0000000001301474

AUTHOR

Alexandre Abhervé

showing 51 related works from this author

A spin-crossover complex based on a 2,6-bis(pyrazol-1-yl)pyridine (1-bpp) ligand functionalized with a carboxylate group

2014

Combining Fe(ii) with the carboxylate-functionalized 2,6-bis(pyrazol-1-yl)pyridine (bppCOOH) ligand results in the spin-crossover compound [Fe(bppCOOH)2](ClO4)2 which shows an abrupt spin transition with a T1/2 of ca. 380 K and a TLIESST of 60 K due to the presence of a hydrogen-bonded linear network of complexes.

010405 organic chemistryStereochemistryLigandSpin transition010402 general chemistry01 natural sciencesMedicinal chemistry3. Good health0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundLinear networkBPP ligandchemistrySpin crossoverGroup (periodic table)PyridineCarboxylateDalton Transactions
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Tuning the nuclearity of iron(iii) polynuclear clusters by using tetradentate Schiff-base ligands

2014

Three novel octanuclear, hexanuclear and tetranuclear complexes of high-spin Fe(III) ions were obtained by the reaction of the N,N′-bis-(1R-imidazol-4-ylmethylene)-ethane-1,2-diamine ligand (R = H, CH3) and its derivatives with Fe(ClO4)3·6H2O and KSCN. The tetradentate Schiff-base ligand acts as a bis(bidentate) chelating bridge between two adjacent high-spin Fe(III) centers. The presence of a methyl group in the imidazolyl substituent, the change of counterions or the replacement of imidazole by pyridine has a drastic effect on the nuclearity of the cluster. The magnetic properties of all compounds exhibit antiferromagnetic interactions via μ-oxo or μ-hydroxo pathways in Fe(III) dimers.

Schiff baseDenticityLigandInorganic chemistrySubstituentGeneral ChemistryCatalysischemistry.chemical_compoundCrystallographychemistryPyridineMaterials ChemistryImidazoleChelationMethyl groupNew J. Chem.
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Nonanuclear Spin-Crossover Complex Containing Iron(II) and Iron(III) Based on a 2,6-Bis(pyrazol-1-yl)pyridine Ligand Functionalized with a Carboxylat…

2016

The synthesis and magnetostructural characterization of [Fe(III)3(μ3-O)(H2O)3[Fe(II)(bppCOOH)(bppCOO)]6](ClO4)13·(CH3)2CO)6·(solvate) (2) are reported. This compound is obtained as a secondary product during synthesis of the mononuclear complex [Fe(II)(bppCOOH)2](ClO4)2 (1). The single-crystal X-ray diffraction structure of 2 shows that it contains the nonanuclear cluster of the formula [Fe(III)3(μ3-O)(H2O)3[Fe(II)(bppCOOH)(bppCOO)]6](13+), which is formed by a central Fe(III)3O core coordinated to six partially deprotonated [Fe(II)(bppCOOH)(bppCOO)](+) complexes. Raman spectroscopy studies on single crystals of 1 and 2 have been performed to elucidate the spin and oxidation states of iron …

010405 organic chemistryStereochemistryTrimer010402 general chemistry01 natural sciences0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundsymbols.namesakeCrystallographyDeprotonationchemistrySpin crossoverCluster (physics)symbolsAntiferromagnetismCarboxylatePhysical and Theoretical ChemistrySpin (physics)Raman spectroscopyInorganic chemistry
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Magnetic Molecular Conductors Based on Bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) and the Tris(chlorocyananilato)ferrate(III) Complex

2019

Electrocrystallization of the bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) organic donor in the presence of the [Fe(ClCNAn)3]3– tris(chlorocyananilato)ferrate(III) paramagnetic anion in different stoichiometric ratios and solvent mixtures afforded two different hybrid systems formulated as [BEDT-TTF]4[Fe(ClCNAn)3]·3H2O (1) and [BEDT-TTF]5[Fe(ClCNAn)3]2·2CH3CN (2) (An = anilato). Compounds 1 and 2 present unusual structures without the typical segregated organic and inorganic layers, where layers of 1 are formed by Λ and Δ enantiomers of the anionic paramagnetic complex together with mixed-valence BEDT-TTF tetramers, while layers of 2 are formed by Λ and Δ enantiomers of the paramagnetic…

Crystal structure010402 general chemistry01 natural sciencesInorganic Chemistrychemistry.chemical_compoundParamagnetismMolecular interactionsMolecule[CHIM.COOR]Chemical Sciences/Coordination chemistryPhysical and Theoretical Chemistry010405 organic chemistry[CHIM.MATE]Chemical Sciences/Material chemistryMolecules3. Good health0104 chemical sciencesSolventCrystallographyMonomerchemistryRadical ionOligomersCrystal structuresSolventsStoichiometryTetrathiafulvaleneInorganic Chemistry
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Iron( ii ) and cobalt( ii ) complexes based on anionic phenanthroline-imidazolate ligands: reversible single-crystal-to-single-crystal transformations

2018

A series of low-spin FeII and CoII complexes based on phenanthroline-imidazolate (PIMP) ligands are reported. The FeII complex (H9O4)[Fe(PIMP)3]·(C4H10O)2(H2O) (1a) shows reversible crystalline phase transformations to afford two new phases (H9O4)[Fe(PIMP)3]·(H2O) (1b) and (H9O4)[Fe(PIMP)3]·(C8H18O)(C4H10O)(H2O) (1c) by release of diethyl ether and absorption of diethyl/dibutyl ether, respectively. This reversible uptake/release of solvent molecules is a clear example of single-crystal-to-single-crystal transformation involving a discrete metal complex. On the other hand, the corresponding CoII complex (H9O4)[Co(PIMP)3]·(C4H10O)2(H2O)2 (2) does not exhibit similar phase transformations. In …

010405 organic chemistryPhenanthrolinechemistry.chemical_elementGeneral Chemistry010402 general chemistryCondensed Matter Physics01 natural sciences3. Good health0104 chemical sciencesSolventDibutyl etherMetalchemistry.chemical_compoundCrystallographyDeprotonationchemistryvisual_artImidazolatevisual_art.visual_art_medium[CHIM]Chemical SciencesGeneral Materials Science[CHIM.COOR]Chemical Sciences/Coordination chemistryDiethyl etherCobaltComputingMilieux_MISCELLANEOUS
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Nanosheets of Two-Dimensional Magnetic and Conducting Fe(II)/Fe(III) Mixed-Valence Metal-Organic Frameworks.

2017

We report the synthesis, magnetic properties, electrical conductivity, and delamination into thin nanosheets of two anilato-based Fe(II)/Fe(III) mixed-valence two-dimensional metal–organic frameworks (MOFs). Compounds [(H3O)(H2O)(phenazine)3][FeIIFeIII(C6O4X2)3]·12H2O [X = Cl (1) and Br (2)] present a honeycomb layered structure with an eclipsed packing that generates hexagonal channels containing the water molecules. Both compounds show ferrimagnetic ordering at ca. 2 K coexisting with electrical conductivity (with room temperature conductivities of 0.03 and 0.003 S/cm). Changing the X group from Cl to Br leads to a decrease in the ordering temperature and room temperature conductivity tha…

Materials scienceValence (chemistry)Inorganic chemistry02 engineering and technologyConductivity010402 general chemistry021001 nanoscience & nanotechnology01 natural sciences0104 chemical sciencesElectronegativityCrystallographyFerrimagnetismElectrical resistivity and conductivityMonolayerMoleculeGeneral Materials ScienceMetal-organic framework0210 nano-technologyACS applied materialsinterfaces
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Bimetallic MnIII–FeII hybrid complexes formed by a functionalized MnIII Anderson polyoxometalate coordinated to FeII: observation of a field-induced …

2015

The synthesis and crystal structure of an Anderson POM functionalized with two 2,6-di(pyrazol-1-yl)-pyridine (1-bpp) ligands are reported (compound 1). High-frequency electron paramagnetic resonance (HF-EPR) and magnetic measurements show that it presents a significant negative axial zero-field splitting and field-induced slow relaxation of magnetization due to the presence of isolated MnIII anisotropic magnetic ions. Complexation of 1 with FeII gives rise to a 2D cationic network formed by Anderson POMs coordinated to two FeII ions through the two tridentate 1-bpp ligands and to other two FeII ions through two oxo ligands in compound 2, and to an anionic polymeric network formed by Anderso…

Materials scienceStereochemistryRelaxation (NMR)General ChemistryCrystal structureLIESSTlaw.inventionCrystallographyMagnetizationlawSpin crossoverPolyoxometalateMaterials ChemistryMoleculeElectron paramagnetic resonanceJournal of Materials Chemistry C
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Spin-crossover compounds based on iron(II) complexes of 2,6-bis(pyrazol-1-yl)pyridine (bpp) functionalized with carboxylic acid and ethyl carboxylic …

2018

International audience; Four new salts of the iron(II) complex of the 2,6-bis(pyrazol-1-yl)pyridine ligand functionalized with a carboxylic acid group (bppCOOH) of formulas [Fe(bppCOOH)2](BF4)2 (1(BF4)2), [Fe(bppCOOH)2](CF3SO3)2·yMe2CO (1(CF3SO3)2·yMe2CO), [Fe(bppCOOH)2](AsF6)2·yMe2CO (1(AsF6)2·yMe2CO) and [Fe(bppCOOH)2](SbF6)2·yMe2CO (1(SbF6)2·yMe2CO) have been prepared and characterized together with a more complete structural and photomagnetic characterization of the previously reported [Fe(bppCOOH)2](ClO4)2 (1(ClO4)2). Furthermore, the iron(II) complex of the ethyl ester derivative of bppCOOH (bppCOOEt) has been prepared and characterized (compound [Fe(bppCOOEt)2](ClO4)2·yMe2CO, 2(ClO4)…

chemistry.chemical_classification010405 organic chemistryLigandCarboxylic acidSpin transition[CHIM.MATE]Chemical Sciences/Material chemistryQuímica010402 general chemistry01 natural sciencesMedicinal chemistryLIESST0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundchemistrySpin crossoverPyridineÀcids carboxílicsCompostos de coordinacióIsostructuralDerivative (chemistry)
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Spin-crossover complex encapsulation within a magnetic metal-organic framework.

2016

The solid-state incorporation of a mononuclear iron(III) complex within the pores of a magnetic 3D metal–organic framework (MOF) in a single crystal to single crystal process leads to the formation of a new hybrid material showing both a guest-dependent long-range magnetic ordering and a spin-crossover (SCO) behaviour.

Materials scienceMetals and AlloysPhysics::OpticsNanotechnology02 engineering and technologyGeneral Chemistry010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesCatalysis0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsEncapsulation (networking)Chemical engineeringSpin crossoverMaterials ChemistryCeramics and CompositesMetal-organic framework0210 nano-technologyHybrid materialSingle crystalChemical communications (Cambridge, England)
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A family of layered chiral porous magnets exhibiting tunable ordering temperatures.

2013

A simple change of the substituents in the bridging ligand allows tuning of the ordering temperatures, Tc, in the new family of layered chiral magnets A[M(II)M(III)(X2An)3]·G (A = [(H3O)(phz)3](+) (phz = phenazine) or NBu4(+); X2An(2-) = C6O4X2(2-) = 2,5-dihydroxy-1,4-benzoquinone derivative dianion, with M(III) = Cr, Fe; M(II) = Mn, Fe, Co, etc.; X = Cl, Br, I, H; G = water or acetone). Depending on the nature of X, an increase in Tc from ca. 5.5 to 6.3, 8.2, and 11.0 K (for X = Cl, Br, I, and H, respectively) is observed in the MnCr derivative. Furthermore, the presence of the chiral cation [(H3O)(phz)3](+), formed by the association of a hydronium ion with three phenazine molecules, lead…

010405 organic chemistryHexagonal crystal systemInorganic chemistryPhenazineBridging ligand010402 general chemistry01 natural sciences3. Good health0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryMagnetAcetone[CHIM]Chemical SciencesMoleculePhysical and Theoretical ChemistryPorosityComputingMilieux_MISCELLANEOUSDerivative (chemistry)Inorganic chemistry
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One-dimensional and two-dimensional anilate-based magnets with inserted spin-crossover complexes.

2014

The syntheses, structures, and magnetic properties of a family of bimetallic anilate-based compounds with inserted spin-crossover cationic complexes are reported. The structures of 1-4 present a two-dimensional anionic network formed by Mn(II) and Cr(III) ions linked through anilate ligands with inserted [Fe(III)(sal2-trien)](+) (1), [Fe(III)(4-OH-sal2-trien)](+) (2), [Fe(III)(sal2-epe)](+) (3), or [Fe(III)(5-Cl-sal2-trien)](+) (4) complexes. The structure of 5 is formed by anionic [Mn(II)Cl2Cr(III)(Cl2An)3](3-) chains surrounded by [Fe(II)(tren(imid)3)](2+), Cl(-), and solvent molecules. The magnetic properties indicate that 1-4 undergo a long-range ferrimagnetic ordering at ca. 10 K. On t…

Inorganic ChemistrySolventCrystallographyChemistryFerrimagnetismStereochemistrySpin crossoverMagnetCationic polymerizationMoleculePhysical and Theoretical ChemistryBimetallic stripIonInorganic chemistry
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Graphene related magnetic materials: micromechanical exfoliation of 2D layered magnets based on bimetallic anilate complexes with inserted [FeIII(aca…

2015

The syntheses, structures and magnetic properties of the coordination compounds of formula [FeIII(acac2-trien)][MnIICrIII(Cl2 An)3]·(CH3CN)2 (1), [FeIII(acac2-trien)][MnIICrIII(Br2An)3]·(CH3CN)2 (2) and [GaIII(acac2-trien)][MnIICrIII(Br2An)3]·(CH3CN)2 (3) are reported. They exhibit a 2D anionic network formed by Mn(II) and Cr(III) ions linked through anilate ligands, while the [FeIII(acac2-trien)]+ or [GaIII(acac2-trien)]+ charge-compensating cations are placed inside the hexagonal channels of the 2D network, instead of being inserted in the interlamellar spacing. Thus, these crystals are formed by hybrid layers assembled through van der Waals interactions. The magnetic properties indicate …

chemistry.chemical_classificationMaterials scienceGrapheneIonic bondingNanotechnologyGeneral ChemistryExfoliation jointCoordination complexlaw.inventionCrystallographysymbols.namesakechemistryFerrimagnetismlawsymbolsMoleculevan der Waals forceBimetallic stripChemical Science
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Hybrid magnetic materials based on coordination chemistry: from switching magnetic molecules to 2D coordination polymers

2015

El trabajo descrito en esta tesis se encuadra en el ámbito de los materiales moleculares. Presenta varias estrategias para preparar nuevos materiales híbridos multifuncionales. Los complejos de transición de espín (SCO) constituyen uno de los ejemplos más espectaculares de biestabilidad molecular. En estos sistemas, las transiciones entre los estados de bajo espín (LS) y alto espín (HS) pueden estar inducidos por una variedad de estímulos externos (temperatura, presión o radiación electromagnética). Además de los interesantes aspectos fundamentales, este fenómeno es de interés creciente en el área de los materiales funcionales debido a las posibles aplicaciones en sensores, memorias o dispo…

coordination polymersspin-crossoverUNESCO::QUÍMICAcoordination chemistrymultifunctional materials:QUÍMICA [UNESCO]
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CCDC 1856807: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

Space GroupCrystallographybis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(hexafluoroarsenate) acetone solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1835925: Experimental Crystal Structure Determination

2018

Related Article: Alexandre Abhervé, Samia Benmansour, Carlos José Gómez-García, Narcis Avarvari|2018|CrystEngComm|20|4141|doi:10.1039/C8CE00561C

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatesoxonium tris(2-phenyl-1H-imidazo[45-f][110]phenanthrolinate)-cobalt(ii) diethyl ether solvate pentahydrate
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CCDC 1470626: Experimental Crystal Structure Determination

2017

Related Article: Samia Benmansour, Alexandre Abhervé, Patricia Gómez-Claramunt, Cristina Vallés-García, Carlos J. Gómez-García|2017|ACS Applied Materials and Interfaces|9|26210|doi:10.1021/acsami.7b08322

Space GroupCrystallographycatena-[oxonium tris(phenazine) tris(mu-25-dibromo-36-dioxocyclohexa-14-diene-14-diolato)-di-iron tridecahydrate]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 953847: Experimental Crystal Structure Determination

2013

Related Article: Matteo Atzori, Samia Benmansour, Guillermo Mínguez Espallargas, Miguel Clemente-León, Alexandre Abhervé, Patricia Gómez-Claramunt, Eugenio Coronado, Flavia Artizzu, Elisa Sessini, Paola Deplano, Angela Serpe, Maria Laura Mercuri, and Carlos J. Gómez García|2013|Inorg.Chem.|52|10031|doi:10.1021/ic4013284

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[oxonium tris(mu~2~-36-dibromo-45-dioxocyclohexa-26-diene-12-diolato)-chromium-manganese phenazine acetone solvate monohydrate]Experimental 3D Coordinates
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CCDC 1856804: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

bis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(tetrafluoroborate)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1856814: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) diperchlorateExperimental 3D Coordinates
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CCDC 1945945: Experimental Crystal Structure Determination

2019

Related Article: Suchithra Ashoka Sahadevan, Alexandre Abhervé, Noemi Monni, Pascale Auban-Senzier, Joan Cano, Francesc Lloret, Miguel Julve, Hengbo Cui, Reizo Kato, Enric Canadell, Maria Laura Mercuri, Narcis Avarvari|2019|Inorg.Chem.|58|15359|doi:10.1021/acs.inorgchem.9b02404

pentakis(bis(ethylenedithio)tetrathiafulvalene radical) bis(tris(chlorocyananilato)-iron(iii)) acetonitrile solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1835922: Experimental Crystal Structure Determination

2018

Related Article: Alexandre Abhervé, Samia Benmansour, Carlos José Gómez-García, Narcis Avarvari|2018|CrystEngComm|20|4141|doi:10.1039/C8CE00561C

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersoxonium tris(2-phenyl-1H-imidazo[45-f][110]phenanthrolinate)-iron(ii) diethyl ether tetrahydrateExperimental 3D Coordinates
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CCDC 1856808: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

bis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(hexafluoroantimonate) acetone solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 973768: Experimental Crystal Structure Determination

2014

Related Article: Alexandre Abhervé, Juan Modesto Clemente-Juan, Miguel Clemente-León, Eugenio Coronado, Jaursup Boonmak, Sujittra Youngme|2014|New J.Chem.|38|2105|doi:10.1039/C3NJ01516E

bis(mu-NN'-ethane-12-diylbis(1-(pyridin-2-yl)methanimine))-tris(mu-hydroxo)-(mu-oxo)-aqua-heptakis(isothiocyanato)-tetra-iron(iii) acetonitrile solvate dihydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1856805: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

bis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(tetrafluoroborate)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1054373: Experimental Crystal Structure Determination

2015

Related Article: Alexandre Abhervé, Samuel Mañas-Valero, Miguel Clemente-León, Eugenio Coronado|2015|Chemical Science|6|4665|doi:10.1039/C5SC00957J

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-((415-Dimethyl-581114-tetra-azaoctadeca-241416-tetraene-217-diolato)-iron(iii) tris(mu2-36-dibromo-25-dioxy-14-benzoquinone)-chromium(iii)-manganese(ii) acetonitrile solvate)Experimental 3D Coordinates
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CCDC 1470627: Experimental Crystal Structure Determination

2017

Related Article: Samia Benmansour, Alexandre Abhervé, Patricia Gómez-Claramunt, Cristina Vallés-García, Carlos J. Gómez-García|2017|ACS Applied Materials and Interfaces|9|26210|doi:10.1021/acsami.7b08322

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[oxonium tris(phenazine) tris(mu-25-dichloro-36-dioxocyclohexa-14-diene-14-diolato)-di-iron tridecahydrate]Experimental 3D Coordinates
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CCDC 1856813: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

Space GroupCrystallographyCrystal Systembis[ethyl 26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylate]-iron(ii) diperchlorate acetone solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1054374: Experimental Crystal Structure Determination

2015

Related Article: Alexandre Abhervé, Samuel Mañas-Valero, Miguel Clemente-León, Eugenio Coronado|2015|Chemical Science|6|4665|doi:10.1039/C5SC00957J

catena-((415-Dimethyl-581114-tetra-azaoctadeca-241416-tetraene-217-diolato)-gallium(iii) tris(mu2-36-dibromo-25-dioxy-14-benzoquinone)-chromium(iii)-manganese(ii) acetonitrile solvate)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 973767: Experimental Crystal Structure Determination

2014

Related Article: Alexandre Abhervé, Juan Modesto Clemente-Juan, Miguel Clemente-León, Eugenio Coronado, Jaursup Boonmak, Sujittra Youngme|2014|New J.Chem.|38|2105|doi:10.1039/C3NJ01516E

hexakis(mu-NN'-ethane-12-diylbis(1-(5-methyl-1H-imidazol-4-yl)methanimine))-tris(mu-oxo)-hexakis(isothiocyanato)-hexa-iron(iii) diperchlorate tetrakis(thiocyanate) diethyl ether methanol solvate hydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1835924: Experimental Crystal Structure Determination

2018

Related Article: Alexandre Abhervé, Samia Benmansour, Carlos José Gómez-García, Narcis Avarvari|2018|CrystEngComm|20|4141|doi:10.1039/C8CE00561C

Space GroupCrystallographyCrystal SystemCrystal Structureoxonium tris(2-phenyl-1H-imidazo[45-f][110]phenanthrolinate)-iron(ii) di-n-butyl ether diethyl ether solvate tetrahydrateCell ParametersExperimental 3D Coordinates
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CCDC 1835923: Experimental Crystal Structure Determination

2018

Related Article: Alexandre Abhervé, Samia Benmansour, Carlos José Gómez-García, Narcis Avarvari|2018|CrystEngComm|20|4141|doi:10.1039/C8CE00561C

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersoxonium tris(2-phenyl-1H-imidazo[45-f][110]phenanthrolinate)-iron(ii) tetrahydrateExperimental 3D Coordinates
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CCDC 1058520: Experimental Crystal Structure Determination

2015

Related Article: Alexandre Abhervé, Mario Palacios-Corella, Juan Modesto Clemente-Juan, Raphael Marx, Petr Neugebauer, Joris van Slageren, Miguel Clemente-León, Eugenio Coronado|2015|J.Mater.Chem.C|3|7936|doi:10.1039/C5TC01089F

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[bis(mu-N-(13-dioxy-2-(oxymethyl)propan-2-yl)-26-di(1H-pyrazol-1-yl)isonicotinamide)-octakis(mu-oxo)-diaqua-bis(NN-dimethylformamide)-decaoxo-di-iron-manganese-hexa-molybdenum hydroxide NN-dimethylformamide solvate monohydrate]Cell ParametersExperimental 3D Coordinates
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CCDC 1856809: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

Space GroupCrystallographyCrystal Systembis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(trifluoromethanesulfonate) acetone solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1486674: Experimental Crystal Structure Determination

2016

Related Article: Alexandre Abhervé, María José Recio-Carretero, Maurici López-Jordà, Juan Modesto Clemente-Juan, Josep Canet-Ferrer, Andrés Cantarero, Miguel Clemente-León, and Eugenio Coronado|2016|Inorg.Chem.|55|9361|doi:10.1021/acs.inorgchem.6b01508

Space GroupCrystallographyhexakis(mu-26-di(1H-pyrazol-1-yl)isonicotinato)-(mu-oxo)-triaqua-hexakis(26-di(1H-pyrazol-1-yl)isonicotinic acid)-hexa-iron(ii)-tri-iron(iii) tridecaperchlorate acetone solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 977453: Experimental Crystal Structure Determination

2014

Related Article: Alexandre Abhervé, Miguel Clemente-León, Eugenio Coronado, Carlos J. Gómez-García, Maurici López-Jordà|2014|Dalton Trans.|43|9406|doi:10.1039/C4DT00327F

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) diperchlorateExperimental 3D Coordinates
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CCDC 1058519: Experimental Crystal Structure Determination

2015

Related Article: Alexandre Abhervé, Mario Palacios-Corella, Juan Modesto Clemente-Juan, Raphael Marx, Petr Neugebauer, Joris van Slageren, Miguel Clemente-León, Eugenio Coronado|2015|J.Mater.Chem.C|3|7936|doi:10.1039/C5TC01089F

Space GroupCrystallographyCrystal Systemtris(tetra-n-butylammonium) bis(mu-N-(13-dioxy-2-(oxymethyl)propan-2-yl)-26-di(1H-pyrazol-1-yl)isonicotinamide)-hexakis(mu-oxo)-dodecaoxo-manganese-hexa-molybdenum NN-dimethylacetamide solvate hydrateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 953846: Experimental Crystal Structure Determination

2013

Related Article: Matteo Atzori, Samia Benmansour, Guillermo Mínguez Espallargas, Miguel Clemente-León, Alexandre Abhervé, Patricia Gómez-Claramunt, Eugenio Coronado, Flavia Artizzu, Elisa Sessini, Paola Deplano, Angela Serpe, Maria Laura Mercuri, and Carlos J. Gómez García|2013|Inorg.Chem.|52|10031|doi:10.1021/ic4013284

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-(Oxonium tris(mu~2~-25-dichloro-36-dioxy-14-benzoquinone)-aqua-chromium-manganese tris(phenazine))Cell ParametersExperimental 3D Coordinates
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CCDC 1856812: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal Systembis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(trifluoromethanesulfonate) acetone solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 973770: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametershexakis(mu-NN'-ethane-12-diylbis(1-(5-methyl-1H-imidazol-4-yl)methanimine))-tris(mu-oxo)-hexakis(isothiocyanato)-hexa-iron(iii) hemikis(hexafluoro-iron(iii)) thiocyanate methanol solvate monohydrateExperimental 3D Coordinates
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CCDC 1835927: Experimental Crystal Structure Determination

2018

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bis{2-[2-(trifluoromethyl)phenyl]-1H-imidazo[45-f][110]phenanthrolinate}-{2-[2-(trifluoromethyl)phenyl]-1H-imidazo[45-f][110]phenanthroline}-cobalt(ii) ethanol solvate dihydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1856811: Experimental Crystal Structure Determination

2018

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bis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(hexafluoroantimonate) acetone solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1054372: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-((415-Dimethyl-581114-tetra-azaoctadeca-241416-tetraene-217-diolato)-iron(iii) tris(mu2-36-dichloro-25-dioxy-14-benzoquinone)-chromium(iii)-manganese(ii) acetonitrile solvate)Experimental 3D Coordinates
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CCDC 973771: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyoctakis(mu-NN'-ethane-12-diylbis(1-(1H-imidazol-4-yl)methanimine))-tetrakis(mu-oxo)-octakis(isothiocyanato)-octa-iron(iii) pentaperchlorate tris(thiocyanate) hexahydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1486675: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyhexakis(mu-26-di(1H-pyrazol-1-yl)isonicotinato)-(mu-oxo)-triaqua-hexakis(26-di(1H-pyrazol-1-yl)isonicotinic acid)-hexa-iron(ii)-tri-iron(iii) tridecaperchlorate acetone solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1856810: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographyCrystal Systembis[ethyl 26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylate]-iron(ii) diperchlorate acetone solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1945944: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographytetrakis(bis(ethylenedithio)tetrathiafulvalene radical) tris(chlorocyananilato)-iron(iii) trihydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1856806: Experimental Crystal Structure Determination

2018

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Space GroupCrystallographybis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(hexafluoroarsenate) acetone solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 953848: Experimental Crystal Structure Determination

2013

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Space GroupCrystallographyCrystal Systemcatena-(Oxonium tris(mu~2~-25-dibromo-36-dioxy-14-benzoquinone)-aqua-di-manganese tris(phenazine) monohydrate)Crystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 973769: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametershexakis(mu-NN'-ethane-12-diylbis(1-(1H-imidazol-4-yl)methanimine))-tris(mu-oxo)-hexakis(isothiocyanato)-hexa-iron(iii) hexanitrate methanol solvate monohydrateExperimental 3D Coordinates
researchProduct

CCDC 1835926: Experimental Crystal Structure Determination

2018

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bis{2-[2-(trifluoromethyl)phenyl]-1H-imidazo[45-f][110]phenanthrolinate}-{2-[2-(trifluoromethyl)phenyl]-1H-imidazo[45-f][110]phenanthroline}-iron(ii) ethanol solvate heptahydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 953849: Experimental Crystal Structure Determination

2013

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