6533b824fe1ef96bd1280854

RESEARCH PRODUCT

Die stufenweise Synthese von 4,11,18,25-Tetra-tert-butyl-[1.1.1.1]metacyclophan-7,14,21,28-tetraol und 4,11-Dimethyl-[1.1.1.1]-metacyclophan-7,14,21,28-tetraol

Hermann KämmererVolker BöhmerGünter HappelDusanka Rathay

subject

Cyclic compoundAcetic acidchemistry.chemical_compoundChemistryOrganic chemistryMoleculeGeneral Chemistry

description

Two phenolic alcohols with four phenolic units in their molecules are obtained by stepwise synthesis starting from simple phenolic derivatives. The phenolic alcohols are cyclized by boiling of a diluted solution in acetic acid. A third cyclic compound is obtained by debutylation of that cyclic compound which contains two neighbouringtert-butyl groups and two methyl groupspara to the phenolic hydroxyl groups.

https://doi.org/10.1007/bf00907297