Search results for " COMPOSITES"
showing 10 items of 1620 documents
From fracture to damage mechanics: a behavior law for microcracked composites using the concept of crack opening mode
2010
International audience; Many studies have been carried out in order to build a coherent macroscopic behavior law for a composite containing microcracks. All of them are only partially coherent and none of them is complete. This study proposes a hyperelastic behavior law for a microcracked composite, respecting all the conditions associated with the damage activation/deactivation, stress/strain relation continuity, induced anisotropy and the Clausius–Duhem inequality. This approach is based on the definition of the Crack Opening Mode for Damage Mechanics as it exists in Fracture Mechanics.
Electrospun PCL/GO-g-PEG structures: Processing-morphology-properties relationships
2017
Abstract Polycaprolactone (PCL) biocomposite nanofiber scaffolds with different concentrations of graphene oxide (GO) and GO surface grafted with poly(ethylene glycol) (GO-g-PEG) were prepared by electrospinning. Morphological, mechanical as well as wettability characterizations of electrospun nanofibers were carried out. Results showed that the average diameter of PLA/GO electrospun nanofibers decreased upon increasing the filler content. Differently, the diameter increased while using GO-g-PEG. Both nanofillers enhanced the electrospun PCL hydrophilicity even if PCL/GO-g-PEG samples exhibited improved wettability. The Young moduli of the composite nanofiber mats were improved by adding GO…
Mechanical behavior of polylactic acid/polycaprolactone porous layered functional composites
2016
Abstract Biopolymeric porous devices exhibiting graded properties can play a crucial role in several fields, such as tissue engineering or controlled drugs release. In this context, the gradient of a specific property can be achieved by developing porous laminates composed by different types of materials. This work presents for the first time a multi-phasic porous laminate based on polycaprolactone (PCL) and polylactic acid (PLA) prepared by combining melt mixing, compression molding and particle leaching. All the materials were characterized from a morphological and a mechanical point of view. The results put into evidence the possibility to tune and to predict the mechanical properties by…
Scaffolds based on hyaluronan crosslinked with a polyaminoacid: Novel candidates for tissue engineering application
2008
New porous scaffolds, with a suitable hydrolytic and enzymatic degradation, useful for tissue engineering applications have been obtained by a carbodiimide mediated reaction between hyaluronan (HA) and a synthetic polymer with a polyaminoacid structure such as α,β-polyaspartylhydrazide (PAHy). Scaffolds with a different molar ratio between PAHy repeating units and HA repeating units have been prepared and characterized from a chemical and physicochemical point of view. Tests of indirect and direct cytotoxicity, cell adhesion, and spreading on these biomaterials have been performed by using murine L929 fibroblasts. The new biomaterials showed a good cell compatibility and ability to allow ce…
Numerical simulations of the mechanical characteristics of glass fibre reinforced C-profiles
2006
A mechanical characterisation analysis on pultruded glass fibre reinforced C-shaped profiles, developed as modular construction elements to assemble fastening systems, such as doors, window frames and shutters is presented. The key idea is to perform the analysis, and all the related identification procedures of the material parameters, via a coupled approach, based on a limited number of standard laboratory tests and on the numerical finite element simulations of the same tests. The proposed approach allows one to identify all those material parameters which are difficult to detect, by means of simple laboratory experiments on specimens that are extracted from commercial products. It also …
Bubble formation and motion in non-crimp fabrics with perturbed bundle geometry
2010
The behaviour of the fluid front during impregnation of non-crimp fabrics has been considered. Particular attention is paid to creation of bubbles at the fluid front and a virtual 3D model mimickin ...
Self-organization of porphyrin units induced by magnetic field during sol-gel polymerization
2007
The use of a magnetic field as a controlling factor during the hydrolysis-polycondensation of porphyrin precursors substituted by Si(OR)(3) groups, induces a self-organization of porphyrin moieties due to the stacking of these units in the hybrid material and this study also confirms the effect of the magnetic field in the nano- and micrometric organization during the kinetically controlled polycondensation process.
Excitons in SiO2: a review
1992
Abstract In this paper, excitonic properties of crystalline and glassy SiO 2 are reviewed. Experimental spectroscopic data (optical absorption and reflection spectra, as well as spectra of luminescence and its excitation), luminescence decay kinetics at different temperatures, and photoelectric properties — photoconductivity and photoelectron emission — were used to determine excitons in SiO 2 . Information on migration of excitons was obtained on the basis of energy transport to impurity luminescence centers, the latter being detectors of quasiparticles. Determination of excitonic properties in glassy SiO 2 was based on the comparison of the observed phenomena in crystalline and glassy mat…
Photo-induced magnetic bistability in a controlled assembly of anisotropic coordination nanoparticles.
2011
International audience; Anisotropic coordination nanoparticles of the photomagnetic network Cs(I)(2)Cu(II)(7)[Mo(IV)(CN)(8)](4) are obtained through a surfactant-free high-yield synthetic procedure in water. These particles are organised as Langmuir-Blodgett films with a preferential orientation of the nano-objects within the film that exhibit a magnetic bistability below 20 K with a very large coercivity due to an efficient photo-transformation.
Description of Relaxor State in Na1/2Bi1/2TiO3-SrTiO3-PbTiO3 System of Solid Solutions
2011
Vogel-Fulcher law, traditionally applied to describe dispersion of dielectric permittivity in relaxor ferroelectrics, requires introduction of two different relaxation mechanisms above and below freezing temperature correspondingly. Extending distribution function of relaxation times, previously known for low-temperature region, allows creating common description of relaxation in all range, where distribution function of relaxation times can be regarded as wide, without freezing at certain temperature.