Influence of Host-Guest and Host-Host Interactions on the Spin-Crossover 3D Hofmann-type Clathrates {FeII(pina)[MI(CN)2]2·xMeOH (MI = Ag, Au)

[EN] The synthesis, structural characterization and magnetic properties of two new isostructural porous 3D compounds with the general formula {FeII(pina)[MI(CN)2]2}·xMeOH (x = 0¿5; pina = N-(pyridin-4-yl)isonicotinamide; MI = AgI and x ~ 5 (1·xMeOH); MI = AuI and x ~ 5 (2·xMeOH)) are presented. The single-crystal X-ray diffraction analyses have revealed that the structure of 1·xMeOH (or 2·xMeOH) presents two equivalent doubly interpenetrated 3D frameworks stabilized by both argentophilic (or aurophilic) interactions and interligand C¿O···HC H-bonds. Despite the interpenetration of the networks, these compounds display accessible void volume capable of hosting up to five molecules of methano…

Effect of Guest Molecules on Spin Transition Temperature in Loaded Hofmann‐Like Clathrates with Improved Porosity

The synthesis, crystal structure, magnetic and calorimetric studies of a new clathrate compound of the Hofmann-type spin crossover (SCO) metal-organic framework (MOF) {Fe(bpb)[MII(CN)4]}·xGuest (bpb = bis(4-pyridyl)butadiyne, and MII = Ni, Pt) with characteristic fsc topology is reported. The framework {Fe(bpb)[MII(CN)4]} can host up to 1.5 guest molecules of (trifluoromethyl)benzene and display complete one-step cooperative SCO behavior. Our systematic study on {Fe(bpb)[Pt(CN)4]}·xGuest shows a general reciprocal correlation between the SCO temperature with the volume of the guest molecules.

Spin crossover in iron(II) complexes with ferrocene-bearing triazole-pyridine ligands.

In the search for new multifunctional spin crossover molecular materials, here we describe the synthesis, crystal structures and magnetic and photomagnetic properties of the complexes trans-[Fe(Fctzpy)2(NCX)2]·CHCl3 where Fc-tzpy is the ferrocene-appended ligand 4-(2-pyridyl)-1H-1,2,3-triazol- 1-ylferrocene, X = S (1) and X = Se (2). Both complexes display thermal- and light-induced (LIESST) spin crossover properties characterised by T1/2 = 85 and 168 K, ΔS = 55 and 66 J K−1 mol−1 , ΔH = 4.7 and 11.1 kJ mol−1 and TLIESST = 47 K and 39 K for 1 and 2 respectively. The crystal structure of 1 and 2 measured at 275 K is consistent with the iron(II) ion in the high-spin state while the crystal st…

Guest induced reversible on–off switching of elastic frustration in a 3D spin crossover coordination polymer with room temperature hysteretic behaviour

A binary reversible switch between low-temperature multi-step spin crossover (SCO), through the evolution of the population γHS(T) with high-spin (HS)-low-spin (LS) sequence: HS1LS0 (state 1) ↔ HS2/3LS1/3 (state 2) ↔ HS1/2LS1/2 (state 3) ↔ HS1/3LS2/3 (state 4) ↔ HS0LS1 (state 5), and complete one step hysteretic spin transition featuring 20 K wide thermal hysteresis centred at 290 K occurs in the three-dimensional (3D) Hofmann-type porous coordination polymer {FeII(3,8phen)[Au(CN)2]2}·xPhNO2 (3,8phen = 3,8-phenanthroline, PhNO2 = nitrobenzene), made up of two identical interpenetrated pcu-type frameworks. The included PhNO2 guest (x = 1, 1·PhNO2) acts as a molecular wedge between the interp…

Innenrücktitelbild: First Step Towards a Devil's Staircase in Spin-Crossover Materials (Angew. Chem. 30/2016)

Guest Induced Strong Cooperative One- and Two-Step Spin Transitions in Highly Porous Iron(II) Hofmann-Type Metal-Organic Frameworks.

[EN] The synthesis, crystal structure, magnetic, calorimetric, and Mo¿ ssbauer studies of a series of new Hofmann-type spin crossover (SCO) metal¿organic frameworks (MOFs) is reported. The new SCO-MOFs arise from self-assembly of FeII, bis(4-pyridyl)butadiyne (bpb), and [Ag(CN)2] ¿ or [MII(CN)4] 2¿ (MII = Ni, Pd). Interpenetration of four identical 3D networks with ¿-Po topology are obtained for {Fe(bpb)[AgI (CN)2]2} due to the length of the rod-like bismonodentate bpb and [Ag(CN)2] ¿ ligands. The four networks are tightly packed and organized in two subsets orthogonally interpenetrated, while the networks in each subset display parallel interpenetration. This nonporous material undergoes a…

Chiral and Racemic Spin Crossover Polymorphs in a Family of Mononuclear Iron(II) Compounds

[EN] Understanding the origin of cooperativity and the equilibrium temperature of transition (T1/2) displayed by the spin-crossover (SCO) compounds as well as controlling these parameters are of paramount importance for future applications. For this task, the occurrence of polymorphism, presented by a number of SCO complexes, may provide deep insight into the influence of the supramolecular organization on the SCO behavior. In this context, herein we present a novel family of mononuclear octahedral FeII complexes with formula cis- [Fe(bqen)(NCX)2], where bqen is the chelating tetradentate ligand N,N¿-bis(8-quinolyl)ethane-1,2-diamine and X = S, Se. Depending on the preparation method, these…

Inside Back Cover: First Step Towards a Devil's Staircase in Spin-Crossover Materials (Angew. Chem. Int. Ed. 30/2016)

International audience; Periodic and aperiodic spin-state concentration waves form during “Devil's staircase”-type spin-crossover in a new bimetallic 2D coordination polymer {Fe[(Hg(SCN)3)2](4,4′-bipy)2}n. In their Communication on page 8675 ff., J. A. Real, E. Collet et al. describe the appearance of spin-state concentration waves between long-range spatially ordered structures of low- and high-spin states during multistep spin-crossover.

Electronic Structure Modulation in an Exceptionally Stable Non-Heme Nitrosyl Iron(II) Spin-Crossover Complex

The highly stable nitrosyl iron(II) mononuclear complex [Fe(bztpen)(NO)](PF6)(2) (bztpen=N-benzyl-N,N',N'-tris(2-pyridylmethyl)ethylenediamine) displays an S=1/2 S=3/2 spin crossover (SCO) behavior (T-1/2=370 K, Delta H= 12.48 kJmol(-1), Delta S=33 JK(-1) mol(-1)) stemming from strong magnetic coupling between the NO radical (S=1/2) and thermally interconverted (S=0 S=2) ferrous spin states. The crystal structure of this robust complex has been investigated in the temperature range 120-420 K affording a detailed picture of how the electronic distribution of the t(2g)-e(g) orbitals modulates the structure of the {FeNO}(7) bond, providing valuable magneto-structural and spectroscopic correlat…

Spin crossover behavior in a series of iron(III) alkoxide complexes.

The synthesis, crystal structures, magnetic behavior, and electron paramagnetic resonance studies of five new FeIII spin crossover (SCO) complexes are reported. The [FeIIIN5O] coordination core is constituted of the pentadentate ligand bztpen (N5) and a series of alkoxide anions (ethoxide, propoxide, n-butoxide, isobutoxide, and ethylene glycoxide). The methoxide derivative previously reported by us is also reinvestigated. The six complexes crystallize in the orthorhombic Pbca space group and show similar molecular structures and crystal packing. The coordination octahedron is strongly distorted in both the high- and low-temperature structures. The structural changes upon spin conversion ar…

Extrinsicvs.intrinsic luminescence and their interplay with spin crossover in 3D Hofmann-type coordination polymers

The research of new multifunctional materials, as those undergoing spin crossover (SCO) and luminescent properties, is extremely important in the development of further optical and electronic switching devices. As a new step towards this ambitious aim, the coupling of SCO and fluorescence is presented here following two main strategies: whether the fluorescent agent is integrated as a part of the main structure of a 3D SCO coordination polymer {FeII(bpan)[MI(CN)2]2} (bpan = bis(4-pyridyl)anthracene, MI = Ag (FebpanAg), Au (FebpanAu)) or is a guest molecule inserted within the cavities of the 3D switchable framework {FeII(bpb)[MI(CN)2]2}·pyrene (bpb = bis(4-pyridyl)butadiyne, MI = Ag (FebpbA…

Clathration of Five-Membered Aromatic Rings in the Bimetallic Spin Crossover Metal–Organic Framework [Fe(TPT)2/3{MI(CN)2}2]·G (MI = Ag, Au)

Six clathrate compounds of the three-dimensional spin crossover metal−organic framework formulated [Fe(TPT)2/3{MI (CN)2}2]· nG, where TPT is 2,4,6-tris(4-pyridyl)-1,3,5-triazine, MI = Ag or Au and G represent the guest molecules furan, pyrrole and thiophene, were synthesized using slow diffusion techniques. The clathrate compounds were characterized by single-crystal X-ray diffraction at 120 and 300 K, thermogravimetric analysis and thermal dependence of the magnetic susceptibility. All compounds crystallize in the R3̅ m trigonal space group. The FeII defines a unique [FeN6] crystallographic site with the equatorial positions occupied by four dicyanometallate ligands while the axial positio…

Structural, magnetic and calorimetric studies of a crystalline phase of the spin crossover compound [Fe(tzpy)2(NCSe)2]

The compound [Fe(tzpy)2(NCSe)2] (tzpy = 3-(2-pyridyl)-[1,2,3]triazolo[1,5-a]pyridine)) has been synthesized and its crystal structure, magnetic behavior and calorimetric properties investigated. Samples constituted of single crystals of [Fe(tzpy)2(NCSe) 2] display a relatively cooperative spin-state change centered at T1/2 ¿ 251.7 K with a hysteresis loop 3.5 K wide. The average enthalpy (¿H) and entropy (¿S) changes upon the spin crossover behavior (SCO) obtained from DSC measurements are 11.1 ± 0.4 kJ mol -1 and 44.5 ± 3 J K-1 mol-1, respectively. The magnetic and calorimetric data have been satisfactorily simulated using the mean-field regular solution model (Slichter-Drickamer) and the …

Thermo- and photo-modulation of exciplex fluorescence in a 3D spin crossover Hofmann-type coordination polymer

[EN] The search for bifunctional materials showing synergies between spin crossover (SCO) and luminescence has attracted substantial interest since they could be promising platforms for new switching electronic and optical technologies. In this context, we present the first three-dimensional Fe-II Hofmann-type coordination polymer exhibiting SCO properties and luminescence. The complex {Fe-II(bpben)[Au(CN)(2)]}@pyr (bpben = 1,4-bis(4-pyridyl)benzene) functionalized with pyrene (pyr) guests undergoes a cooperative multi-step SCO, which has been investigated by single crystal X-ray diffraction, single crystal UV-Vis absorption spectroscopy, and magnetic and calorimetric measurements. The resu…

Two- and one-step cooperative spin transitions in Hofmann-like clathrates with enhanced loading capacity

Structural, magnetic, calorimetric and Mo¨ssbauer studies of the cooperative spin crossover naphthalene and nitrobenzene clathrates of the novel FeII Hofmann-like porous metal–organic framework {Fe(bpb)[Pt(CN)4]}2Guest are described (bpb = bis(4-pyridyl)butadiyne).

Pulsed-laser switching in the bistability domain of a cooperative spin crossover compound: a critical study through calorimetry

The photoswitching from the low spin (LS) to high spin (HS) state and the reverse process in the bistability domain of spin crossover (SCO) compounds is a promising function to be used in molecular electronic devices, and evidenced mainly through spectroscopy. The phenomenon, and in particular its mechanism, is however still under debate since some controversial experimental results have been reported. Here we present a calorimetric experimental study of the photoswitching of the [Fe(pyrazine)Pt(CN)4] SCO material by a nanosecond-pulsed green laser. Our results confirm that the single laser pulse of varying energies results in significant LS to HS transformations and show that calorimetry p…

Homoleptic iron(II) complexes with the ionogenic ligand 6,6′-Bis(1H-tetrazol-5-yl)-2,2′-bipyridine: spin crossover behavior in a singular 2D spin crossover coordination polymer

Deprotonation of the ionogenic tetradentate ligand 6,6′-bis(1H-tetrazol-5-yl)-2,2′-bipyridine [H2bipy(ttr)2] in the presence of FeII in solution has afforded an anionic mononuclear complex and a neutral two-dimensional coordination polymer formulated as, respectively, NEt3H{Fe[bipy(ttr)2][Hbipy(ttr)2]}·3MeOH (1) and {Fe[bipy(ttr)2]}n (2). The anions [Hbipy(ttr)2]− and [bipy(ttr)2]2– embrace the FeII centers defining discrete molecular units 1 with the FeII ion lying in a distorted bisdisphenoid dodecahedron, a rare example of octacoordination in the coordination environment of this cation. The magnetic behavior of 1 shows that the FeII is high-spin, and its Mössbauer spectrum is characteriz…

Nanoporosity, Inclusion Chemistry, and Spin Crossover in Orthogonally Interlocked Two-Dimensional Metal-Organic Frameworks

[Fe(tvp)(2)(NCS)(2)] (1) (tvp=trans-(4,4-vinylenedipyridine)) consists of two independent perpendicular stacks of mutually interpenetrated two-dimensional grids. This uncommon supramolecular conformation defines square-sectional nanochannels (diagonal approximate to 2.2nm) in which inclusion molecules are located. The guest-loaded framework 1@guest displays complete thermal spin-crossover (SCO) behavior with the characteristic temperature T-1/2 dependent on the guest molecule, whereas the guest-free species 1 is paramagnetic whatever the temperature. For the benzene-guest derivatives, the characteristic SCO temperature T-1/2 decreases as the Hammet sigma(p) parameter increases. In general, …

catena-Poly[[diaquabis[1,4-bis(pyridin-4-yl)buta-1,3-diyne-κN]iron(II)]-μ-cyanido-κ2N:C-[dicyanido-κ2C-platinum(II)]-μ-cyanido-κ2C:N]

The molecular structure of the title compound, [FePt(CN)4(C14H8N2)2(H2O)2]n, consists of one-dimensional polymeric [–Fe–NC–Pt(CN)2–CN–]∞chains. Two water molecules and two monodentate 1,4-bis(pyridin-4-yl)buta-1,3-diyne (bpb) ligand molecules complete the octahedral coordination sphere of the FeIIatoms. The Fe—N(py) bond length (py is pyridine) is 2.2700 (15) Å, Fe—N(cyanide) is 2.1185 (16) Å and the Fe—O distance is 2.1275 (14) Å. The water molecules are hydrogen bonded to either bpb ligands or cyanide groups of the planar [Pt(CN)4]2−anion of adjacent polymeric chains. These O—H...N hydrogen bonds, in conjunction with offset and tilted π–π stacking interactions between bpb ligands and cyan…

Cover Feature: Cyanido‐Bridged Fe II –M I Dimetallic Hofmann‐Like Spin‐Crossover Coordination Polymers Based on 2,6‐Naphthyridine (Eur. J. Inorg. Chem. 3‐4/2018)

Cyanido-Bridged FeII-MI Dimetallic Hofmann-Like Spin-Crossover Coordination Polymers Based on 2,6-Naphthyridine

[EN] Two new 3D spin-crossover (SCO) Hofmann-type coordination polymers {Fe(2,6-naphthy)[Ag(CN)2][Ag2(CN)3]} (1; 2,6-naphthy = 2,6-naphthyridine) and {Fe(2,6-naphthy)- [Au(CN)2]2}·0.5PhNO2 (2) were synthesized and characterized. Both derivatives are made up of infinite stacks of {Fe[Ag(CN)2]2- [Ag2(CN)3]}n and {Fe[Au(CN)2]2}n layered grids connected by pillars of 2,6-naphthy ligands coordinated to the axial positions of the FeII centers of alternate layers.

Exploiting Pressure To Induce a "Guest-Blocked" Spin Transition in a Framework Material.

A new functionalized 1,2,4-triazole ligand, 4-[(E)-2-(5-methyl-2-thienyl)vinyl]-1,2,4-triazole (thiome), was prepared to assess the broad applicability of strategically producing multistep spin transitions in two-dimensional Hofmann-type materials of the type [FeIIPd(CN)4(R-1,2,4-trz)2]·nH2O (R-1,2,4-trz = a 4-functionalized 1,2,4-triazole ligand). A variety of structural and magnetic investigations on the resultant framework material [FeIIPd(CN)4(thiome)2]·2H2O (A·2H2O) reveal that a high-spin (HS) to low-spin (LS) transition is inhibited in A·2H2O due to a combination of guest and ligand steric bulk effects. The water molecules can be reversibly removed with retention of the porous host f…

{[Hg(SCN)3]2(n-L)}2-: An Efficient Secondary Building Unit for the Synthesis of 2D Iron(II) Spin-Crossover Coordination Polymers

[EN] We report an unprecedented series of two-dimensional (2D) spin-crossover (SCO) heterobimetallic coordination polymers generically formulated as {Fe-II[(He(SCN)(3))(2)](L)(x))}center dot Solv, where x = 2 for L = tvp (trans-(4,4'-vinylenedipyridine)) (1tvp), bpmh ((1E,2E)-1,2-bis(pyridin-4-ylmethylene)hydrazine) (1bpmh center dot nCH(3)OH; n = 0, 1), by eh ( (1E,2E)-1,2-bis (1-(pyridin-4-yl) ethyliden e) hydrazine) (Ibpeh center dot nH(2)O; n = 0, 1) and x = 2.33 for L = 0 0 bpbz (1,4-bis(pyridin-4-yl)benzene) (1bpbz center dot nH(2)O; n = 0, 2/ 3). The results confirm that self-assembly of Fell, [Hg-II(SCN)(4)](2-), and ditopic rodlike bridging ligands L containing 4-pyridyl moieties f…

Competing Phases Involving Spin-State and Ligand Structural Orderings in a Multistable Two-Dimensional Spin Crossover Coordination Polymer

[EN] Competition between spin-crossover and structural ligand ordering is identified as responsible for multistability and generation of six different phases in a rigid two-dimensional coordination polymer formulated {Fe-II[Hg-II(SCN)(3)](2) mu-(4,4'-bipy)(2)}(n) (1) (4,4'-bipy = 4,4'-bipyridine). The structure of 1 consists of infinite linear [Fe(mu-4,4'-bipy)](n)(2n+) chains linked by in situ formed {[Hg-II(SCN)(3)](2)(mu-4,4'-bipy)}(2n-) anionic dimers. The thermal dependence of the high-spin fraction, his, features four magnetic phases defined by steps following the sequence gamma(HS) = 1 (phase 1) gamma(HS) = 1/2 (phase 2) gamma(HS) approximate to 1/3 (phase 3) gamma(HS) = 0 (phase 4) …

CCDC 1042612: Experimental Crystal Structure Determination

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

CCDC 971025: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Maksym Seredyuk, M. Carmen Muñoz, José A. Real|2014|Chem.Commun.|50|1833|doi:10.1039/C3CC48595A

CCDC 1965274: Experimental Crystal Structure Determination

Related Article: Manuel Meneses-Sánchez, Lucía Piñeiro-López, Teresa Delgado, Carlos Bartual-Murgui, M. Carmen Muñoz, Pradip Chakraborty, José Antonio Real|2020|J.Mater.Chem.C|8|1623|doi:10.1039/C9TC06422B

CCDC 1417554: Experimental Crystal Structure Determination

Related Article: Tania Romero-Morcillo, Francisco Javier Valverde-Muñoz, Lucía Piñeiro-López, M. Carmen Muñoz, Tomás Romero, Pedro Molina, José A. Real|2015|Dalton Trans.|44|18911|doi:10.1039/C5DT03084F

CCDC 1480120: Experimental Crystal Structure Determination

Related Article: Natasha F. Sciortino, Florence Ragon, Katrina A. Zenere, Peter D. Southon, Gregory J. Halder, Karena W. Chapman, Lucía Piñeiro-López, José A. Real, Cameron J. Kepert, and Suzanne M. Neville|2016|Inorg.Chem.|55|10490|doi:10.1021/acs.inorgchem.6b01686

CCDC 1050042: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Zulema Arcís-Castillo, M. Carmen Muñoz, and José A. Real|2014|Cryst.Growth Des.|14|6311|doi:10.1021/cg5010616

CCDC 2016312: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco-Javier Valverde-Muñoz, Elzbieta Trzop, M. Carmen Muñoz, Maksym Seredyuk, Javier Castells-Gil, Iván da Silva, Carlos Martí-Gastaldo, Eric Collet, José Antonio Real|2021|Chemical Science|12|1317|doi:10.1039/D0SC04420B

CCDC 1572177: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

CCDC 1572180: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

CCDC 971023: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Maksym Seredyuk, M. Carmen Muñoz, José A. Real|2014|Chem.Commun.|50|1833|doi:10.1039/C3CC48595A

CCDC 1042617: Experimental Crystal Structure Determination

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

CCDC 1572183: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

CCDC 1572184: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

CCDC 1042613: Experimental Crystal Structure Determination

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

CCDC 1910592: Experimental Crystal Structure Determination

Related Article: Francisco Javier Valverde-Muñoz, Carlos Bartual-Murgui, Lucía Piñeiro-López, M. Carmen Muñoz, José Antonio Real|2019|Inorg.Chem.|58|10038|doi:10.1021/acs.inorgchem.9b01189

CCDC 1050041: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Zulema Arcís-Castillo, M. Carmen Muñoz, and José A. Real|2014|Cryst.Growth Des.|14|6311|doi:10.1021/cg5010616

CCDC 1565402: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco Javier-Valverde-Muñoz, Maksym Seredyuk, Carlos Bartual-Murgui, M. Carmen Muñoz, José Antonio Real|2018|Eur.J.Inorg.Chem.||289|doi:10.1002/ejic.201700920

CCDC 1020145: Experimental Crystal Structure Determination

Related Article: Norma Ortega-Villar, Areli Yesareth Guerrero-Estrada, Lucía Piñeiro-López, M. Carmen Muñoz, Marcos Flores-Álamo, Rafael Moreno-Esparza, José A. Real, and Víctor M. Ugalde-Saldívar|2015|Inorg.Chem.|54|3413|doi:10.1021/ic503081x

CCDC 1050040: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Zulema Arcís-Castillo, M. Carmen Muñoz, and José A. Real|2014|Cryst.Growth Des.|14|6311|doi:10.1021/cg5010616

CCDC 1020141: Experimental Crystal Structure Determination

Related Article: Norma Ortega-Villar, Areli Yesareth Guerrero-Estrada, Lucía Piñeiro-López, M. Carmen Muñoz, Marcos Flores-Álamo, Rafael Moreno-Esparza, José A. Real, and Víctor M. Ugalde-Saldívar|2015|Inorg.Chem.|54|3413|doi:10.1021/ic503081x

CCDC 1572181: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

CCDC 1480121: Experimental Crystal Structure Determination

Related Article: Natasha F. Sciortino, Florence Ragon, Katrina A. Zenere, Peter D. Southon, Gregory J. Halder, Karena W. Chapman, Lucía Piñeiro-López, José A. Real, Cameron J. Kepert, and Suzanne M. Neville|2016|Inorg.Chem.|55|10490|doi:10.1021/acs.inorgchem.6b01686

CCDC 1457784: Experimental Crystal Structure Determination

Related Article: Daopeng Zhang, Elzbieta Trzop, Francisco J. Valverde-Muñoz, Lucía Piñeiro-López, M. Carmen Muñoz, Eric Collet, José A. Real|2017|Cryst.Growth Des.|17|2736|doi:10.1021/acs.cgd.7b00218

CCDC 1418191: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk , Lucía Piñeiro-López , M. Carmen Muñoz , Francisco J. Martínez-Casado , Gábor Molnár , José Alberto Rodriguez-Velamazán , Azzedine Bousseksou , José Antonio Real|2015|Inorg.Chem.|54|7424|doi:10.1021/acs.inorgchem.5b01001

CCDC 1020147: Experimental Crystal Structure Determination

Related Article: Norma Ortega-Villar, Areli Yesareth Guerrero-Estrada, Lucía Piñeiro-López, M. Carmen Muñoz, Marcos Flores-Álamo, Rafael Moreno-Esparza, José A. Real, and Víctor M. Ugalde-Saldívar|2015|Inorg.Chem.|54|3413|doi:10.1021/ic503081x

CCDC 1847351: Experimental Crystal Structure Determination

Related Article: Teresa Delgado, Manuel Meneses-Sánchez, Lucía Piñeiro-López, Carlos Bartual-Murgui, M. Carmen Muñoz, José Antonio Real|2018|Chemical Science|9|8446|doi:10.1039/C8SC02677G

CCDC 1418192: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk , Lucía Piñeiro-López , M. Carmen Muñoz , Francisco J. Martínez-Casado , Gábor Molnár , José Alberto Rodriguez-Velamazán , Azzedine Bousseksou , José Antonio Real|2015|Inorg.Chem.|54|7424|doi:10.1021/acs.inorgchem.5b01001

CCDC 2010363: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco-Javier Valverde-Muñoz, Elzbieta Trzop, M. Carmen Muñoz, Maksym Seredyuk, Javier Castells-Gil, Iván da Silva, Carlos Martí-Gastaldo, Eric Collet, José Antonio Real|2021|Chemical Science|12|1317|doi:10.1039/D0SC04420B

CCDC 1480123: Experimental Crystal Structure Determination

Related Article: Natasha F. Sciortino, Florence Ragon, Katrina A. Zenere, Peter D. Southon, Gregory J. Halder, Karena W. Chapman, Lucía Piñeiro-López, José A. Real, Cameron J. Kepert, and Suzanne M. Neville|2016|Inorg.Chem.|55|10490|doi:10.1021/acs.inorgchem.6b01686

CCDC 1050034: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Zulema Arcís-Castillo, M. Carmen Muñoz, and José A. Real|2014|Cryst.Growth Des.|14|6311|doi:10.1021/cg5010616

CCDC 1020143: Experimental Crystal Structure Determination

Related Article: Norma Ortega-Villar, Areli Yesareth Guerrero-Estrada, Lucía Piñeiro-López, M. Carmen Muñoz, Marcos Flores-Álamo, Rafael Moreno-Esparza, José A. Real, and Víctor M. Ugalde-Saldívar|2015|Inorg.Chem.|54|3413|doi:10.1021/ic503081x

CCDC 1457780: Experimental Crystal Structure Determination

Related Article: Daopeng Zhang, Elzbieta Trzop, Francisco J. Valverde-Muñoz, Lucía Piñeiro-López, M. Carmen Muñoz, Eric Collet, José A. Real|2017|Cryst.Growth Des.|17|2736|doi:10.1021/acs.cgd.7b00218

CCDC 1418190: Experimental Crystal Structure Determination

Related Article: Maksym Seredyuk , Lucía Piñeiro-López , M. Carmen Muñoz , Francisco J. Martínez-Casado , Gábor Molnár , José Alberto Rodriguez-Velamazán , Azzedine Bousseksou , José Antonio Real|2015|Inorg.Chem.|54|7424|doi:10.1021/acs.inorgchem.5b01001

CCDC 1910594: Experimental Crystal Structure Determination

Related Article: Francisco Javier Valverde-Muñoz, Carlos Bartual-Murgui, Lucía Piñeiro-López, M. Carmen Muñoz, José Antonio Real|2019|Inorg.Chem.|58|10038|doi:10.1021/acs.inorgchem.9b01189

CCDC 1847352: Experimental Crystal Structure Determination

Related Article: Teresa Delgado, Manuel Meneses-Sánchez, Lucía Piñeiro-López, Carlos Bartual-Murgui, M. Carmen Muñoz, José Antonio Real|2018|Chemical Science|9|8446|doi:10.1039/C8SC02677G

CCDC 1572182: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

CCDC 1585097: Experimental Crystal Structure Determination

Related Article: Daopeng Zhang, Francisco Javier Valverde-Muñoz, Carlos Bartual-Murgui, Lucía Piñeiro-López, M. Carmen Muñoz, José Antonio Real|2018|Inorg.Chem.|57|1562|doi:10.1021/acs.inorgchem.7b02906

CCDC 1910593: Experimental Crystal Structure Determination

Related Article: Francisco Javier Valverde-Muñoz, Carlos Bartual-Murgui, Lucía Piñeiro-López, M. Carmen Muñoz, José Antonio Real|2019|Inorg.Chem.|58|10038|doi:10.1021/acs.inorgchem.9b01189

CCDC 1020146: Experimental Crystal Structure Determination

Related Article: Norma Ortega-Villar, Areli Yesareth Guerrero-Estrada, Lucía Piñeiro-López, M. Carmen Muñoz, Marcos Flores-Álamo, Rafael Moreno-Esparza, José A. Real, and Víctor M. Ugalde-Saldívar|2015|Inorg.Chem.|54|3413|doi:10.1021/ic503081x

CCDC 2010365: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco-Javier Valverde-Muñoz, Elzbieta Trzop, M. Carmen Muñoz, Maksym Seredyuk, Javier Castells-Gil, Iván da Silva, Carlos Martí-Gastaldo, Eric Collet, José Antonio Real|2021|Chemical Science|12|1317|doi:10.1039/D0SC04420B

CCDC 1457779: Experimental Crystal Structure Determination

Related Article: Daopeng Zhang, Elzbieta Trzop, Francisco J. Valverde-Muñoz, Lucía Piñeiro-López, M. Carmen Muñoz, Eric Collet, José A. Real|2017|Cryst.Growth Des.|17|2736|doi:10.1021/acs.cgd.7b00218

CCDC 1050032: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Zulema Arcís-Castillo, M. Carmen Muñoz, and José A. Real|2014|Cryst.Growth Des.|14|6311|doi:10.1021/cg5010616

CCDC 971022: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Maksym Seredyuk, M. Carmen Muñoz, José A. Real|2014|Chem.Commun.|50|1833|doi:10.1039/C3CC48595A

CCDC 1565404: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco Javier-Valverde-Muñoz, Maksym Seredyuk, Carlos Bartual-Murgui, M. Carmen Muñoz, José Antonio Real|2018|Eur.J.Inorg.Chem.||289|doi:10.1002/ejic.201700920

CCDC 971024: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Maksym Seredyuk, M. Carmen Muñoz, José A. Real|2014|Chem.Commun.|50|1833|doi:10.1039/C3CC48595A

CCDC 1965275: Experimental Crystal Structure Determination

Related Article: Manuel Meneses-Sánchez, Lucía Piñeiro-López, Teresa Delgado, Carlos Bartual-Murgui, M. Carmen Muñoz, Pradip Chakraborty, José Antonio Real|2020|J.Mater.Chem.C|8|1623|doi:10.1039/C9TC06422B

CCDC 1585098: Experimental Crystal Structure Determination

Related Article: Daopeng Zhang, Francisco Javier Valverde-Muñoz, Carlos Bartual-Murgui, Lucía Piñeiro-López, M. Carmen Muñoz, José Antonio Real|2018|Inorg.Chem.|57|1562|doi:10.1021/acs.inorgchem.7b02906

CCDC 1417556: Experimental Crystal Structure Determination

Related Article: Tania Romero-Morcillo, Francisco Javier Valverde-Muñoz, Lucía Piñeiro-López, M. Carmen Muñoz, Tomás Romero, Pedro Molina, José A. Real|2015|Dalton Trans.|44|18911|doi:10.1039/C5DT03084F

CCDC 1020142: Experimental Crystal Structure Determination

Related Article: Norma Ortega-Villar, Areli Yesareth Guerrero-Estrada, Lucía Piñeiro-López, M. Carmen Muñoz, Marcos Flores-Álamo, Rafael Moreno-Esparza, José A. Real, and Víctor M. Ugalde-Saldívar|2015|Inorg.Chem.|54|3413|doi:10.1021/ic503081x

CCDC 1965272: Experimental Crystal Structure Determination

Related Article: Manuel Meneses-Sánchez, Lucía Piñeiro-López, Teresa Delgado, Carlos Bartual-Murgui, M. Carmen Muñoz, Pradip Chakraborty, José Antonio Real|2020|J.Mater.Chem.C|8|1623|doi:10.1039/C9TC06422B

CCDC 2010361: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco-Javier Valverde-Muñoz, Elzbieta Trzop, M. Carmen Muñoz, Maksym Seredyuk, Javier Castells-Gil, Iván da Silva, Carlos Martí-Gastaldo, Eric Collet, José Antonio Real|2021|Chemical Science|12|1317|doi:10.1039/D0SC04420B

CCDC 1050039: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Zulema Arcís-Castillo, M. Carmen Muñoz, and José A. Real|2014|Cryst.Growth Des.|14|6311|doi:10.1021/cg5010616

CCDC 1480122: Experimental Crystal Structure Determination

Related Article: Natasha F. Sciortino, Florence Ragon, Katrina A. Zenere, Peter D. Southon, Gregory J. Halder, Karena W. Chapman, Lucía Piñeiro-López, José A. Real, Cameron J. Kepert, and Suzanne M. Neville|2016|Inorg.Chem.|55|10490|doi:10.1021/acs.inorgchem.6b01686

CCDC 1965273: Experimental Crystal Structure Determination

Related Article: Manuel Meneses-Sánchez, Lucía Piñeiro-López, Teresa Delgado, Carlos Bartual-Murgui, M. Carmen Muñoz, Pradip Chakraborty, José Antonio Real|2020|J.Mater.Chem.C|8|1623|doi:10.1039/C9TC06422B

CCDC 1042615: Experimental Crystal Structure Determination

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

CCDC 1020140: Experimental Crystal Structure Determination

Related Article: Norma Ortega-Villar, Areli Yesareth Guerrero-Estrada, Lucía Piñeiro-López, M. Carmen Muñoz, Marcos Flores-Álamo, Rafael Moreno-Esparza, José A. Real, and Víctor M. Ugalde-Saldívar|2015|Inorg.Chem.|54|3413|doi:10.1021/ic503081x

CCDC 1565403: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco Javier-Valverde-Muñoz, Maksym Seredyuk, Carlos Bartual-Murgui, M. Carmen Muñoz, José Antonio Real|2018|Eur.J.Inorg.Chem.||289|doi:10.1002/ejic.201700920

CCDC 1042614: Experimental Crystal Structure Determination

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

CCDC 1585096: Experimental Crystal Structure Determination

Related Article: Daopeng Zhang, Francisco Javier Valverde-Muñoz, Carlos Bartual-Murgui, Lucía Piñeiro-López, M. Carmen Muñoz, José Antonio Real|2018|Inorg.Chem.|57|1562|doi:10.1021/acs.inorgchem.7b02906

CCDC 1050043: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Zulema Arcís-Castillo, M. Carmen Muñoz, and José A. Real|2014|Cryst.Growth Des.|14|6311|doi:10.1021/cg5010616

CCDC 2010360: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco-Javier Valverde-Muñoz, Elzbieta Trzop, M. Carmen Muñoz, Maksym Seredyuk, Javier Castells-Gil, Iván da Silva, Carlos Martí-Gastaldo, Eric Collet, José Antonio Real|2021|Chemical Science|12|1317|doi:10.1039/D0SC04420B

CCDC 1417555: Experimental Crystal Structure Determination

Related Article: Tania Romero-Morcillo, Francisco Javier Valverde-Muñoz, Lucía Piñeiro-López, M. Carmen Muñoz, Tomás Romero, Pedro Molina, José A. Real|2015|Dalton Trans.|44|18911|doi:10.1039/C5DT03084F

CCDC 1050036: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Zulema Arcís-Castillo, M. Carmen Muñoz, and José A. Real|2014|Cryst.Growth Des.|14|6311|doi:10.1021/cg5010616

CCDC 1585094: Experimental Crystal Structure Determination

Related Article: Daopeng Zhang, Francisco Javier Valverde-Muñoz, Carlos Bartual-Murgui, Lucía Piñeiro-López, M. Carmen Muñoz, José Antonio Real|2018|Inorg.Chem.|57|1562|doi:10.1021/acs.inorgchem.7b02906

CCDC 1050033: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Zulema Arcís-Castillo, M. Carmen Muñoz, and José A. Real|2014|Cryst.Growth Des.|14|6311|doi:10.1021/cg5010616

CCDC 1910591: Experimental Crystal Structure Determination

Related Article: Francisco Javier Valverde-Muñoz, Carlos Bartual-Murgui, Lucía Piñeiro-López, M. Carmen Muñoz, José Antonio Real|2019|Inorg.Chem.|58|10038|doi:10.1021/acs.inorgchem.9b01189

CCDC 1585095: Experimental Crystal Structure Determination

Related Article: Daopeng Zhang, Francisco Javier Valverde-Muñoz, Carlos Bartual-Murgui, Lucía Piñeiro-López, M. Carmen Muñoz, José Antonio Real|2018|Inorg.Chem.|57|1562|doi:10.1021/acs.inorgchem.7b02906

CCDC 1965271: Experimental Crystal Structure Determination

Related Article: Manuel Meneses-Sánchez, Lucía Piñeiro-López, Teresa Delgado, Carlos Bartual-Murgui, M. Carmen Muñoz, Pradip Chakraborty, José Antonio Real|2020|J.Mater.Chem.C|8|1623|doi:10.1039/C9TC06422B

CCDC 2010362: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco-Javier Valverde-Muñoz, Elzbieta Trzop, M. Carmen Muñoz, Maksym Seredyuk, Javier Castells-Gil, Iván da Silva, Carlos Martí-Gastaldo, Eric Collet, José Antonio Real|2021|Chemical Science|12|1317|doi:10.1039/D0SC04420B

CCDC 2010366: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco-Javier Valverde-Muñoz, Elzbieta Trzop, M. Carmen Muñoz, Maksym Seredyuk, Javier Castells-Gil, Iván da Silva, Carlos Martí-Gastaldo, Eric Collet, José Antonio Real|2021|Chemical Science|12|1317|doi:10.1039/D0SC04420B

CCDC 1965270: Experimental Crystal Structure Determination

Related Article: Manuel Meneses-Sánchez, Lucía Piñeiro-López, Teresa Delgado, Carlos Bartual-Murgui, M. Carmen Muñoz, Pradip Chakraborty, José Antonio Real|2020|J.Mater.Chem.C|8|1623|doi:10.1039/C9TC06422B

CCDC 1050038: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Zulema Arcís-Castillo, M. Carmen Muñoz, and José A. Real|2014|Cryst.Growth Des.|14|6311|doi:10.1021/cg5010616

CCDC 1862017: Experimental Crystal Structure Determination

Related Article: Teresa Delgado, Manuel Meneses-Sánchez, Lucía Piñeiro-López, Carlos Bartual-Murgui, M. Carmen Muñoz, José Antonio Real|2018|Chemical Science|9|8446|doi:10.1039/C8SC02677G

CCDC 1572179: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

CCDC 1572178: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

CCDC 1020148: Experimental Crystal Structure Determination

Related Article: Norma Ortega-Villar, Areli Yesareth Guerrero-Estrada, Lucía Piñeiro-López, M. Carmen Muñoz, Marcos Flores-Álamo, Rafael Moreno-Esparza, José A. Real, and Víctor M. Ugalde-Saldívar|2015|Inorg.Chem.|54|3413|doi:10.1021/ic503081x

CCDC 1020149: Experimental Crystal Structure Determination

Related Article: Norma Ortega-Villar, Areli Yesareth Guerrero-Estrada, Lucía Piñeiro-López, M. Carmen Muñoz, Marcos Flores-Álamo, Rafael Moreno-Esparza, José A. Real, and Víctor M. Ugalde-Saldívar|2015|Inorg.Chem.|54|3413|doi:10.1021/ic503081x

CCDC 1042616: Experimental Crystal Structure Determination

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

CCDC 1020144: Experimental Crystal Structure Determination

Related Article: Norma Ortega-Villar, Areli Yesareth Guerrero-Estrada, Lucía Piñeiro-López, M. Carmen Muñoz, Marcos Flores-Álamo, Rafael Moreno-Esparza, José A. Real, and Víctor M. Ugalde-Saldívar|2015|Inorg.Chem.|54|3413|doi:10.1021/ic503081x

CCDC 1050035: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Zulema Arcís-Castillo, M. Carmen Muñoz, and José A. Real|2014|Cryst.Growth Des.|14|6311|doi:10.1021/cg5010616

CCDC 1585093: Experimental Crystal Structure Determination

Related Article: Daopeng Zhang, Francisco Javier Valverde-Muñoz, Carlos Bartual-Murgui, Lucía Piñeiro-López, M. Carmen Muñoz, José Antonio Real|2018|Inorg.Chem.|57|1562|doi:10.1021/acs.inorgchem.7b02906

CCDC 971021: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Maksym Seredyuk, M. Carmen Muñoz, José A. Real|2014|Chem.Commun.|50|1833|doi:10.1039/C3CC48595A

CCDC 1847353: Experimental Crystal Structure Determination

Related Article: Teresa Delgado, Manuel Meneses-Sánchez, Lucía Piñeiro-López, Carlos Bartual-Murgui, M. Carmen Muñoz, José Antonio Real|2018|Chemical Science|9|8446|doi:10.1039/C8SC02677G

CCDC 2010364: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Francisco-Javier Valverde-Muñoz, Elzbieta Trzop, M. Carmen Muñoz, Maksym Seredyuk, Javier Castells-Gil, Iván da Silva, Carlos Martí-Gastaldo, Eric Collet, José Antonio Real|2021|Chemical Science|12|1317|doi:10.1039/D0SC04420B

CCDC 1042611: Experimental Crystal Structure Determination

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

CCDC 1042610: Experimental Crystal Structure Determination

Related Article: Tania Romero-Morcillo, Noelia De la Pinta, Lorena M. Callejo, Lucía Piñeiro-López, M. Carmen Muñoz, Gotzon Madariaga, Sacramento Ferrer, Tomasz Breczewski, Roberto Cortés, José A. Real|2015|Chem.-Eur.J.|21|12112|doi:10.1002/chem.201500310

CCDC 1050037: Experimental Crystal Structure Determination

Related Article: Lucía Piñeiro-López, Zulema Arcís-Castillo, M. Carmen Muñoz, and José A. Real|2014|Cryst.Growth Des.|14|6311|doi:10.1021/cg5010616