6533b825fe1ef96bd1281e58
RESEARCH PRODUCT
Formation and mixed-valent behaviour of a substituted tetraferrocenylstannane.
Katja HeinzeChristoph FörsterTeuta GasiDaniel Sieblersubject
Models MolecularMolecular StructureNear-infrared spectroscopyMetals and AlloysAnalytical chemistryIntermetallicchemistry.chemical_elementTin CompoundsGeneral ChemistryNuclear magnetic resonance spectroscopyCrystallography X-RayCopperCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographyParamagnetismchemistryMixed valentMaterials ChemistryCeramics and CompositesMoleculeFerrous CompoundsSpectroscopydescription
A tetrasubstituted tetraferrocenylstannane is formed from 1-bromoferrocene-1′-carboxylic acid methyl ester and copper bronze. The molecular structure is almost perfectly tetrahedral with Fe⋯Fe distances of around 6 A. In solution two sequential one-electron processes and one two-electron process are indicative of mixed-valent intermediates. Intermetallic interactions have been probed by preparative oxidation, paramagnetic NMR spectroscopy, Mosbauer spectroscopy, UV/Vis/NIR spectroscopy and DFT calculations.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2010-04-22 | Chemical communications (Cambridge, England) |