6533b82efe1ef96bd12933d3

RESEARCH PRODUCT

Measurement of the Md3+/Md2+ Reduction Potential Studied with Flow Electrolytic Chromatography

Takahiro KikuchiKazuaki TsukadaTetsuya SatoHiromitsu HabaYoshitaka KasamatsuJulia EvenNozomi SatoYuichiro NagameAtsushi ToyoshimaYoshihiro KitatsujiMasato AsaiZijie LiMatthias SchädelAtsushi ShinoharaY. KaneyaKazuhiro OoeKazuhiro Ooe

subject

ChromatographyStandard hydrogen electrodeFlow (psychology)Analytical chemistrychemistry.chemical_elementElectrolyteIonMendeleviumInorganic ChemistryReduction (complexity)chemistryPhysical and Theoretical ChemistryLuminescenceChromatography column

description

The reduction behavior of mendelevium (Md) was studied using a flow electrolytic chromatography apparatus. By application of the appropriate potentials on the chromatography column, the more stable Md(3+) is reduced to Md(2+). The reduction potential of the Md(3+) + e(-) → Md(2+) couple was determined to be -0.16 ± 0.05 V versus a normal hydrogen electrode.

https://doi.org/10.1021/ic401571h