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RESEARCH PRODUCT
Non-hindered ansasamarocenes, versatile catalysts for diene/olefin/polar monomer copolymerisations. What is really the active species?
Alain DormondMarc VisseauxBruno DomenichiniDenise Barbier-baudryFanny Bonnetsubject
Olefin fiberDieneOrganic Chemistrychemistry.chemical_elementBiochemistryChlorideCatalysisInorganic Chemistrychemistry.chemical_compoundMonomerchemistryPolymerizationPolycaprolactoneMaterials ChemistrymedicineOrganic chemistryLithiumPhysical and Theoretical Chemistrymedicine.drugdescription
Abstract Catalytic systems containing an ansabiscyclopentadienyllanthanide core and lithium and/or magnesium salts are obtained by reaction of the chloride precursors with allyllithium. These allyl complexes lead to the same active species which polymerises 1,3-dienes, copolymerises 1,3-dienes and α-olefin or α,ω-dienes or allows the controlled diblock polyisoprene/polycaprolactone copolymerisation. The exact nature of this active species and of the allyl precursors is investigated here.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2002-03-01 | Journal of Organometallic Chemistry |