Search results for " COMPOSITES"
showing 10 items of 1620 documents
Numerical model of macro-segregation during directional crystallization process
1998
Abstract In the paper the mathematical model of macro-segregation proceeding during the directional crystallization process is presented. The boundary-initial problem considered is discussed. Next the numerical approximation constructed on the basis of the boundary element method supplemented by a procedure called the artificial heat source method is described. The boundary condition on the solidification front resulting from the alloy component balance is introduced, while in finally the practical aspects of computations concerning the course of the process are discussed.
Anisotropy and symmetry for elastic properties of laminates reinforced by balanced fabrics
2001
In this article, we present a theoretical study on elastic properties of laminates composed by balanced fabric layers. Using the polar representation method for plane elastic tensors, we first describe some properties of symmetry of a general laminate composed by balanced fabrics and we write the formulas expressing positions of its axes of symmetry. Then, limiting our study to laminates composed of identical plies, we solve two problems of symmetry of the laminate elastic tensors: uncoupling and quasi-homogeneity. We found all the solutions of the uncoupling problem for the case of 3-, 4- and 5-ply laminate and all those of the quasi-homogeneity problem for the case of 4-, 5- and 6-ply lam…
A finite element formulation for large deflection of multilayered magneto-electro-elastic plates
2014
An original finite element formulation for the analysis of large deflections in magneto-electro-elastic multilayered plates is presented. The formulation is based on an equivalent single-layer model in which first order shear deformation theory with von Karman strains and quasi-static behavior for the electric and magnetic fields are assumed. To obtain the plate model, the electro-magnetic state is firstly determined and condensed to the mechanical primary variables, namely the generalized displacements. In turn, this result is used to obtain laminate effective stiffness coefficients that allow to express the plate mechanical stress resultants in terms of the generalized displacements and a…
A non-linear Ritz method for progressive failure analysis of variable angle tow composite laminates
2022
A Ritz formulation for non-linear analysis of damage initiation and evolution in variable angle tow composite plates under progressive loading is presented. The model is built on a few key items. It assumes first order shear deformation theory kinematics and non-liner strains in the von Karman sense. The constitutive relationships are formulated in the framework of continuum damage mechanics at the ply level, so that each laminate layer can experience in-plane damage initiation and evolution, then reflected in material softening and loss of local stiffness. A Ritz polynomial expansion of the primary variables and the minimization of the total potential energy provide the discrete solution e…
First lamina hybridization of high performance CFRP with Kevlar fibers: Effect on impact behavior and nondestructive evaluation
2022
The impact behavior of a carbon-Kevlar hybrid composite, widely used in sport car manufacturing, was evaluated. To highlight the hybridization effect, comparative analyses were performed with the basic CFRP laminate having the same lay-up. Tensile, bending and low velocity impact tests, followed by nondestructive inspections, highlighted that Kevlar first lamina hybridization leads to an increment in specific impact strength, up to 55%. To assess the most reliable technique to detect the impact damage, nondestructive evaluation was performed by pulsed thermography, phased array ultrasonic technique, computed tomography and digital radiography. Phased array ultrasonic technique can be consid…
Facile formation of a meso–meso linked porphyrin dimer catalyzed by a manganese(iv)–oxo porphyrin
2011
A manganese(IV)-oxo porphyrin catalyzes C-C bond formation between zinc porphyrins at the meso-position with a two-electron oxidant to afford the meso-meso linked porphyrin dimer efficiently. The meso-meso linked dimer is formed via formation of the porphyrin radical cation, and the rate-determining step in the catalytic cycle is the formation of a manganese(IV)-oxo porphyrin with a two-electron oxidant.
Template-controlled synthesis of chiral cyclohexylhemicucurbit[8]uril
2015
Enantiomerically pure cyclohexylhemicucurbit[8]uril (cycHC[8]), possessing a barrel-shaped cavity, has been prepared in high yield on a gram scale from either (R,R,N,N')-cyclohex-1,2-diylurea and formaldehyde or cycHC[6]. In either case, a dynamic covalent library is first generated from which the desired cycHC can be amplified using a suitable anion template.
Synthesis of huge macrocycles using two calix[4]arenes as templates.
2005
Macrocycles with up to 100 atoms have been synthesised using two calix[4]arenes as templates: first, (3,5-dialkenyloxy)phenyl groups are attached to the wide rim of a calix[4]arene via urea links, then the alkenyl groups are connected via a metathesis reaction using a tetratosylurea calix[4]arene for their correct prearrangement and finally the urea functions are cleaved to detach the newly formed macrocycles.
Gold(ii) in redox-switchable gold(i) catalysis
2019
Chemical communications 55(32), 4615 - 4618 (2019). doi:10.1039/C9CC00283A
A post-synthetic approach triggers selective and reversible sulphur dioxide adsorption on a metal-organic framework.
2018
We report the application of a post-synthetic solid-state cation-exchange process to afford a novel 3D MOF with hydrated barium cations hosted at pores able to trigger selective and reversible SO2 adsorption. Computational modelling supports the full reversibility of the adsorption process on the basis of weak supramolecular interactions between SO2 and coordinated water molecules.