6533b7dcfe1ef96bd12732d2

RESEARCH PRODUCT

Mit Donorzentren versehener korbförmiger Molekülhohlraum — Darstellung, Struktur, Eigenschaften

Kari RissanenFritz VögtleUte U. WolfJörg Breitenbach

subject

chemistry.chemical_classificationanimal structuresStructure analysisChemistryStereochemistryEtherCrystal structureCondensation reactionSulfonamidebody regionsInorganic Chemistrychemistry.chemical_compoundnervous systemembryonic structuresX-ray crystallographyPyridineMolecule

description

Basket-shaped Molecular Cavity-Containing Donor Centres — Synthesis, Structure, Properties The macrocyclic basket-shaped molecule 2, composed of three 4-donor-substituted pyridine units, is synthesized by cyclisation of the chloromethyl compound 7 with sulfonamide 8. The X-ray structure analysis of 2 gives an impression of the shape of the molecular basket. Furthermore it demonstrates that the toluenesulfonamide residues interlink, creating dimeric units of 2 in the crystal.

https://doi.org/10.1002/cber.19911241027