6533b831fe1ef96bd1299048
RESEARCH PRODUCT
A post-synthetic approach triggers selective and reversible sulphur dioxide adsorption on a metal-organic framework.
Rodrigo Gil San MillánMarta MonEstefanía TiburcioJorge A. R. NavarroJesús Ferrando-soriaEmilio PardoDonatella Armentanosubject
Metals and AlloysSupramolecular chemistrychemistry.chemical_elementBarium02 engineering and technologyGeneral Chemistry010402 general chemistry021001 nanoscience & nanotechnologycomplex mixtures01 natural sciencesSulfurCatalysis0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsAdsorptionchemistryChemical engineeringScientific methodMaterials ChemistryCeramics and CompositesMolecule0210 nano-technologydescription
We report the application of a post-synthetic solid-state cation-exchange process to afford a novel 3D MOF with hydrated barium cations hosted at pores able to trigger selective and reversible SO2 adsorption. Computational modelling supports the full reversibility of the adsorption process on the basis of weak supramolecular interactions between SO2 and coordinated water molecules.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2018-07-28 | Chemical communications (Cambridge, England) |