6533b862fe1ef96bd12c622d

RESEARCH PRODUCT

Perovskite Solar Cells: Stable under Space Conditions

Ferdinand C. GrozemaMaría C. Gélvez-ruedaTom J. SavenijeChris DreessenDaniel Pérez-del-reyClaus G. ZimmermannLennart Van Den HengelHenk J. BolinkAna M. Igual-muñoz

subject

Espai exteriorMaterials scienceCondensed matter physicsEnergy Engineering and Power Technology02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnologySpace (mathematics)01 natural sciences7. Clean energyAtomic and Molecular Physics and Optics0104 chemical sciencesElectronic Optical and Magnetic Materials13. Climate actionElectrical and Electronic Engineering0210 nano-technologyCèl·lules fotoelèctriquesPerovskite (structure)

description

Metal halide perovskite solar cells (PSCs) are of interest for high altitude and space applications due to their lightweight and versatile form factor. However, their resilience toward the particle spectrum encountered in space is still of concern. For space cells, the effect of these particles is condensed into an equivalent 1 MeV electron fluence. The effect of high doses of 1 MeV e-beam radiation up to an accumulated fluence to 10^16 e-cm-2 on methylammonium lead iodide perovskite thin films and solar cells is probed. By using substrate and encapsulation materials that are stable under the high energy e-beam radiation, its net effect on the perovskite film and solar cells can be studied. The quartz substrate-based PSCs are stable under the high doses of 1 MeV e-beam irradiation. Time-resolved microwave conductivity analysis on pristine and irradiated films indicates that there is a small reduction in the charge carrier diffusion length upon irradiation. Nevertheless, this diffusion length remains larger than the perovskite film thickness used in the solar cells, even for the highest accumulated fluence of 10^16 e-cm-2. This demonstrates that PSCs are promising candidates for space applications.

https://doi.org/10.1002/solr.202000447