6533b873fe1ef96bd12d4de9

RESEARCH PRODUCT

A novel dimer of oxo-di(acetato)-bridged manganese(III) dimers complex of potential biological significance

Claudio SangregorioAndrea CaneschiRafael RuizM. Carmen MuñozPatrizia RossiJosé Antonio RealAna B. Gaspar

subject

ManganeseAqueous solutionStereochemistryCarboxylato complexesDimerchemistry.chemical_elementCrystal structureManganeseInorganic Chemistrychemistry.chemical_compoundAcetic acidN ligandsO ligandschemistryBiological significanceFISICA APLICADACrystal structuresMaterials ChemistryPhysical and Theoretical ChemistryCluster compounds

description

[EN] Assembly of the tetranuclear oxomanganese(III) acetato cluster [Mn4O2(O2CMe)(7)(phen)(2)](BF4) from the dinuclear oxo-di(acetato)bridged manganese(III) species [Mn2O(O2CMe)(2)(H2O)(2)(phen)(2)](BF4)(2) . 3H(2)O in aqueous/acetic acid MeOH solution occurs via the new 'dimer of dimers' Mn-III complex [Mn2O(O2CMe)(3)(H2O)(phen)(2)](BF4) . MeOH possesing an unprecedent [Mn-4(mu-O)(2)(mu-O2Me)(4) (mu-(OH2O2CMe)-O-...)(2)] core.

yearjournalcountryeditionlanguage
2000-07-01
10.1016/s1387-7003(00)00099-xhttps://dx.doi.org/10.1016/S1387-7003(00)00099-X