Search results for " Circular"
showing 10 items of 253 documents
Epitaxial films of the magnetic shape memory material
2007
Abstract By DC-sputtering from a stoichiometric target onto sapphire substrates we prepared epitaxial films of Ni 2 MnGa . X-ray diffraction in two circle geometry shows only the Ni 2 MnGa peaks corresponding to a (1 1 0) oriented growth on the (1 1 0) oriented sapphire substrate. Rocking curve scans shows that the out of plane orientation has a width of only 1 . 1 ∘ . By four circle X-ray diffraction we find an in-plane aligned growth. The Curie temperature as determined by SQUID magnetometry is 368 K. On cooling down the low field magnetization drops at around 260–280 K indicating the austenite to martensite transition. The presence of two different phases at high and low temperature also…
Epitaxial film growth and magnetic properties ofCo2FeSi
2006
We have grown thin films of the Heusler compound ${\mathrm{Co}}_{2}\mathrm{Fe}\mathrm{Si}$ by RF magnetron sputtering. On (100)-oriented MgO substrates we find fully epitaxial (100)-oriented and $L{2}_{1}$ ordered growth. On ${\mathrm{Al}}_{2}{\mathrm{O}}_{3}(11\overline{2}0)$ substrates, the film growth is (110)-oriented, and several in-plane epitaxial domains are observed. The temperature dependence of the electrical resistivity shows a power law with an exponent of $7∕2$ at low temperatures. Investigation of the bulk magnetic properties reveals an extrapolated saturation magnetization of $5.0{\ensuremath{\mu}}_{B}∕\mathrm{f.u.}$ at $0\phantom{\rule{0.3em}{0ex}}\mathrm{K}$. The films on $…
Solvent-induced high-spin transition in double-decker 3d–4f metallacrowns
2019
Element-specific magnetic spin and orbital magnetic moments of $3d\text{\ensuremath{-}}4f$ double-decker metallacrown molecules have been investigated using x-ray magnetic circular dichroism. The double-decker metallacrowns comprise one rare-earth Gd(III) or Tb(III) ion embedded between two squared scaffolds of four Ni(II) ions. We observe a strong increase of the Ni(II) moments if the molecules are dissolved in methanol, indicating a spin crossover from a low-spin to a high-spin state. In contrast, dichloromethane does not change the spin state. This result is explained by a change of the coordination environment of nickel. The comparison of charge-transfer multiplet calculations with the …
Time-resolved photoemission electron microscopy
2009
The excellent time structure of Synchrotron radiation and short-pulse lasers has opened the door to a novel way of time-resolved imaging using PEEM. Periodic or repetitive processes can be studied by stroboscopic illumination with the pulsed photon beam. Since the first experiments in 2003, two fields of applications have been established in several groups. One concerns the investigation of fast magnetisation processes like precessional switching, Gigahertz-eigenmodes of ferromagnetic nanostructures or travelling spin waves in thin films. More recently, femtosecond lasers have been used for imaging of localised surface plasmons in nanoparticles and their temporal behaviour in the femtosecon…
Study of the implementation of SPIF as a Reshaping strategy in terms of formability and accuracy performance
2022
The adaption of circular economy strategies has become increasingly necessary in current times. Researches need to be addressed on finding alternative processes or the modification of the existing processes in order to reprocess End-of-Life (EoL) components and consequently recover both materials and their functions. This research paper focuses on the use of single point incremental forming (SPIF) process for the Reshaping of sheet metal EoL components. Uniaxial and biaxial pre-straining was performed on AA5754 sheets to imitate an end-of-life component, and SPIF operations were carried out so as to obtain reshaped components. In previous works, the authors have proven the technical feasibi…
Biowaste in a circular bioeconomy in Mediterranean area: A case study of compost and vermicompost as growing substrates alternative to peat
2020
European policies are advocating a transition toward circular bio-economy, an economy aiming at reducing the dependence from fossil-based resources, limiting greenhouse gas emissions and environmental impacts. The aim of this paper is to assess the potential for circularity for bio-waste and related by-products, to highlight the role of compost and vermicompost in the circular bioeconomy and their use in the agricultural sector. Three different substrates were tested in the soilless cultivation of Salvia officinalis, a Mediterranean nutraceutical and healthy plant: vermicompost (40%), compost (40%) and peat (100%). The average values of the main biometric parameters were calculated and comp…
Evaluation of the Purity of Magnesium Hydroxide Recovered from Saltwork Bitterns
2022
Magnesium has been listed among the 30 critical raw materials by the European Union. In recent years, many green and sustainable alternative Mg2+ sources have been sought to satisfy the EU’s demand and to avoid mineral ore consumption. In this context, saltwork bitterns, the by-products of solar sea salt production, have attracted much attention thanks to their high Mg2+ concentrations (up to 80 g/L) and low Ca2+ and bicarbonate contents (<0.5 g/L). Although investigations on Mg2+ extraction from bitterns in the form of Mg(OH)2(s) have already been performed, product purity has never been properly addressed. Mg(OH)2(s) is a chemical compound of great interest and extensive utility in num…
The complete mitochondrial genome of Bactrocera biguttula (Bezzi) (Diptera: Tephritidae) and phylogenetic relationships with other Dacini
2018
Bactrocera biguttula is an African olive fruit fly that does not attack cultivated olives but rather develops in the fruits of wild species of Olea and Noronhia. The complete mitochondrial genome of an individual specimen was characterized in comparison to other Bactrocera. The phylogenetic relationships of B. biguttula with other Dacini were investigated, with special focus on B. oleae, an agricultural pest known to attack cultivated and wild olives. The sequence had a total length of 15,829 bp, and included the typical features of insect mitogenomes, similarly to the other Bactrocera analysed. Start codons included ATG, ATC, ATT, and TCG (in COI). The majority of stop codons (TAA) were fu…
The Hammerhead Ribozyme: A Long History for a Short RNA
2017
Small nucleolytic ribozymes are a family of naturally occurring RNA motifs that catalyse a self-transesterification reaction in a highly sequence-specific manner. The hammerhead ribozyme was the first reported and the most extensively studied member of this family. However, and despite intense biochemical and structural research for three decades since its discovery, the history of this model ribozyme seems to be far from finished. The hammerhead ribozyme has been regarded as a biological oddity typical of small circular RNA pathogens of plants. More recently, numerous and new variations of this ribozyme have been found to inhabit the genomes of organisms from all life kingdoms, although th…
Structure, interdomain dynamics, and pH-dependent autoactivation of pro-rhodesain, the main lysosomal cysteine protease from African trypanosomes
2021
AbstractRhodesain is the lysosomal cathepsin L-like cysteine protease ofT. brucei rhodesiense, the causative agent of Human African Trypanosomiasis. The enzyme is essential for the proliferation and pathogenicity of the parasite as well as its ability to overcome the blood-brain barrier of the host. Lysosomal cathepsins are expressed as zymogens with an inactivating pro-domain that is cleaved under acidic conditions. A structure of the uncleaved maturation intermediate from a trypanosomal cathepsin L-like protease is currently not available. We thus established the heterologous expression ofT. brucei rhodesiensepro-rhodesain inE. coliand determined its crystal structure. The trypanosomal pr…