6533b7d9fe1ef96bd126cc3b

RESEARCH PRODUCT

Green and Direct Synthesis of Benzaldehyde and Benzyl Benzoate in One Pot

Giuseppe AvelloneAntonino ScurriaFrancesco GiordanoValerica PandarusRosaria CiriminnaFrançois BélandValeria La ParolaBabak KarimiMario PagliaroMina Ghahremani

subject

General Chemical EngineeringBenzyl benzoateORMOSILchemistry.chemical_elementGold catalysis010402 general chemistry01 natural sciencesOrmosilOxygenMedicinal chemistryBenzaldehydechemistry.chemical_compoundBenzyl benzoateEnvironmental ChemistryOne pot010405 organic chemistryRenewable Energy Sustainability and the EnvironmentSolagel catalysisGeneral ChemistrySettore CHIM/06 - Chimica OrganicaBenzaldehyde0104 chemical scienceschemistryBenzyl alcoholAerobic oxidationSolâgel catalysis

description

High yields of valued benzaldehyde and benzyl benzoate are obtained in one pot starting from benzyl alcohol using oxygen as only oxidant under mild conditions (2 bar O2, 100 °C) along with an ultralow amount (0.02 mol %) of Au nanoparticles heterogenized over a spherical ORMOSIL mesoporous support. The process is remarkably selective and the catalyst is stable.

yearjournalcountryeditionlanguage
2018-09-10
10.1021/acssuschemeng.8b03893http://www.cnr.it/prodotto/i/393408