6533b857fe1ef96bd12b3a16

RESEARCH PRODUCT

Is the special pair structure a good strategy for the kinetics during the last step of the energy transfer with the nearest antenna? A chemical model approach.

Shawkat M. AlyPierre D. HarveyPierre D. HarveyAdam LangloisJean-michel CamusRoger Guilard

subject

Molecular StructureMetalloporphyrinsEnergy transferKineticsMetals and AlloysStructure (category theory)General ChemistryPorphyrinMolecular physicsCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsBase (group theory)chemistry.chemical_compoundKineticsZincchemistryEnergy TransferModels ChemicalComputational chemistryMaterials ChemistryCeramics and CompositesMoleculeMagnesiumAntenna (radio)

description

A cofacial bis(Mg(II)porphyrin)-C(6)H(4)-free base ([Mg(2)]-bridge-FB) dyad shows S(1) energy transfer in both directions and much slower rates than similar monoporphyrin systems are observed.

10.1039/c3cc38740bhttps://pubmed.ncbi.nlm.nih.gov/23396549