6533b870fe1ef96bd12cf3e7

RESEARCH PRODUCT

Energy transfer in diiodoBodipy-grafted upconversion nanohybrids.

María González-béjarJulia Pérez-prietoAgnieszka KowalczykArtur BednarkiewiczLaura Francés-sorianoMarta Liras

subject

education.field_of_studyPhotonMaterials scienceEnergy transferPopulationPhysics::OpticsNanotechnologyAstrophysics::Cosmology and Extragalactic Astrophysics02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnologyPhotochemistry01 natural sciencesPhoton upconversion0104 chemical scienceschemistry.chemical_compoundchemistryExcited stateMetastabilityGeneral Materials ScienceBODIPY0210 nano-technologyAbsorption (electromagnetic radiation)educationAstrophysics::Galaxy Astrophysics

description

Steady-state and time-resolved emission studies on nanohybrids consisting of NaYF4:Yb,Er and a diiodo-substituted Bodipy (UCNP-IBDP) show that the Yb(3+) metastable state, formed after absorption of a near-infrared (NIR) photon, can decay via two competitive energy transfer processes: sensitization of IBDP after absorption of a second NIR photon and population of Er(3+) excited states.

10.1039/c5nr07229hhttps://pubmed.ncbi.nlm.nih.gov/26645906