Search results for " Elimi"
showing 10 items of 91 documents
Cluster Algorithm Integrated with Modification of Gaussian Elimination to Solve a System of Linear Equations
2020
The data accumulation and their inhomogeneous distribution lead to the issue of large and sparse systems solving in various fields: industrials, emergency management, etc. Complex structure in the data error creates additional risk to obtain an adequate solution. To facilitate problem-solving, we describe the technique that is based on intellectual division of data with following application of cluster algorithm and the modification of Gaussian elimination to different portions of data. In this paper, we present results of developed technique that was applied to samples of synthetic and real data. We compare them with outcomes of other algorithms (intelligence and classical) by using of num…
Kemp elimination: a probe reaction to study ionic liquids properties.
2008
The amino induced elimination of benzisoxazole into the relevant o-cyanophenolate ion (Kemp elimination) has been studied in [bmim][BF 4] solution at 298 K. To have information about the interactions between reactants and ionic liquid, the reaction has been carried out at different temperatures (293-313 K). Several primary, secondary, and tertiary amines have been used to study the effect of amine structure on the reaction rate. The collected data show that the amine structure seems to have a crucial role in determining the reaction rate. Furthermore, as different cation or anion structures of an ionic liquid can significantly affect its properties, the title reaction has been performed in …
Phenylation of cationic allylpalladium(II) complexes by tetraphenylborate anion. A mechanistic study
1990
Abstract The mechanism of the reaction of allyl complexes [Pd(η3-2-R′C3H4)(NN′)]+ (NN′ = α-diimine ligand) wiht BPh4− in the presence of activated olefins (ol), yielding the products [Pd(η2-ol)(NN′)] and PhCH2C(R′)CH2, has been investigated. The results are interpreted in terms of extensive association between the cationic substrate and the BPh4− anion in a tight ion-pair, followed by rate-determining phenyl transfer to the palladium center and fast reductive elimination of allylbenzene.
La recente riforma della disciplina italiana del subappalto nella prospettiva del bid rigging
2023
L’articolo analizza in chiave critica la disciplina nazionale del subappalto nell’ambito delle gare pubbliche, così come recentemente riformata a seguito di diversi interventi normativi in ottemperanza alla procedura d’infrazione avviata dalla Commissione UE. Stando alla tesi dell’A., l’attuale quadro normativo – caratterizzato dalla quasi totale eliminazione delle limitazioni previgenti (probabilmente anche spingendosi oltre ciò che la Commissione UE ha richiesto) – difetta nel trovare un equo bilanciamento tra il principio della massima partecipazione alla gara, da un lato, e l’esigenza di prevenire e svelare potenziali condotte collusive, dall’altro. La suddetta conclusione, peraltro, ap…
Mathematical formulation of pulse amplitude modulation selective harmonic elimination in multilevel three phase inverters
2022
In this paper multilevel cascaded H-bridges (CHB) three phase inverters with 2n dc sources, n=1,2,3,... are considered and a mathematical formulation providing both 2n switching angles and dc voltage source to eliminate n+1 harmonics and their respective multiple from their output voltage waveform, is proposed. The computed angles don't depend on modulation index and the source voltages linearly vary with it. The proposed procedure finds the solution through an analytical formula that avoids to solve transcendental systems and presents very low computational cost. A lot of low order harmonics are eliminated, returning a very low total harmonic distortion (THD). Particularly for 9-level conf…
Mixed Harmonic Elimination Control for a Single-Phase 9 Level Grid-Connected Inverter
2018
The power quality requirements are increasingly stringent, due to the continuous growth of devices connected to the grid that introduce harmonics. These devices include DC to AC energy conversion systems, i.e. grid connected inverters. The design, control and operation of these systems must take into account the rules of interconnection to the electricity grid. To improve the quality of the output waveform of the grid-connected inverter, Multilevel Converters (MC) with selective harmonic elimination modulation technique can be used. This paper presents a single-phase nine level grid-connected inverter with DC/DC input stages. The obtained switching angles for THD minimization are independen…
Trastornos de la alimentación. Trastornos de eliminación
2020
La patología que vamos a ver en este tema es sumamente interesante desde la perspectiva del desarrollo psicológico. El acto de alimentación es el primer regulador del afecto, en la medida en que la supervivencia física del individuo se asienta, ineludiblemente, sobre esta función somática. Cuestión largamente explorada y abordada desde la perspectiva psicodinámica –no en vano la primera etapa del desarrollo libidinal es la etapa oral–, la patología de la alimentación en los niños se está reconceptualizando en los últimos años como un proceso relacional y multisistémico (Davies et al., 2006). En el caso de los denominados Trastornos de la eliminación –encopresis y enuresis–, indican un fraca…
Calibration and simulation of ASM2d at different temperatures in a phosphorous removal pilot plant
2006
In this work, an organic and nutrient removal pilot plant was used to study the temperature influence on phosphorus accumulating organisms. Three experiments were carried out at 13, 20 and 24.5 degrees C, achieving a high phosphorus removal percentage in all cases. The ASM2d model was calibrated at 13 and 20 degrees C and the Arrhenius equation constant was obtained for phosphorus removal processes showing that the temperature influences on the biological phosphorus removal subprocesses in a different degree. The 24.5 degrees C experiment was simulated using the model parameters obtained by means of the Arrhenius equation. The simulation results for the three experiments showed good corresp…
External and internal elimination of supernumerary larvae in the whitefly parasitoid Eretmocerus mundus Mercet (Hymenoptera: Aphelinidae)
2008
Abstract The solitary parasitoid Eretmocerus mundus Mercet (Hymenoptera: Aphelinidae) is one of the key biological control agents of the whitefly Bemisia argentifolii Bellows & Perring, also known as B. tabaci (Gennadius) B-biotype (Homoptera: Aleyrodidae). We present new information on its biology, and particularly about larval elimination during the first instar in cases of superparasitism. For the first time, physical elimination of supernumerary larvae was observed, both outside and inside the host. These findings are documented with confocal microscopy images and video recordings. We observed more than 350 B. argentifolii nymphs, parasitized with one, two or more than two larvae. Physi…
Reactions of m-Terphenyl-Stabilized Germylene and Stannylene with Water and Methanol: Oxidative Addition versus Arene Elimination and Different React…
2015
Reactions of the divalent germylene Ge(ArMe6)2 (ArMe6 = C6H3-2,6-{C6H2-2,4,6-(CH3)3}2) with water or methanol gave the Ge(IV) insertion product (ArMe6)2Ge(H)OH (1) or (ArMe6)2Ge(H)OMe (2), respectively. In contrast, its stannylene congener Sn(ArMe6)2 reacted with water or methanol to produce the Sn(II) species {ArMe6Sn(μ-OH)}2 (3) or {ArMe6Sn(μ-OMe)}2 (4), respectively, with elimination of ArMe6H. Compounds 1–4 were characterized by IR and NMR spectroscopy as well as by X-ray crystallography. Density functional theory calculations yielded mechanistic insight into the formation of (ArMe6)2Ge(H)OH and {ArMe6Sn(μ-OH)}2. The insertion of an m-terphenyl-stabilized germylene into the O–H bond was…