates
researchProduct

CCDC 1969472: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstetrakis(mu-cyano)-dicyano-bis(hydrogen tripyrazolylborate)-bis(2-(2-pyridyl)imidazole)-tetrakis(nitrato)-bis(triphenylphosphine oxide)-di-gadolinium-di-iron acetonitrile solvateExperimental 3D Coordinates
researchProduct

CCDC 953098: Experimental Crystal Structure Determination

2013

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu~2~-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-tetrakis(mu~2~-cyano)-aqua-(22'-bipyridine)-(nitrato)-bis(cyano)-nickel-gadolinium-tungsten acetonitrile solvate dihydrate]Experimental 3D Coordinates
researchProduct

CCDC 2054785: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu-25-bis(pyridin-2-yl)pyrazine)-tetrakis(mu-cyano)-bis(22'-[ethane-12-diylbis(azanylylidenemethanylylidene)]diphenolato)-tetracyano-di-cobalt-di-manganese]Experimental 3D Coordinates
researchProduct

CCDC 1574908: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal Systemcatena-[tris(mu-cyano)-(mu-1024-dimethyl-36141720-pentaazatricyclo[20.3.1.1812]heptacosa-1(26)268(27)91113202224-decaene-2627-diolato)-(22'-bipyridine)-tricyano-copper(ii)-manganese(ii)-tungsten(v) (22'-bipyridine)-hexacyano-tungsten(v) acetonitrile solvate hydrate]Crystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 995945: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-22'-(propane-13-diylbis(nitrilomethylylidene))bis(6-methoxyphenolato))-bis(mu-cyano)-bis(110-phenanthroline)-tetra-aqua-hexacyano-copper-di-iron-dysprosium nitrate heptahydrateExperimental 3D Coordinates
researchProduct

CCDC 1524158: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersaqua-tricyano-(mu-cyano)-nitrato-(110-phenanthroline)-(246-tris(pyridin-2-yl)-135-triazine)-chromium(iii)-manganese(ii) monohydrateExperimental 3D Coordinates
researchProduct

CCDC 1524157: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersaqua-tricyano-(mu-cyano)-nitrato-(246-tris(pyridin-2-yl)-135-triazine)-(1-(pyridin-2-yl)methanamine)-chromium(iii)-manganese(ii) acetonitrile unknown solvateExperimental 3D Coordinates
researchProduct

CCDC 1907944: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal Systemtetrakis(mu-cyano)-tetranitrato-dicyano-bis(triphenylphosphine oxide)-bis(2-(pyridin-2-yl)imidazolyl)-bis(hydrogen tris(pyrazolyl)borate)-di-iron-di-europium acetonitrile solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1403662: Experimental Crystal Structure Determination

2015

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Nadia Marino, Giovanni de Munno, Francesc Lloret, Miguel Julve|2015|RSC Advances|5|95410|doi:10.1039/C5RA16307B

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-cyano)-bis(cyano)-(44'-dimethyl-22'-bipyridine)-(22'-(ethane-12-diylbis(nitrilomethylylidene))diphenolato)-cobalt-manganese monohydrate]Experimental 3D Coordinates
researchProduct

CCDC 1510890: Experimental Crystal Structure Determination

2016

Related Article: Maria-Gabriela Alexandru, Diana Visinescu, Sergiu Shova, Francesc Lloret, Miguel Julve|2017|Dalton Trans.|46|39|doi:10.1039/C6DT04087J

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-[(22'-[ethane-12-diylbis(azanylylidenemethylylidene)]diphenolato)-(29-dimethyl-110-phenanthroline)-bis(mu-cyano)-cyano-cobalt(ii)-manganese(iii) dihydrate]
researchProduct

CCDC 1969475: Experimental Crystal Structure Determination

2021

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstetrakis(mu-cyano)-dicyano-bis(hydrogen tripyrazolylborate)-bis(2-(2-pyridyl)imidazole)-tetrakis(nitrato)-bis(triphenylphosphine oxide)-di-iron-di-praseodymium acetonitrile solvateExperimental 3D Coordinates
researchProduct