6533b857fe1ef96bd12b44d8
RESEARCH PRODUCT
From six-coordinate to eight-coordinate iron(ii) complexes with pyridyltriazolo-pyridine frameworks
Rafael BallesterosRafael Ballesteros-garridoBelén AbarcaJosé Antonio RealSacramento FerrerM. Carmen MuñozRosa Adamsubject
010405 organic chemistryLigandChemistryStereochemistryGeneral Chemistry010402 general chemistryCondensed Matter Physics01 natural sciencesMedicinal chemistry0104 chemical scienceschemistry.chemical_compoundFISICA APLICADAPyridineGeneral Materials ScienceTriazolopyridinedescription
A new octacoordinated Fe(II) compound, [FeII(LN4)2](BPh4)2·3CH2Cl2, as an example of the scarce FeN8 systems, has been isolated with a tetradentate triazolopyridine-based ligand from a solution containing the related hexacoordinated [FeII(LN3)2]2+ complex, with LN3 = pyridyltriazolo-pyridyl-bromopyrimidine and LN4 = bis(pyridyltriazolo-pyridine).
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2016-01-01 | CrystEngComm |