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RESEARCH PRODUCT
Study of the Fragmentation of D-Glucose and Alkylmonoglycosides in the Presence of Sodium Ions in an Ion-Trap Mass Spectrometer
Miriam Beneito-cambraJosé Manuel Herrero-martínezVirginia Bernabé-zafónGuillermo Ramis-ramossubject
ElectrosprayCollision-induced dissociationChemistryBiochemistry (medical)Clinical BiochemistryAnalytical chemistryMass spectrometryBiochemistryAnalytical ChemistryAdductIonFragmentation (mass spectrometry)ElectrochemistryMoleculelipids (amino acids peptides and proteins)Ion trapSpectroscopydescription
Abstract Using electrospray ion-trap mass spectrometry, the fragmentation of D-glucose and alkylmonoglycopyranosides (alkyl-GPs) was studied. In the presence of Na+, B1 and 0,2A fragmentations were observed. The alkyl-GPs also showed a 2,5Afragmentation. A cluster containing no carbon atoms and adducts of this cluster with neutral molecules were observed. Standards of alkylmonoglycofuranosides (alkyl-GFs) were not available; however, their fragmentation was studied by high-performace liquid chromatography–mass spectrometry (HPLC-MS) and HPLC-MS2 using an industrial mixture of alkylpolyglycosides. The cluster and its adducts were more easily formed by the alkyl-GPs than by the alkyl-GFs, but the 0,2A cross-ring cleavage was more easily produced by the alkyl-GFs.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2009-03-28 | Analytical Letters |