6533b82cfe1ef96bd1290096

RESEARCH PRODUCT

A novel two-dimensional honeycomb-like bimetallic iron(iii)–nickel(ii) cyanide-bridged magnetic material [Ni(cyclam)]3[Fe(CN)6]2·nH2O (cyclam = 1,4,8,11-tetraazacyclodecane)

Mustapha GhaziFrancesc LloretJosé M. Domínguez-veraJosé M. MorenoHelen Stoeckli-evansRaikko KivekäsEnrique Colacio

subject

Materials scienceCyanideUNESCO::QUÍMICAchemistry.chemical_elementHoneycomb like:QUÍMICA [UNESCO]Catalysischemistry.chemical_compoundCyclamMagnetic propertiesMaterials ChemistryAntiferromagnetismBimetallic stripHoneycomb-likeUNESCO::QUÍMICA::Química inorgánicaMetallurgyMetals and AlloysHoneycomb-like ; Bimetallic Iron ; Ferromagnetic ; Magnetic propertiesGeneral Chemistry:QUÍMICA::Química inorgánica [UNESCO]Surfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographyNickelchemistryFerromagnetismMagnetFerromagneticBimetallic IronCeramics and Composites

description

The 2D honeycomb-like layered iron(iii)–nickel(ii) cyanidebridged complex [Ni(cyclam)]3[Fe(CN)6]2·nH2O exhibits ferromagnetic intralayer and antiferromagnetic interlayer interactions; above 3 K the magnetic properties are typical of a metamagnet with Hc = 5000 G, whereas below 3 K a canted structure is formed, leading to a long range ferromagnetic ordering. Lloret Pastor, Francisco, Francisco.Lloret@uv.es

yearjournalcountryeditionlanguage
1999-01-01
http://hdl.handle.net/10550/16758