6533b82dfe1ef96bd12907c7

RESEARCH PRODUCT

Networks based on hydrogen-bonds containing phosphorus anions and tris(3,5-dimethylpyrazolyl)borate nickel(II) moieties

José PérezM. Dolores SantanaMalva LiuLuis GarcíaLuisa López-banetGabriel GarcíaLuis Lezama

subject

Hydrogen bondInorganic chemistrySupramolecular chemistrychemistry.chemical_elementNuclear magnetic resonance spectroscopyPhosphinatePhosphonateInorganic Chemistrychemistry.chemical_compoundNickelMonomerchemistryPolymer chemistryMaterials ChemistryMoleculePhysical and Theoretical Chemistry

description

Abstract Five structural kinds of nickel hydrogen-bonded networks containing hydrotris(3,5-dimethylpyrazolyl)borate ligands (Tp∗) have been elucidated by X-ray diffraction, [Tp∗Ni(OH2)3][(p-NO2C6H4O)2PO2] (4), [Tp∗Ni(OH2)3][Me2PO2]·Me2P(O)OH (5), [Tp∗Ni(OH2)3][(nBuO)2PO2]·0.5H2O (6), [(Hpz)Tp∗Ni(OH2)2][(Ph)PO2OH] (7) and [Tp∗Ni(OH2)2(Me2PO2)] (8). The most relevant supramolecular feature of complexes 4–8 is all of them form coordination networks based on hydrogen bonds between water molecules and phosphate, phosphonate or phosphinate anions. These hydrogen bonds are formed within the monomer units in addition to connect monomers along the chains. Their behaviors in solution were investigated by one- and two-dimensional 1H NMR techniques.

yearjournalcountryeditionlanguage
2012-01-01Polyhedron
https://doi.org/10.1016/j.poly.2011.10.014