6533b7d2fe1ef96bd125ed80

RESEARCH PRODUCT

Sequestering aromatic molecules with a spin-crossover Fe(II) microporous coordination polymer.

Masashi AraiJosé Antonio RealM. Carmen MuñozSusumu KitagawaAna B. GasparMasaaki OhbaFrancisco J. Muñoz-lara

subject

AnthraceneEthyleneMolecular StructureCoordination polymerPolymersOrganic ChemistryPhenazineInorganic chemistryMolecular ConformationGeneral ChemistryMicroporous materialCrystallography X-RayCatalysischemistry.chemical_compoundMagneticschemistrySpin crossoverPolymer chemistryMoleculeFerrous CompoundsNaphthalene

description

All in a spin: A series of three-dimensional porous coordination polymer {Fe(dpe)[Pt(CN)(4)]}⋅G (dpe = 1,2-di(4-pyridyl)ethylene; G = phenazine, anthracene, or naphthalene) exhibiting spin crossover and host-guest functions is reported. The magnetic properties of the framework are very sensitive to the chemical nature (aromatic or hydroxilic solvents) and the size of the included guest molecules.

yearjournalcountryeditionlanguage
2012-02-04Chemistry (Weinheim an der Bergstrasse, Germany)
10.1002/chem.201200377https://pubmed.ncbi.nlm.nih.gov/22628190