6533b7dbfe1ef96bd12713b9

RESEARCH PRODUCT

ZnO/CdTe/CuSCN, a promising heterostructure to act as inorganic eta-solar cell

Stéphane BastideClaude Lévy-clémentB. O'reganA. KattyVicente Muñoz-sanjoséRamón Tena-zaeraRamón Tena-zaera

subject

business.industryChemistryInorganic chemistryMetals and AlloysHeterojunctionSurfaces and InterfacesPhotovoltaic effectSubstrate (electronics)Chemical vapor depositionCadmium telluride photovoltaicsSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialslaw.inventionlawSolar cellMaterials ChemistryOptoelectronicsThin filmbusinessLayer (electronics)

description

Abstract The ZnO/CdTe/CuSCN heterostructure was analyzed as a candidate to act as an inorganic eta -solar cell. A ZnO film consisting of single crystal nanocolumns was electrodeposited on a transparent conducting substrate which acts as n-type material. As absorber material we used CdTe, which was deposited on the ZnO columnar film by Metal Organic Chemical Vapor Deposition. In order to complete the eta -solar cell we deposited a CuSCN layer by chemical solution deposition. A conformal and uniform CdTe coverage of the ZnO columns was achieved, producing a very efficient light trapping effect. The effective absorption (∼87%) and effective reflectance (∼10%) of the complete heterostructure in the 400–800 nm (AM1.5) solar spectrum range are very favorable for the use of this heterostructure in photovoltaic devices. Preliminary current–voltage characterization made on this ZnO/CdTe/CuSCN heterostructure shows rectifying behavior and a photovoltaic effect.

https://doi.org/10.1016/j.tsf.2005.01.010