6533b823fe1ef96bd127e151

RESEARCH PRODUCT

Tridentate C–I⋯O−–N+ halogen bonds

J. Mikko RautiainenRakesh PuttreddyKari RissanenHeikki M. TuononenFilip Topić

subject

Halogen bond010405 organic chemistryChemistryhalogen bondschemistry.chemical_elementGeneral Chemistry010402 general chemistryCondensed Matter PhysicsPhotochemistry01 natural sciencesOxygen0104 chemical sciencesPolymer chemistryHalogenGeneral Materials Scienceta116Lone pair

description

The X-ray structures of the first co-crystals where the three oxygen lone pairs in N-oxides are fully utilized for tridentate C–I⋯O−–N+ halogen bonding with 1,ω-diiodoperfluoroalkanes are reported, studied computationally, and compared with the corresponding silver(I) N-oxide complexes.

https://doi.org/10.1039/c7ce01381g