6533b86efe1ef96bd12cac0f
RESEARCH PRODUCT
NI halogen bonding supported stabilization of a discrete pseudo-linear [I12]2− polyiodide
Manu LahtinenHeikki RintaAnssi Peuronensubject
Halogen bondInorganic chemistryGeneral ChemistryDABCOCondensed Matter Physicschemistry.chemical_compoundPolyiodideTemplatechemistryhalogen bondingDiaminePolymer chemistryGeneral Materials Scienceta116description
Two different dicationic N-donors, based on the DABCO diamine, have been studied as templates for polyiodides. The results present a new strategy for polyiodide stabilization, which involves both N⋯I halogen bonding and cation–anion interactions. This is highlighted by the self-assembly of an unprecedented discrete pseudo-linear dodecaiodide species.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2015-01-01 | CrystEngComm |