Phosphororganische Verbindungen, XXIX. Metallverbindungen sekundärer Phosphinoxyde und einige Umsetzungen

6533b835fe1ef96bd129e962

RESEARCH PRODUCT

Phosphororganische Verbindungen, XXIX. Metallverbindungen sekundärer Phosphinoxyde und einige Umsetzungen

Leopold Horner Vicente G. Toscano Peter Beck

subject

Inorganic Chemistry Chemistry Medicinal chemistry

description

Metallverbindungen sekundarer Phosphinoxyde entstehen 1. durch Spaltung von tertiaren Phosphinoxyden mit Natriumhydrid, 2. durch Reduktion von Phosphinylchloriden mit Natrium bzw. Magnesium, 3. durch Autoxydation von z. B. Diphenyl-[α-hydroxy-benzyl]-phosphin zum entsprechenden Phosphinoxyd. Letzteres steht als Alkaliverbindung mit der Diphenylphosphinoxydalkali-Verbindung und Benzaldehyd im Gleichgewicht. – Die Alkaliverbindungen sekundarer Phosphinoxyde liefern mit Alkylogeniden tertiare Phosphinoxyde.

year	journal	country	edition	language
1961-05-01	Chemische Berichte

https://doi.org/10.1002/cber.19610940522

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