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RESEARCH PRODUCT

Layered-Expanded Mesostructured Silicas: Generalized Synthesis and Functionalization

Lorenzo FernándezPedro AmorósAurelio BeltránCarmen GuillemJulio LatorreFrancisco Pérez-plaDaniel BeltránPedro BurgueteAna CrosJamal El HaskouriJosé Manuel Morales

subject

Materials scienceamorphous silicaGeneral Chemical Engineering02 engineering and technology010402 general chemistry01 natural sciencesArticlelcsh:Chemistrychemistry.chemical_compoundColloidGeneral Materials ScienceLamellar structure021001 nanoscience & nanotechnology0104 chemical sciencesTemplatelayered materialslcsh:QD1-999AtranechemistryChemical engineeringfunctionalizationSurface modificationdispersionAmorphous silica0210 nano-technologyDispersion (chemistry)

description

Mesostructured layered silicas have been prepared through a surfactant-assisted procedure using neutral alkylamines as templates and starting from atrane complexes as hydrolytic inorganic precursors. By adjusting the synthetic parameters, this kinetically controlled reproducible one-pot method allows for obtaining both pure and functionalized (inorganic or organically) lamellar silica frameworks. These are easily deconstructed and built up again, which provides a simple way for expanding the interlamellar space. The materials present high dispersibility, which results in stable colloidal suspensions.

https://doi.org/10.3390/nano8100817