6533b7d4fe1ef96bd12633a8
RESEARCH PRODUCT
Novel Iron(II) Microporous Spin-Crossover Coordination Polymers with Enhanced Pore Size
Vadim KsenofontovAna B. GasparM. Carmen MuñozFrancisco J. Muñoz-laraJosé Antonio Realsubject
Pore sizeModels MolecularPolymersSurface PropertiesInorganic chemistryConductivityInorganic ChemistryCrystalchemistry.chemical_compoundSpin crossoverMemory devicesCrystalMoleculeFerrous CompoundsPhysical and Theoretical ChemistryParticle SizeBenzenechemistry.chemical_classificationConductivityTemperatureMicroporous materialPolymerCrystallographychemistryFISICA APLICADATransitionPorosityFramework materialdescription
In this Communication, we report the synthesis and characterization of novel Hofmann-like spin-crossover porous coordination polymers of composition {Fe(L)[M(CN)4]}·G [L = 1,4-bis(4-pyridylethynyl)- benzene and MII = Ni, Pd, and Pt]. The spin-crossover properties of the framework are closely related to the number and nature of the guest molecules included in the pores.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2012-12-25 |